Nomenclature of Compound

Complex
Inorganic Chemistry3

GROUP 1 :
AFIF TRIBAWONO ( 1301489)
DINAR KHAIRUNISA (1307218)
RAAFI SUHARTI ( 1300445)
WIDI SRI MULYANI (1307220)

Nomenclature
compounds
before 1930

of

complex

1. discoverer(Magnus salt , Gmelin compound , and

Zeise salt)
Vauquelin Salt : [Pd(NH3)4] [PdCl4]
Magnus Salt
: [Pd(NH3)4] [PtCl4]
Gmelin Compound : [Co(NH3)6]2(C2O4)3
Zaise salt
: K[PtCl3(C2H4)].H2O
Prusia Blue (prusia blue)
: KFe[Fe(CN)6].H2O
Luteo Complex (yellow) : [Co(NH3)6Cl]Cl2
2. Color
( Complex
Prussian(green)
blue , :luteo
,
Praseo
[Co(NHcomplex
3)4Cl2]

complex praseo )

Nomenclature of complex
compounds

The name and number of the existing

ligands as well as the name of the central
atom and its degree of oxidation
[Fe(NH3)4(CN)2]NO3 tetramindisianobesi(III)nitrat

The name and number of ligands , the

name of the central atom and the charge of
the existing complex
[Fe(NH3)4(CN)2]NO3 = tetramindisianobesi(+1) nitrat

Naming Ligands
(based on charged)
neutral ligand
negative ligand
Positive ligand (not common)
Writing ligand: Usually the donor atom is written section
front, except for a few ligands; H2O, H2S, and H2Te

Neutral
ligands are
given
the
same name
as
the
uncoordinate
d molecule,
but with
spaces
omitted.
Some
neutral
molecules,
when
serving
as
ligands are
given special
names.
These are:

Anionic
ligands
are given names
that end in the
letter o. When
the name of the
free, :
When the name
of
the
free,
uncoordinated
anion
ends
in
ide, the ligand
name is
changed to end in
ido.
Some
examples are:

uncoordinated
anion ends in
ate,
the
ligand n ame
is changed to
end in ato.
Some
examples are

Ligands are often abbreviated name

Mention sequence
Ligands
Name the ligands first, in alphabetical
order, then the metal atom or ion.
(Holtzclaw dan
Robinson,1988:769;IUPAC,1994 :151)

 The sequence suggested that the ligand mention

of the alphabet used as a basis in the order
mentioned ligand is the ligand name after
Indonesianized.
The amount of ligand that is expressed by the
prefix in, tri, tetra, etc.

 If the prefix has been used to refer to the existing

number of substituents on the ligand, the amount
of ligand expressed by prefixes bis, tris, tetrakis,
and so on.
Ligand consisting of two or more atoms written in
parentheses
examples:
[Co(en)2Cl2]+
ion bis(etilendiamin)diklorokobalt(III)

Nomenclature Neutral Complex Compound

1) Name of neutral complex compounds written in
one word.
2) Write or mention the name and number of
ligands
3) Write or mention the name of the central atom
and the oxidation state of the central atom is
written in Roman numerals. And the oxidation
number of the central atom zero price does not
need to be written

 Cation complex compounds

Cation complex compounds nomenclature as
ion complex follow this rules:
1) Beginning with writing or mention the word ion
2) Write or mention the name and number of
ligand-owned
3) Write or mention central atom name followed
oxidation number is written in Roman
numerals.
Besides the above nomenclature can be write in
the following way :
1) Beginning with writing or mention the word ion
2) Write or mention the name and number of
ligand-owned
3) Write or mention the name and the charge of
the complex ion that is written in Arabic

 Name of anion Complex

Expressed with ion followed by
the name and number of ligands,
the name of the central atom in
Latin ending by -ium -um or
replaced with -at as well as the
oxidation state of the central atom
is written with Roman numerals
(---- Arabic numbers)

 Ionic complex compounds composed of

cations and anions. One can be a
complex ion.
Ionic complex compound name written
in two words, first called the name of
the cation, followed by the name of the
anion
examples:
=> diamminesilver (I) chloride, [Ag(NH)2]
Cl
=> potassium hexacyanoferrate (III),
K3[Fe(CN)6]

Complex
compound that
have isomer
Nama senyawa ditambah dengan
awalan yang menyatakan isomer
misalnya : -cis, -trans, fac, mer dll
Nomenclatur of the compound

Cisdiamminedichloroplatinum
(II)

Transdiamminedichloroplatinum (II)

fac-[Ru(H2O)3Cl3]

mer-[Ru(H2O)3Cl3]

fac-triaquotrichlororutenium
(III)

mer-triaquotrichlororutenium
(III)

Nomenclature of complex
compounds with ligands
bridge
bridging ligand is a ligand donor atoms can bind two
or more atomic centers
ligands bridge should not the same compound

[(NH3)5Cr-OH-Cr(NH3)5]Cl5
Ion -hidroksobis-[pentaaminakromium(III)
Ion -hidroksobis-[pentaaminakromium(+5)

nomenclature of complex
compounds with ligands
bridge

[(MeCN)2Li(-I)2Li(NCMe)2]
-iodobis[diasetonitrillitium(I)]

nomenclature of complex
compounds with ligands
bridge

[(NH3)4Co(-NH2)(-SO2)Co(NH3)4]
Ion-amiso-sulfonilbis[tetraaminakobal(II)]

Complex compounds with

Polydentate ligands
Complex ion [Co(en)3]3+
contains
three
ligands
ethylenediamine.
The
complex
ions
formed
octahedral
coordination
structure with atoms of
cobalt (III) as the central
atom
Tris(ethylenediamine)cobalt(III)

Compound Complex with two

of the central atom bind to
each other

[Br4Re-ReBr4]2-

ion bis [tetrabromorenat(III)(Re-Re) atau

ion bis[tetrabromorenat(Re-Re)(2-)]
[(CO)5Mn-Mn(CO)5]
bis(pentakarbonilmangan)(Mn-Mn)
[(CO)4Co-Re(CO)5]
pentakarbonil(tetrakarbonilkobaltio)renium (CoRe)

Unsaturated ligand name

was given the prefix N- (Hapto), while the number
of atoms involved in the system is not saturated
expressed numerically rank the prefix n-, 5prefix is used when there are 5 atoms involved in
the system is not saturated as the ligand C5H5
(cyclopentadienyl). If there are two atoms
involved in the system is not saturated used early
N- or 2-.
examples:
Cis - [Pt (NH3)(C2H4) Cl2].
Cis-amina(-etilena)dikloroplatina(II).

Meta-losena
Complex bis (n5-cyclopentadienyl)
metal complex is also called metalosena
M = Fe :ferosena

Mn
: manganosena
Co :kobaltosena
Ni :nikelosena
Groups existing branches are numbered at
the lowest price. The carbon atom in the
first ring are numbered 1 to 5, while on the
other ring are numbered 1 'to 5'.

Polimer Complex
Compound

[Pt(NH3)2Br3]n

Katena-poli[diaminedibromoplatina(III)- - bromo

[ZnCl2(NH3)]n

Katena-poli[(aminaclorozink(II)) - kloro]

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