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Charged Surfaces
OH
OH
OH2
H+
OH
OH
OH
OH
H+
GOUY-CHAPMAN
DOUBLE-LAYER
MODEL
STERN-GRAHAME
TRIPLE-LAYER
MODEL
Diffusion Rates
Diffusion, Fickian:
First law (steady state):
C
J D
x
C
C
D 2
t
x
2
dC
RkfC
dt
pH
Ligand-assisted dissolution
Thought to be minor for many
aluminosilicates, but key for many other
minerals (ex.: FeOOH minerals)
Similar to surface-complex control, ligands
strongly binding with surface groups on
the mineral surface can greatly increase
rate (and solubility of the ion in solution,
changing the SI)
Nuclei formation
Classical view of precipitation start with the
formation of a critical nuclei, which requires
a large degree of supersaturation
Energy to form a nuclei: Gj=Gbulk-Gsurf
Rate of nuclei formation is then related to
the energy to form the particle, the size of
the critical nuclei, collisional efficiency of
ions involved, the degree of supersaturation,
and temperature
Nucleation rate
B 2 2
J exp 3 3
2
k T (ln S )
Where B is a shape factor equal to 16/3 for a sphere and
32 for a cube, is the interfacial free energy, is the
molecular volume, k is Boltzmanns constant (1.38x10-23
J/K), T is temperature (K), S is the supersaturation ratio
(C/Cs), and is a pre-exponential factor (around 10333
cm-3 sec-1 and approximated by ( = D/(^5/3) )