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Mini-Seminar

Dr. James Throne, Instructor

8:00-8:50 - Technology of Sheet


Heating
9:00-9:50 - Constitutive Equations
Applied to Sheet Stretching
10:00-10:50 - Trimming as
Mechanical Fracture

Mini-Seminar
Advanced Topics in Thermoforming

Part 1: 8:00-8:50
Technology of Sheet Heating

Lets
begin!

Mini-Seminar
Advanced Topics in Thermoforming
All materials contained herein are the intellectual
property of Sherwood Technologies, Inc., copyright
1999-2006
No material may be copied or referred to in any
manner without express written consent of the
copyright holder
All materials, written or oral, are the opinions of
Sherwood Technologies, Inc., and James L. Throne,
PhD
Neither Sherwood Technologies, Inc. nor James L.
Throne, PhD are compensated in any way by
companies cited in materials presented herein
Neither Sherwood Technologies, Inc., nor James L.
Throne, PhD are to be held responsible for any
misuse of these materials that result in injury or
damage to persons or property

Mini-Seminar
Advanced Topics in Thermoforming
This mini-seminar requires you to have a
working engineering knowledge of heat
transfer and stress-strain mechanics
Dont attend if you cant handle theory
and equations
Each mini-seminar will last 50 minutes,
followed by a 10-minute bio break
Please turn off cell phones
PowerPoint presentations are available at
the end of the seminar for downloading
to your memory stick

Part 1: Technology of Sheet Heating

Outline

Fundamentals
Dimensionless Groups - Definitions
Radiation Explained
Arithmetic
Energy Dome
Radiant Heat Transfer Equation
Ditto - Where is the Problem?
Problem Solved! No?

Part 1: Technology of Sheet Heating

Fundamentals
Conduction
Convection
Radiation

Part 1: Technology of Sheet Heating

CONDUCTION
Solid-solid energy interchange
Moving thermal energy through sheet
Moving thermal energy, sheet to mold
In very thin sheet, conduction is used to move
thermal energy from heater to sheet through
direct contact
Important Parameters
Thermal conductivity
Heat capacity or Enthalpy

Part 1: Technology of Sheet Heating

CONVECTION
Fluid-solid energy interchange
Sheet heating (or cooling) during sheet
heating in oven
Free surface cooling in mold cavity
Primary way of heating very thick sheet
Important Parameters
Convective heat transfer coefficient
Air velocity, temperature
Recrystallization, recrystallization rate

Part 1: Technology of Sheet Heating

Convection heat transfer coefficient values


Fluid
Quiescent air
Air with fan
Air with blower
Air/water mist
Fog
Water spray

h(Btu ft2 hr oF)


0.8 - 2
2 - 5
5 - 20
50 - 100
50 - 100
50 - 150

Part 1: Technology of Sheet Heating

Dimensionless Groups - Definitions


Biot number
Bi = hL/k
Fourier number
Fo = aq/L2
h
convective heat transfer coefficient
L
half-thickness (heating on both sides)
k
thermal conductivity
a
thermal diffusivity, k/rcp
q
time
r
density
cp
specific heat

Part 1: Technology of Sheet Heating

RADIATION
Electromagnetic energy interchange at a
distance
Method commonly used to heat all but very
thin or very thick sheet
Important parameters
Heater temperature
Heater and sheet emissivities
Thin-gauge sheet transmissivity
Sheet, heater geometry, spacing

Part 1: Technology of Sheet Heating

Radiation Fundamentals

Black body, gray body, real body


Emissivity and absorptivity
Energy interchange
Wavelength-dependent energy transmission in
the far-infrared region
Semi-transparency in thin-gauge sheet

Part 1: Technology of Sheet Heating

Dimensionless Groups - Definitions


Radiation Biot number Bir = hrL/k
Radiation number
Rad = LFFgs/k
hr
radiative heat transfer coefficient
L
half-thickness (heating on both sides)
k
thermal conductivity
F
View factor
Fg
Emissivity factor
s
Stefan-Boltzmann constant

Part 1: Technology of Sheet Heating

Radiation concepts - Explained


Emissivity, e, absorptivity, a, considered
similar
Emissivity = 1, black body
Emissivity between 0 and 1 and wavelengthindependent, gray body
Typical polymer emissivity, 0.90 < e < 0.95
Typical polymer emissivity, e=e(l),
absorptivity, a=a(l)
Thin films semi-transparent, t = t(l)

Part 1: Technology of Sheet Heating

The Black Body Energy


Curve, Showing
Increasing Energy
Output (logarithmic
scale, left axis),
Shifting of Peak
Wavelength to
Shorter Values With
Increasing Heater
Temperature

Part 1: Technology of Sheet Heating

So What is Wavelength?
Visible Wavelength of light:
0.4 - 0.7 mm
Near-infrared:
0.7 - 2.5 mm
Far-infrared (most TFing): 2.5 - 15 mm (+)

Part 1: Technology of Sheet Heating

So What is Wavelength?
Visible Wavelength of light:
0.4 - 0.7 mm
Near-infrared:
0.7 - 2.5 mm
Far-infrared (most TFing): 2.5 - 15 mm (+)

Part 1: Technology of Sheet Heating

Radiation concepts - Explained


Energy interchange between heater [source]
and sheet [sink]
What you see is what you heat!
Wavelength symbol is l, units are microns
[mm]
For l < 0.38 mm, ultraviolet
For 0.38 < l < 0.7 mm, visible
For 0.7 < l < 2.5 mm, near infrared
For 2.5 < l < 100 mm, far infrared
Most thermoforming, l between 3 and 15 mm

Part 1: Technology of Sheet Heating

IR scans for thin-gage polymers

Note key 3.5 mm and 8 mm wavelengths

Part 1: Technology of Sheet Heating

WavelengthDependent
Transmission
Through Thin
Films of

PS
PE
and PVC

[Thank you, Ircon!]

Part 1: Technology of Sheet Heating

IR scans for thin-gage polymers

Part 1: Technology of Sheet Heating

Thick - or Heavy-Gauge Heating, Showing


Temperature Profile Through Sheet

Part 1: Technology of Sheet Heating

Thin-Gauge Heating,
Showing Radiant
Energy Absorbing and
Transmitting Through
Flat Temperature
Profile Sheet

Part 1: Technology of Sheet Heating

Radiation is extremely complex


Diffuse v. specular surface (textured v.
polished sheet)
Planar v. curved surface (effect of sag)
Effect of pigment (differential energy
absorption at surface)
Radio-opaque v. volumetric absorbing
Internal reflection v. transmission
Reflection, absorption at multilayer interface

Part 1: Technology of Sheet Heating

What goes on inside the sheet


Reflectivity and
transmissivity of a
thick semitransparent sheet
of plastic
Properties are
determined through
ray tracing

Part 1: Technology of Sheet Heating

Radiation is extremely complex


This morning we consider only the simplest of
radiant energy transfer, viz, diffuse radiation
from gray body heaters to planar, radioopaque, unpigmented, gray body, single layer,
amorphous sheet
If time, we look at a slightly more complex
situation

Part 1: Technology of Sheet Heating

Emissivity - What is
it anyway?
Incoming radiation is
either:
Absorbed by the
plastic
Reflected from the
plastic
Transmitted
through the plastic

Part 1: Technology of Sheet Heating

An ideal material
absorbs all incoming
radiation (a=1)
An ideal material emits
all of its energy (e=1)
That ideal material is
called a black body
Most real materials
have absorptivities,
emissivities less than
one [1]

Plastics, rusty,
oxidized metals have
emissivities of 0.90.95

Part 1: Technology of Sheet Heating

Conduction Heat Transfer - Assumptions


One-dimensional (thickness)
Transient (time-dependent)
Initial sheet temperature independent of sheet
thickness
Step change in surface temperature
Surface temperature independent of sheet
thickness
Thermal properties independent of temperature
Surface temperature same on both sides of
sheet

Part 1: Technology of Sheet Heating

Conduction Heat Transfer - Equation


T
T
cp r
= k

q x x

or

T
2T
=a 2
q
x

T(x,q) is instant temperature, q is time, a is thermal


diffusivity, x is distance into sheet
BC1: T(x,0) = Ti
BC2: T(0,q) = To
BC3:
(symmetry about the centerline
T
k
= 0 of the sheet)
x
x =L

Part 1: Technology of Sheet Heating

Conduction Heat Transfer Dimensionless Equation

Y
Y
= 2
Fo x
2

Y = (T-To)/(Ti-To),
Fo = aq/L2, x = x/L

Part 1: Technology of Sheet Heating

Convection Heat Transfer - Assumptions


One-dimensional (thickness)
Transient (time-dependent)
Initial sheet temperature independent of sheet
thickness
Surface temperature dependent on thermal
gradient, convection heat transfer coefficient
Environmental temperature independent of sheet
thickness
Thermal properties independent of temperature
Convection condition same on both sides of
sheet

Part 1: Technology of Sheet Heating

Convection Heat Transfer - Equation


T
2T
=a 2
q
x
T(x,q) is instant temperature, q is time, a is thermal diffusivity, x
is distance into sheet
BC1;
T(x,0) = Ti
BC2:
BC3:

T
= h(T Ta )
x x =0

T
=0
x x =L

(symmetry about the centerline


of the sheet)

Part 1: Technology of Sheet Heating

Convection Heat Transfer Dimensionless Equations

Y
Y Y = 0
= 2
Fo x x x =1
2

Y
= Bi Y
x x =0
Y = (T-Ta)/(Ti-Ta),
Fo = aq/L2, x = x/L, Bi=hL/k

Part 1: Technology of Sheet Heating

Convection Heat Transfer - Graph


Centerline

Surface

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Assumptions


One-dimensional (thickness)
Transient (time-dependent)
Initial sheet temperature independent of sheet
thickness
Surface temperature dependent on radiant
heat flux, fourth-power of temperature
differences

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Assumptions


Geometric factors independent of sheet, heater
shapes
Radiant properties independent of temperature
Diffuse surface absorption only (radio-opaque)
Radiant boundary conditions same on both sides
of sheet

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


T
2T
=a 2
q
x
T(x,q) is instant temperature, q is time, a is
thermal diffusivity, x is distance into sheet
BC1: T(x,0) = Ti

4
4
BC2: T
= sFFg T *h T * s
x x =0
BC3:
(symmetry about the centerline
T
k
= 0 of the sheet)
x x =L

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


What is Fg?

Fg is gray body correction factor for non-black


body radiation
If sheet, heater emissivities (es, eh) are <1 and
independent of wavelength, then
1 1
Fg = 1 / 1
e h e s

If eh = es = 0.9, Fg =0.82

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


What is F?
F is view factor, a geometric parameter
F is the measure of average fraction of energy
transferred from the heater to the sheet
surface
In other words, what you see is what you heat

Part 1: Technology of Sheet Heating

What do heaters heat?


All visible surfaces
Plastic sheet
Heater reflectors
Other heaters (esp. with transparent sheet)
Pin-chain rails
Heater guards
Objects outside the oven edges
Oven sidewalls, shields, baffles
Sag bands and other sheet supports

Part 1: Technology of Sheet Heating

The View Factor


Heaters heat what they see!
Heating efficiency - From a given heater
decreases in proportion to the square of the
distance to the sheet, E prop.to 1/Z2
Oven efficiency depends on minimizing energy
transfer to non-sheet - rails, oven walls, etc.

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


What is F?
Often the view factor is given as a number
(0<F<1)
This is incorrect
We return to an examination of view factor
shortly

Part 1: Technology of Sheet Heating

Radiative Heat Transfer Dimensionless Equations

Y
Y
= 2
Fo x
2

Y
=0
x x =1

Y
= Bir Y
x x =0

Y = (T-Th)/(Ti-Th), Fo = aq/L2, x = x/L, Bir=hrL/k


hr = radiative heat transfer coefficient

hr = sFFg (Th* Ts* )(Th*2 Ts*2 )

Part 1: Technology of Sheet Heating

Combined Conduction, Convection, Radiation


Equation with Boundary Conditions

Y
2Y
= 2
Fo x

Y
=0
x x =1

Y
= [ Bi Bir ] Y
x x =0

Keep in mind that these equations assume


temperature-independent physical
properties and equal boundary conditions
on both sides of the sheet

Part 1: Technology of Sheet Heating

Combined Conduction, Convection, Radiation


Equation with Boundary Conditions
Parabolic equation with nonlinear boundary
conditions
Two methods of solution
Finite Element Analysis [FEA]
Finite Difference Equations [FDE]

Part 1: Technology of Sheet Heating

Combined Conduction, Convection, Radiation


Finite Difference Equation with Boundary
Conditions
Ti ' = Fo (Ti 1 Ti 1 ) (1 Fo )Ti
T0' = T0 2Fo(T1 T0 ) 2Fo(Ta,0 Bi0T0 ) 2FoRad0 (Th*,40 T0*4 )
TN' = TN 2Fo(TN 1 TN ) 2Fo(Ta, N BiNTN ) 2FoRadN (Th*,4N TN*4 )

where 0 and N represent the top and bottom


surfaces of the sheet and where...

Part 1: Technology of Sheet Heating

Combined Conduction, Convection, Radiation


Finite Difference Equation with Boundary
Conditions
where
1 e s ,i
1 1 e h ,i

FFg ,i = 1 /

F12
e h,i
e s ,i

Average temp:

Rad i = xFFg ,is / k


F12 is the average view
factor,es is the sheet
emissivity, eh is the heater
emissivity
Tavg

1 T0 TN N 1
=
Ti
N 2
i =1

Part 1: Technology of Sheet Heating

Combined Conduction, Convection, Radiation


Finite Difference Equation with Boundary
Conditions
This equation is easily solved using Fortran or
Q-Basic
The calculated time-dependent sheet
temperature is based on an average value for
the energy transferred between the heater and
the surface, viz, a fixed value for the view
factor, F
This result may not apply to many practical
cases

Part 1: Technology of Sheet Heating

The Energy Dome


Cannot be predicted using average value for
view factor, F
Needs first principles in radiation
[What is the Energy Dome?]
[More importantly, how do you calculate it?]

Part 1: Technology of Sheet Heating

The Energy Dome


Concept
When a sheet of finite
dimensions is heated
uniformly with a heater
of similarly finite
dimensions
The center of the sheet
is hotter than the edges
The edges of the sheet
are hotter than the
corners

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
The use of a constant value for F, the view factor

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
Consider the energy
interchange between
differential elements
on the sheet and on
the heater
Here, direction
cosines and the solid
angle radius, r, are
defined

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
The energy interchange between a heater element
dA1 and a sheet surface element dA2 is given as

q12 = sFg T T
*4
h

*4
s

cosf1 cosf2
A2 A1 r 2 dA1dA2

where cos fi are the direction cosines defined


earlier, and r is the distance between the two
elements

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
The equation assumes all heater elements have
the same temperature and all sheet surface
elements have the same temperature
The double integral correctly represents the
view factor integrated over all heater elements
and all sheet surface elements

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
Now replace the differential elements with
discrete elements, A1 and A2

q12 = sFg T T
*4
h

*4
s

A1

A2

cosf1 cosf 2
A1A2
2
r

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
The terms cos f are direction cosines, and r is
the solid angle radius between each pair of the
difference elements, as defined earlier
For each of the planar heater and sheet
elements, the direction cosines are cos f1 = cos
f2 = z/r
z is the line distance between the two elements

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
For each of the planar heater and sheet
elements, r, the spherical radius, is given as:

r = x2 y 2 z 2

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
The direction cosines and the term for r are
now combined in the double summation equation.
When the local sheet and heater temperatures
are also moved inside the double summation, the
following equations obtain...

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
For the energy transfer from one heater
element to all sheet elements

z2
*4
*4
(Th Ts )A2
q1 2 = sFg A1
2
2
2 2

A2 (x y z )

For the energy transfer from all heater


elements to one sheet element
q

1 2

z2
*4
*4
(Th Ts )A1
= sFg A2
2
2
2 2
A1 (x y z )

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
These are the new radiation boundary condition
equations
They are now combined with the traditional
convection boundary conditions
And the finite difference equation is solved for
each heater element and each sheet element

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
As an example, a 7 x 7 matrix heater
interchanges energy with a 7 x 7 matrix sheet
The FDE is solved 49 x 49 times for each time
step
Because the equation is parabolic, no iteration
is necessary

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
If all 49 heater elements have the same
temperature, the result is the energy dome, as
predicted

Part 1: Technology of
Sheet Heating

The net %
energy
received by
each element
when heater
temps are
equal
everywhere

Part 1: Technology of Sheet Heating

Part 1: Technology of Sheet Heating

Radiant Heat Transfer - Equation


Where is the problem?
If the temperatures of the heater elements are
now changed by trial and error so that the
entire sheet heats at the same rate, the
energy dome is flattened

Part 1: Technology of Sheet Heating

The % values
represent the
local heater
flux output
change from
the original
100%

Part 1: Technology of Sheet Heating

Part 1: Technology of Sheet Heating

Problem Solved!
No?
What Assumptions Need to be
Relaxed?

Part 1: Technology of Sheet Heating

Problem Solved! No?


What Assumptions Need to be Relaxed?

1. Most models assume planar sheet (sheet sags


during heating. Does this affect local heating?
Art Buckel says no. Is he right?)
[Note: cosine geometry gets brutal. The 2D model
has been solved using catenary equations to
describe sheet surface. The 3D model using
parabolic hyperboloid equations to describe
sheet surface has not. Read 4Q06 Tech
Article for additional information.]

Part 1: Technology of Sheet Heating

Problem Solved! No?


What Assumptions Need to be Relaxed?
2. Models assume wavelength-independent (and
therefore, temperature-independent) sheet and
heater emissivities
3. Model designed for cut sheet. What about rollfed sheet? (Roll-fed sheet clamped on two
sides, endless, multiple shots in oven)

Part 1: Technology of Sheet Heating

Problem Solved! No?


What Assumptions Need to be Relaxed?
4. Convection boundary condition assumes constant
air temperature, constant convection heat
transfer coefficient (in thin-gauge, sheet
start-stop during transit through oven)

5. Model designed for opaque sheet (Semitransparent sheet is heated by volumetric


energy absorption)

Part 1: Technology of Sheet Heating

Problem Solved! No?


What Assumptions Need to be Relaxed?
6. Model does not include role of pigment, filler
in sheet heating (Solid particles change thermal
properties, absorption characteristics)
7. Model assumes amorphous polymers, so latent
heat of fusion, phase boundary are not
included
8. For combustion radiant heaters, the role of
the absorption and reradiation of combustion
gases (H2O, CO2) needs to be included

Part 1: Technology of Sheet Heating

Problem Solved! No?


What Assumptions Need to be Relaxed?
9. Diffuse absorption, reflection, reradiation from
oven walls, etc., need to be included
10. Most models assume uniform radiant heating,
air environment on both sides of sheet (Radiant
heaters are usually at different temperatures,
air is trapped against underside of sheet)

Part 1: Technology of Sheet Heating

Problem Solved! No?


What Assumptions Need to be Relaxed?
11. Model assumes monolayer. Multilayer
laminates involve interfacial reflection and
localized absorption, as well as interfacial
conduction

Part 1: Technology of Sheet Heating

Okay, give us an example of how just one


of these assumptions can be relaxed!
Number 5

Radio-opacity v. volumetric absorption or


diathermanousity
Beers law: Wavelength-dependent absorption is
exponentially dependent on depth into the
plastic
Primary assumptions: Sheet remains planar; only
diffuse absorption, reflection

Part 1: Technology of Sheet Heating

Okay, give us an example of how just one


of these assumptions can be relaxed!
Reflectivity and
transmissivity of a
thick semitransparent sheet
of plastic
Properties are
determined through
ray tracing

Part 1: Technology of Sheet Heating

Okay, give us an example of how just one


of these assumptions can be relaxed!
Transmission is given as

t =e

k 2 d / cosq 2

=e

4k2d / l0 cosq 2

Where k2 is the Beers law absorption coefficient,


l0 is the wavelength of the incident energy and
d/cos q2 is the distance the radiant beam
travels through the plastic in one pass

Part 1: Technology of Sheet Heating

Okay, give us an example of how just one


of these assumptions can be relaxed!
Reflectivity at the interface of the sheet surface
is usually given in terms of the relative indices
of refraction at the interface
n1 n2

r12 =
n1 n2

r air plastic

1 n plastic

=
1 n

plastic

Part 1: Technology of Sheet Heating

Okay, give us an example of how just one


of these assumptions can be relaxed!

Reflectivity from the sheet is given as

(1 r ) t 2
Rsheet = r 1
2 2
1 r t

Where r is the reflectivity at both inner and


outer sheet surfaces and t is the transmissivity
of a single pass through the sheet. Note: these
values are wavelength-dependent!

Part 1: Technology of Sheet Heating

Okay, give us an example of how just one


of these assumptions can be relaxed!
Transmissivity through the sheet is given as

sheet

(
1 r )t
=
2

1 r t

2 2

Part 1: Technology of Sheet Heating

Okay, give us an example of how just one


of these assumptions can be relaxed!
Absorptivity within the sheet is given as

Asheet

(
1 r )(1 t )
=
1 rt

Part 1: Technology of Sheet Heating

Okay, give us an example of how just one


of these assumptions can be relaxed!
The general heat conduction equation now includes
a term, q, for volumetric energy absorption:

T
T
rc p
=
ql (T ), x
q x x

Part 1: Technology of Sheet Heating

Okay, give us an example of how just one


of these assumptions can be relaxed!
Has this problem been solved? Yes, analytically, in
the 1970s [Progelhof, Quintiere and Throne]
for coextruded clear PMMA-pigmented ABS.
The general effect of increasing volumetric
absorption is a flattening of the timedependent temperature profile.

Viz, the instant surface temperature does not


increase as rapidly as with radio-opaque sheet
while the instant internal temperatures increase
more rapidly

Part 1: Technology of Sheet Heating

End of

Part 1
Technology of Sheet Heating

Part 1: Technology of Sheet Heating

Part 2

Constitutive Equations Applied to Sheet


Stretching
Begins promptly at 9:00!

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