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Speaker:
Dr. Nalini
Sankararamakrishnan
Centre for Environmental
Science and Engineering,
Indian Institute of Technology Kanpur
Worldwide Arsenic
Contamination
of Groundwater
Distribution of Arsenic
Contamination of Groundwater in
South Asia
Bangladesh*
18
64
89,193
148,393
68
125
0.01
0.01
64
59
38,865
126,134
42.7
75
13,137
78,500
Remediation
Options
Existing wells
Alternative sources
New wells
As removal
Well switching
Shallow wells
Surface wate
Deep wells
Pond water
Dug wells
Seasonality
Pathogens
Criteria (Cost-Benefit
Analysis)
Technica
l
Financia
l
Criteria (Cost-Benefit
Analysis)
Environmental
Technica
l
Financia
l
Environmen
tal
Financial /Economic
* Low cost
* Supports local economies
* Self-sustaining
Technical
Water quality evaluations
WHO Guidelines
National Standards
Flow rate
Use local materials
Social
Socially acceptable
Simple/user friendly
Convenient
Durable
Co-Designing/Co-evolving for
Development
(an iterative process)
10.
Reiteration
1. Problem Awareness
Co(m)-passion, and
Partnership
2. Problem CoDefinition
9 Scale-up
8.
Co-designing/
co-evolving
equitable and
Implementation
sustainable
development
7. Pilot studies
6. Refined Design
(Field and lab
testing, multiple
sites, multiple
countries)
3. Idea CoGeneration
4. Concept
Co-Evaluation
5. Field Experience,
Fabrication,
Experiment, Lab
Work, Analysis
Problem Co-Definition
To design a household drinking water treatment unit to
remove arsenic and pathogens;
Technical Performance: Remove arsenic, bacteria and
parasites to National Standards or WHO Guidelines;
Water Quantity: The flow rate should be > 10 L/hour;
Cost: The cost/unit should be < Rs. 1500. Yearly
replacement parts < Rs. 200, designed for use by
individuals in rural areas and urban slums who earn <Rs.
200/day;
Socially acceptable: ease of use and maintenance by
women
Taste
may
not
acceptable to many users
be
Construction
relatively high
cost
is
Basic Requirements
Adequate Rainfall
-Intensity of Rainfall
-Reliability of
Rainfall
Distribution of Rainfall
Suitable Catchment area
Storage Tank
Operation and
Maintenance
Treatment Of Arsenic
Contaminated Water
Major Treatment Processes
Oxidation and Sedimentation
Coagulation and Filtration
Aluminium Alum
Iron salts
Naturally Occurring Iron
Sorptive Filtration
Activated Alumina
Granulated Ferric Hydroxide/Oxide
Metallic Iron/ Iron Ore
Synthetic Composite Active Materials
Ion Exchange
Membrane Filtration
Nano Filtration
Reverse Osmosis
Oxidizing Reactions
H3AsO3 + O2 = H2AsO4-+ 2 H+
H3AsO3+ HClO = HAsO4--+ Cl-+ 3H+
3H3AsO3 + 2KMnO4 = 3HAsO4--+ 2MnO2++ 2K++ 4H++
H2O
In situ remediation
In situ remediation
Formation of insoluble
Incorporation of soluble
into a growing metal hydroxide
phase;
Adsorption:
arsenic to
insoluble metal
Filtration:
filtration
Separation of precipitates by
through a medium.
Relative Affinity
PO4> SeO3> AsO4> AsO3>> SiO4> SO2> F >
B(OH)3
The
second bucket has an
and
filtration
inner bucket with slits on
the
sides
to
help
sedimentation and keep the
filter sand bed in place.
The chemicals form visible large flocs when mixed (by stirring
with a stick).
Clean water is collected through a plastic pipe fitted with an
outlet covered with a cloth filter to prevent the entry of sand.
Activated Alumina
and
Sono3-Kalshi
[ Iron Fillings]
Flakes
Granules
Fibers
Advantages and
Disadvantages
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