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MANOJ KUMAR
III Semester
ME
Continued.
HYDROPHOBIC EFFECT
The hydrophobic effect represents the
tendency of water to exclude non-polar
molecules. The effect originates from
the disruption of highly dynamic
hydrogen bonds between molecules of
liquid water.
www.ramehart.com/contactangle.htm
Continued..
poor
Hydrophobic interactions
Hydrophobic interactions describe the relations between water and
hydrophobes (low water-soluble molecules).
Hydrophobes are nonpolar molecules and usually have a long chain
of carbons that do not interact with water molecules.
The mixing of fat and water is a good example of this particular
interaction.
The common misconception is that water and fat doesnt mix because
the Van der Waals
forces that are acting upon both water and fat molecules are too weak.
Hydrophobic
interactions ChemWiki
G= H-TS
H=Small positive value
S=Large positive value
APPLICATIONS
A primary purpose of hydrophobic coatings such as polytetrafluoroethylene(PTFE)
or polyxylylene is to act as a barrier against water commonly seen in automobiles
Used in fabrication on metallic nano rod to prevent icing.
Its is widely used in aerospace industry for providing anti-icing
coating on the surface of the aeroplane .
Hydrophobic self cleaning glasses are installed in traffic sensor
control unit.
We induce hydrophobic recovery after plasma treatment, a
physical contact treatment (PCT).
Continued
HYDROPHILIC COATING
Hydrophilic coatings wet the surface
very easily, and maintain the wetness for
longer time. Thus, using hydrophilic
coatings eliminates the need for
additional lubricants.
Hydrophilic Interactions
Interactions between water and other molecules such that the
other molecules are attracted to water are called hydrophilic
interactions.
Molecules that have charged parts to them are attracted to the
charges within the water molecule.
This is an important reason why water is such a good solvent
Continued.
APPLICATIONS
Spray Painting
Film coating
Bio-Medical
r =1+2bh/p2
we can define two levels; namely, the top of the posts and the ground
on which they sit.
A second natural parameter is the ratio S between the top and
bottom surface areas, which is also the post density.
S = b2/p2
Qur D , Reyssat M
Phil. Trans. R. Soc.
A 2008;366:1539-1556
www.me.umn.edu/~lixxx099/EFRI_CAES/Research/texturing.ht
m
Wenzel state
The Second and simplest picture is the so-called Wenzel state
(figure the drop just follows the structures on the material
(Wenzel 1936).
This will affect both the wetting (the value of the equilibrium
angle, that is the one which minimizes the surface energy of the
drop) and the adhesion (characterized here by the value of the
contact angle hysteresis).
cos*=r cos
cos*= -1 + s(1+cos)
THANKS