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P1.4 O3.5
Divide both by the lowest one
P1.4 O3.5
P1O2.5
• Multiply the result to get rid of any fractions.
2X P1O2.5 = P2O5
• Caffeine is 49.48% C, 5.15% H, 28.87% N
and 16.49% O. What is its empirical
formula?
• 49.48 C
1mol = 4.1mol We divide by
12 g lowest (1mol O)
and ratio
doesn’t change
• 5.15 H 1mol
= 5.2mol
1g
1mol Since they are
• 28.87 N = 2.2mol
14 g close to whole
numbers we will
1mol use this formula
• 16.49 O = 1.0mol
16 g
C4.12 H5.15 N2.1 O1
OR C4H5N2O1
•194 g
=2
•97 g
2X C4H5N2O1
C8H10 N4O2.
Example
•Cl1C1H2
would give an empirical wt of 48.5g/mol
x=
molar mass 98.96 g
empirical formula mass = =2
48.5 g
2 X Cl1C1H2
= Cl2C2H4
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