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ARBOL PETROQUIMICO II
ANALISIS DE LA DEMANDA
1,410
1,116
3,775
6,301
Middle East/Africa
1,208
2,077
1,121
4,405
Southeast Asia
295
447
1,220
1,962
Indian Subcontinent
----
675
525
1,200
Europe
664
(146)
72
589
Americas
852
(627)
205
430
14,887
PRODUCCION
PRODUCCION
EFECTO DE LA TEMPERATURA EN LA
DESHIDROGENACION
CO-PRODUCCION DE
PROPILENO
OTROS PROCESOS
EJEMPLOS
PARAMAX
ing:
m
r
efo
A9+
R
/
X
R
/
CC
B/T
o
t
a
hth
p
a
N
HN
BT
A9+
A8
T&
d
H
N
ion
t
a
n
tio
Frac
tion
a
l
y
k
s al
/C8A
Z
B
Tran
+ to
9
A
Tol+
A8
FRN
ion
t
c
a
xtr
BT E tionation
ac
& Fr
BZ
BZ
BZ
PX
Loop
s
e
n
Xyle o PX/BZ
t
C8A
Refining
Unsaturated ROG
FCC C3 cut
FCC C4-C5 cuts
Technology
Final
Products
ss
PRU
Conversion to C3=
(C3=) PP
Purification
Dehydrogenation
H2, C4, Pygas
SR Naphtha
Cracked Naphtha
CCR Reformate
Gas Oil
HC bleed
VGO
AR/VR
Steam
Steam
Cracker
Cracker
Raffin.
(C2=) PE,
PVC
(C3=) PP
Pygas
Aromatics
Aromatics
Complex
Complex
ParamaX
ParamaX
(Styrene) PS
Polyethylene
terephthalat
e PET
HP FCC Technology
Riser separator RS
Stripper / Packing
Regenerator
Bathtub catalyst
distributor
540-560C
C/O = 10
ZSM-5 content
)crystal 40% (10-20%
Feed
LCN recycle
Resid to Propylene
Fuel Gas
Process Scheme
& Technology
Fractionator
Fractionator &&
Gas
Gas Recovery
Recovery
C3
C3 C4
C4 LPG
LPG
Treatment
Treatment
&& Separation
Separation
C3
C3
Splitter
Splitter
Propylene PG
Propane
Naphtha
Naphtha
Splitter
Splitter
Raw C4
720-740C
550C
C/O 8
HCN
LCO
590C
C/O 12
Slurry/CLO
FEED
660C
R2R
R2R
R2R
R2R
Risers
Risers
Risers &&&
Risers
Regenerators
Regenerators
Regenerators
Regenerators
LCN
Recycle
R2R Unit
Main Riser
Resid
PetroRiser
LCN
Propylene
Propane
Gas
Gas Recovery
Recovery
Raffinate
C4-C5 cut
Gasoline
Gasoline
Recycle
FCC
Feed
Distillate
TM
PolynaphthaTM
MF
Pool
Distillate
Valorize Polynaphtha
Gasoline or Distillate
to Motor Fuel to adjust
Gasoline/Diesel ratio
Operability
Continuous Catalyst
Regeneration
is based on
Axens CCR experience
> 100 Octanizing &
Aromizing references
Iso-5 Process
Flexible and easy to
operate regenerator
C3=
MAPD
MAPD
Selective
Selective
Hydrogenation
Hydrogenation
Oligomerization
Oligomerization
AlphaSelect/
-Select/
-Hexol
AlphaHexol
Dimerization
Dimerization
AlphaButol
AlphaButol
Purification
Purification
Multibed
Multibed
Maximum Butadiene
C4 Acetylenes
Acetylenes
C4
C4
Selective
Selective
Hydrogenation
Hydrogenation
Maximum Butenes
Steam Cracker
Butadiene
Butadiene
Selective
Selective
Hydrogenation
Hydrogenation
Hydrogenation
Hydrogenation
IB= Purification
Purification
IB=
Skeletal
Skeletal
Isomerization
Isomerization
C5=
Iso-5
Iso-5
/C5
CC44/C
5
Etherification
CC55Etherification
Catacol
Catacol
Olefins
Olefins
Hydrogenation
Hydrogenation
C2
Dimerization
Dimerization
Dimersol
Dimersol-X
Hydration
Isopure
Isopure
Oligomerization
Oligomerization
Selectopol
Selectopol
Polynaphtha
Polynaphtha
Dehydro.
Olefins
Olefins
Hydrogenation
Hydrogenation
C6-C10
Pygas
Pygas
Selective
Selective
Pygas Hydrogenation
Hydrogenation
GHU1
GHU1
C6-C10
C6-C8
Pygas
Pygas
Hydrodesulfurization
Hydrodesulfurization
GHU2
GHU2
Removal of
Arsenic & Mercury
RAM II
C9-C10
n-Butane
MEK
Solvents
TAME, TAEE
APU
APU
C5
Octenes
MTBE, ETBE
Advanced
Advanced
Pygas
Pygas
Upgrading
Upgrading
LPG
C5-C10
2-Butenes
Hydrogenation Fractionation
Fractionation
Hydrogenation
Max B=2
B=2
Max
C4/C5
Propylene
Butadiene
Isobutane
Isobutylene
SuperSuper-
Max B=1
B=1
Max
Etherification
Etherification
Catacol
Catacol
Lin. - Olefins
1-Butene
Butadiene
Extraction
CC44
1-Hexene
Extraction
Extraction
Sulfolane
Sulfolane
Morphylane
Morphylane
Sulfur
Sulfur
Removal
Removal
OATS
OATS
Benzene
Toluene
C8 Aromatics
to Aro. Complex
To Motor
Gasoline Pool
Condensates
CDU
Aromatic Complex
ParamaX
Naphtha Naphtha
H2
Benzene
Paraxylene
Gasoline
Toluene rich cut, A8+
A9+, raffinate, light naphtha Pool
Kero
HCK
VDU
Gasoline
Bleed
VGO
HP FCC
Delayed HCGO
Coker
Refinery production
400,000 bbl/d
Diesel
Propylene
LPG
Coke
Aromatics production
Paraxylene: 700 kt/y (2.5% of 2009 PX world production)
Benzene: 140 kt/y
Aromatic Complex
ParamaX
Benzene
Paraxylene
Existing refinery
Gasoline
H2 export
Pygas
Kero
Diesel
Residue
Propylene
SC
Ethylene
Aromatics production
Paraxylene: 1,400 kt/y (5% of 2009 PX world production)
Benzene: 650 kt/y
Steam Cracker
Complex
Naphtha
Resid
Coker
FCC
Alternative Fuel
units
Fischer-Tropsch
C4-C5 cut
>8 wt%
C2=
>30 wt%
C3=
Olicrack
C4-C5 cut
C4-C5 cut
or
C3=
8 to 20 wt
%
C 3=
FlexEne
or
C4-C5 cut
Unique integration
With FCC for
flexibility
Gasoline
/Distillate
HUNGARY
BAHA BLANCA
CATALIZADORES
CATALIZADORES
TESIS DE SEPARACION
SEPARACION POR
MEMBRANAS
SEPARACION DE PROPANO Y
PROPILENO
MEXICO