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oleh :
Trisna Kumala Dhaniswara,S.T.,M.T
3. Use conversion factors (which are really ratios) and their UNITS to
CONVERT what is given into what is desired.
5280 ft
1 mile
12 inches
1 ft
Units match
= 633600 inches
Goal
Convert
Menu
Given
-2
k
hr min
45 mi 5280 ft 12 in 2.54 cm 1 x 10
mi
hr
1 ft
c
1 x 10 3 60 min 60 s
1 in
c cancels c
m remains
This is
the
same as
putting
k over k
= 0.020
km
s
Units Match!
6
Goal
units match
mol
185.97 g
= 0.0278
moles Fe(C5H5)2
Fe(C5H5)2
2 x 5 x 1.001 = 10.01
2 x 5 x 12.011 = 120.11
1 x 55.85 = 55.85
185.97 g
mol
4mol NO 2
2mol N 2O 5
= 8.6
moles NO2
1mol O 2
2mol N 2O 5
? mol
= 2.2
mole O2
9
210 g NO2
mol NO 2
46.0g NO 2
Units match
2mol N 2O 5
4mol NO 2
= 2.28
moles N2O5
b. How many grams of N2O5 are needed to produce 75.0 grams of O2?
2N2O5(g) 4NO2(g) + O2(g)
75.0 g
? grams
75.0
g O2
mol O 2
32.0 g O 2
2mol N 2O 5
1mol O 2
108g N 2O 5
mol N 2O 5
3 H2(g)
11
3 H2(g)
3 H2(g)
Units match
3.45 g Al
mol Al
27.0 g Al
We
Now
Now
Lets
must
use
use
work
the
always
themolar
the
molar
problem.
convert
mass
ratio.to
convert
moles.
to grams.
17.0 g AlCl3
13
Molarity
Molarity is a term used to express concentration. The units of molarity are
moles per liter (It is abbreviated as a capital M)
moles
moles
M
Liter 1000 mL
14
Solutions
Molarity
followed by
dilution.
15
Solutions
3.73 g
mol
= 0.140 mol
133.4 g 200.0 x 10-3 L
L
molar mass of AlCl3
2nd:
M1V1 = M2V2
dilution formula
Solution Stoichiometry
50.0 mL of 6.0 M H2SO4 (battery acid) were spilled and
solid NaHCO3 (baking soda) is to be used to neutralize the
acid. How many grams of NaHCO3 must be used?
H2SO4(aq) + 2NaHCO3 2H2O(l) + Na2SO4(aq) + 2CO2(g)
17
Solution Stoichiometry
50.0 mL of 6.0 M H2SO4 (battery acid) were spilled and
solid NaHCO3 (baking soda) is to be used to neutralize the
acid. How many grams of NaHCO3 must be used?
H2SO4(aq) + 2NaHCO3 2H2O(l) + Na2SO4(aq) + 2CO2(g)
50.0 mL
? g Our Goal
6.0 M
=
6.0 mol
L
Look!
A conversion
factor!
18
Solution Stoichiometry
50.0 mL of 6.0 M H2SO4 (battery acid) were spilled and
solid NaHCO3 (baking soda) is to be used to neutralize the
acid. How many grams of NaHCO3 must be used?
H2SO4(aq) + 2NaHCO3 2H2O(l) + Na2SO4(aq) + 2CO2(g)
50.0 mL
? g Our Goal
6.0 M
=
6.0 mol
L
H2SO4
NaHCO3
2 mol
1 mol
H2SO4
NaHCO3
84.0 g
= 50.4 g NaHCO3
mol
NaHCO3
19
Solution Stoichiometry:
Determine how many mL of 0.102 M NaOH solution are needed to
neutralize 35.0 mL of 0.125 M H2SO4 solution.
2
1 2SO4
____NaOH
+ ____H
2 2O
____H
1 2SO4
____Na
20
Solution Stoichiometry:
Determine how many mL of 0.102 M NaOH solution is needed to
neutralize 35.0 mL of 0.125 M H2SO4 solution.
2
1 2SO4
____NaOH
+ ____H
0.102 M mol
L
? mL
Our Goal
2 2O
____H
1 2SO4
____Na
35.0 mL
0.125 mol 0.125 mol
L
1000 mL
Since 1 L = 1000 mL, we can use
this to save on the number of conversions
Solution Stoichiometry:
Determine how many mL of 0.102 M NaOH solution is needed to
neutralize 35.0 mL of 0.125 M H2SO4 solution.
2
1 2SO4
____NaOH
+ ____H
2 2O
____H
1 2SO4
____Na
0.102 M mol
35.0 mL
L
0.125 mol 0.125 mol
? mL
sho
1000mL
rtcu L
t
Units Match
H2SO4
H2SO4
NaOH
35.0 mL
2 mol
1000 mL NaOH = 85.8 mL NaOH
0.125 mol
1 mol
0.102 mol NaOH
1000 mL
H2SO4
H2SO4
22
Solution Stoichiometry
23
Solution Stoichiometry
Ba(OH)2(aq)
0.40 M
47.1 mL
0.75 M
? mL
Ba(OH)2
47.1 mL
0.75mol Ba(OH)2
2H2O(l) +
BaCl2
Units match
HCl
2 mol
Ba(OH)2
HCl
1000 mL
0.40 mol
HCl
= 176 mL HCl
24
1
2
1
____Ba(OH)
2(aq) ____H2O(l) + ____BaCl2(aq)
25.00 mL
? mol
L
1
2
1
____Ba(OH)
2(aq) ____H2O(l) + ____BaCl2(aq)
25.00 mL
Units match on top!
? mol
L
23.28 mL HCl
25.00 x 10-3 L
Ba(OH)2
Ba(OH)2
We must first
write a balanced
equation.
27
HNO 3
2)
HNO 3
units match!
28
Nowthe
place
First copy down
numerical the
the BALANCED
information below
equation!
the compounds.
29
Two starting
amounts?
Where do we
start?
one
30
3mol O 2
4mol KO 2
= 0.1125 mol O2
31
3mol O 2
4mol KO 2
3mol O 2
2mol H 2O
= 0.1125 mol O2
= 0.150 mol O2
32
3mol O 2
4mol KO 2
3mol O 2
2mol H 2O
= 0.1125 mol O2
It was limited by the
amount of KO2.
= 0.150 mol O2
33
actual yield
% yield
x 100
theoretical yield
% yield
12.3
x 100 63.1% yield
19.5
34
= 40.51 g O2
35
mol H 2O
3 mol O 2 32.0g O 2
Based on: 47.0 g H2O
18.02 g H 2O 2 mol H 2O mol O 2
H2 O
= 40.51 g O2
= 125.3 g O2
Question if only 35.2 g of O2 were recovered, what was the percent yield?
actual
35.2
x 100
x 100 86.9% yield
theoretical
40.51
36
= 40.51 g O2
mol H 2O
3 mol O 2 32.0g O 2
Based on: 47.0 g H2O
18.02 g H 2O 2 mol H 2O mol O 2
H2 O
= 125.3 g O2
31.83 g XS H2O
37
25.6 g mole
mol
0.264
-3
213 g 455 x 10 L
L
38
Chemistry: Stoichiometry
Unifying Theme: Constancy, Change, and Measurement
Why
What
How
Enduring
Understandings
Essential Questions
Assessment Examples
Essential
HS4.4.5.1 use the coefficients of a balanced
equation to predict amounts of reactants and
products.
HS4.4.5 demonstrate that adjusting
quantities of reactants will affect the amounts
of products formed.
HS4.4.A.A identify and define Avogadros
number and the mole concept operationally
and conceptually.
HS4.4.A.B utilize dimensional analysis to
perform mole to mole, mass to mass, particle
to mole, and mole to particle calculations.
HS4.4.A.D use formula mass to calculate
percent composition of a compound.
HS.4.4A.F solve problems involving
quantitative relationships in equations
including stoichiometric concepts of mole to
mole, particle to particle, mass to mass, mole
to volume and volume to mole.
HS4.4.A.G manipulate the limiting reagent
concept qualitatively to conclude that the
starting materials of the chemical industry
such as petroleum, are limited resources and
decisions must be made about their wise
consumption.
HS1.6.4 manipulate quantities and/or
numerical values in algebraic equations.
HS1.7.4 recognize mathematics as an
integral part of the scientific process.
HS4.4.1.5 calculate the molecular weight of
a compound given in the Periodic Table.
Pre-assessment
-Brainstorm the collective terms such as
dozen, pairs, gross, etc, and conversions
between the terms and their numerical
values.
Formative Assessment
-Develop a creative concept map to
illustrate the relationships among mole,
mass, volume and number of particles.
Summative Assessment
-Competition: Students are given a
specific amount of iron filing and copper
sulfate. They are required to return exact
one gram of elemental copper after the
reaction is completed.
-Write an article for your school paper
about the air pollution in your community.
Be sure to include the stoichiometric
analysis.
39
Chemistry: Stoichiometry
How
Suggested Instructional Sequence
Introduction of mole concept.
- What is mole?
- Determine the number of rice grains in a given container.
Guided practice in calculation of atomic mass, molar mass, and formula mass.
Utilize dimensional analysis to convert among mole, gram, volume and number of particles.
- Lab Galvanized Iron: determine number of atoms of Zn coated on a piece of galvanized iron.
- Guided practice: mole conversions using mole concept map.
Percent of composition;
- Lab percent of water in popcorn
- Lab determining an Empirical formula such as copper sulfate hydrates.
Introduction of Stoichiometry
- Demonstration: electrolysis of water to illustrate the mole ratio.
- Lab Use stoichiometric relationship to analyze the amount of silver replaced from silver nitric
solution with the copper.
Introduction of limiting reagent
- Using manipulation to demonstrate limiting reagents (cake recipe)
- A research project about the limitation of a natural resource, such as petroleum, copper.
Differentiation Examples
Challenge
-Design a lab to synthesize a
quantitative product when given
a variety of reactants
-Design a lab to determine the
empirical formula for a given
hydrate compound.
Adjust
Predict the volume of carbon
dioxide that would be produced
by adding specified amounts of
vinegar to various teaspoons of
baking soda. Carry out the
activity and compare the
experimental results with your
prediction. Account for any
differences in volume.
ESOL
Create a PowerPoint
presentation to explain
stoichiometry
40