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EXTERNAL EFFECTS
Temperature, catalysts, and changes in
concentration affect equilibria.
The outcome is governed by LE
CHATELIERS PRINCIPLE
EQUILIBRIUM AND
EXTERNAL EFFECTS
Henri Le Chatelier
1850-1936
Studied mining
engineering.
Interested in glass
and ceramics.
Temperature Effects
on Equilibrium
N2O4 (colorless) + heat
2 NO2 (brown)
Ho = + 57.2 kJ
22
[NO
]
[NO22 ]
K
Kcc
[N
[N22O
O44]]
Kc = 0.00077 at 273 K
Kc = 0.0059 at 298 K
Copyright (c) 1999 by Harcourt Brace & Company
All rights reserved
NH3
Production
N2(g) + 3 H2(g)
2 NH3(g)
K = 3.5 x 108 at 298 K
Copyright (c) 1999 by Harcourt Brace & Company
All rights reserved
no change
in K only the position of
equilibrium changes.
Le Chateliers Principle
Le Chateliers Principle
Le Chateliers Principle
Le Chateliers Principle
ButaneIsobutane
Equilibrium
butane
[isobutane]
[isobutane] 2.5
K
=
K =
2.5
[butane]
[butane]
isobutane
Butane
Isobutane
isobutane
Butane
Isobutane
Butane
Isobutane
[isobutane]
1.25
[isobutane]
1.25
Q
== 0.63
Q ==
0.63
[butane]
0.50
[butane]
0.50 ++ 1.50
1.50
Butane
Isobutane
[isobutane]
1.25
[isobutane]
1.25
Q
== 0.63
Q ==
0.63
0.50
1.50
Q is LESS[butane]
THAN K. Therefore,
reaction will
[butane]
0.50 ++the
1.50
shift to the ____________.
Butane
Isobutane
Butane
Isobutane
Butane
Isobutane
Butane
Isobutane
[isobutane]
[isobutane]
K
=
2.50
=
K = 2.50 =
[butane]
[butane]
1.25
1.25 ++ xx
2.00
2.00 -- xx
Butane
Isobutane
[isobutane]
[isobutane]
K
=
2.50
=
K = 2.50 =
[butane]
[butane]
1.25
1.25 ++ xx
2.00
2.00 -- xx
x = 1.07 M
At the new equilibrium position,
[butane] = 0.93 M and [isobutane] = 2.32 M.
22
[NO
]
KKc == [NO22 ] == 0.0059
at
298
KK
0.0059
at
298
c
[N
[N2O
O4 ]]
2 4