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Chem 6C Edition
Stressed-Out Charlie Lin
And Miles whose last name I
cant spell
Transition Metals
Naming
Itll be a salt so name cation first then
anion
The cation or anion will be a complex to
name a complex:
Take all the ligands and put them by their
greek name alphabetically.
Reactions
Q4: Which of the following
coordination compounds will form a
precipitate when treated with an
aqueous solution of AgNO3?
a) [Cr(NH3)3Cl3]
b) [Cr(NH3)6]Cl3
c) [Cr(NH3)Cl]SO4
d) Na3[Cr(CN)6]
e) Na3[CrCl6]
Shapes
4 Primary shapes
Octahedral
6 ligand attachment points groups
Tetrahedral
Square Planar
Linear
2 Ligand attachment points
Isomers
Geometric
Enantiomers
Maybe skip :P
Which of the following compounds is
chiral?
[Cr(en)2Cl2]+ with cis Cl
[Cr(en)2(NH3)2]3+ with trans NH3
[Cr(en)3]3+
[Cr(en)Cl2(NH3)2]+ with cis Cl and cis NH3
http://www.nobelprize.org/nobel_prizes/
chemistry/laureates/2001/illpres/game.h
tml
Paramagnetic
Unpaired electrons and can be magnetized by
external field
Diamagnetic
No unpaired electrons and cannot be magnetized
with external magnetic field
26-34
Some of the first complexes
discovered by Werner in the 1890s
had the empirical formulas given
below. Also are the number of
chloride ions per formula unit
percipitated by the addition of Ag+
(aq).Empirical
Explain
these Number
observations.
Formula
of Cl- per
formula unit
percipitated by Ag+ (aq)
PtCl2*4NH3
PtCl2*3NH3
PtCl2*2NH3
Buffers (21-20)
Describe how you would prepare
200.0 mL of a pH = 4.00 buffer
solution from a solution of 0.150 M
lactic acid, CH3CHOHCOOH (aq), and
a solution of 0.100-M barium
hydroxide, Ba(OH)2 (aq). Take the
pKa of lactic acid to be 3.86.
Titrations
Suppose that 15.0 mL of 0.15 M
(C2H5)2NH (Kb 6.90 x 10-4) is titrated
with 0.10 M HCI.
What is the pH after the addition of 15.0
mL of 0.10 HCl?
Calculate the pH at the midpoint.
Calculate the pH at the equivalence
point.
What is the pH if 1.5 mL of HCl is added
past the equivalence point?
Qualitative Analysis
Entropy
Few notes:
S=0 if reaction is reversible
S>0 for a spontaneous process if its S system
+ Ssurroundings
S is a state function.
Redox
How to determine whether youre in
an acidic or basic environment
If its a metal ion thats not group 1 or if
its already an acid its probably in an
acidic environment
If its a metal oxide, metal hydroxide, or
an anion then its probably in a basic
environment
Electrochemistry
Which of the following is characteristic
of the anode in an electrolysis cell?
a) It is where reduction occurs.
b) It attracts negative ions.
c) It receives electrons from the wire.
d) It may gain weight during
electrolysis.
e) More than one of the above is
correct.
Kinetics
Reaction Rates
Zero Order
First Order
Second Order
Half Lives
18-32
The enzyme catalase catalyzes the
decomposition of H2O2 to H2O (l) and
O2 (g). Use the following data,
determine the value of Rmax and
Km, the Michaelis-Menten constant.
[H2O2]0/mmol
*L-1
1.0
2.0
5.0
R/mmol*L-1*s-1
1.38
2.67
6.00
[H2O2]0/mmol
*L-1
1.0
2.0
5.0
R/mmol*L-1*s-1
1.38
2.67
6.00
2 0
R/mmol*L-1*s-1
1.38
2.67
6.00