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petroleum
Even though believer of organic origin of petroleum
agrees on its origin, they differ on the issues related to
The process of formation and the primary organic
constituents, i.e., marine / continental origin?
Quantity of present day petroleum as directly obtained from
hydrocarbon of living organisms or by the transformation of
hydrocarbon compounds into petroleum?
Nature of energy involved in the transformation? Viz.
biochemical action, heat and pressure, radioactivity,
catalytic phenomena, etc.
Theories of origin of
petroleum
Cosmic theory
Theories of origin of
petroleum
Theories of origin of
petroleum
Theories of origin of
petroleum
Origin of petroleum
Criteria for a sedimentary rock to be effective oil
source rock
TOC content > 0.4%
Elemental carbon: 75 90% (< 75% - immature;
> 90% due to advanced catagenesis)
Bitumen : TOC > 0.05
Kerogen should be of amorphous or oil prone type
rather than of structured or gas prone type
Vitrinite reflectance (RO) > 0.6 and < 1.3
H : C and O : C atomic ratios of kerogen residues
should be favourable. Principle phase of oil
formation occurs at an H : C between 0.84 and 0.69.
Initial crude
Product
Thermal
evolution
Paraffinicnaphthenic oil
Paraffinic oil
Alteration
(Degradation)
Paraffinic &
Paraffinicnaphthenic oil
Aromatic- naphthenic
(<1% S)
Aromaticintermediate oils
Aromatic- asphaltic
oils (>1% S)
Natural Gas
Natural gas consists of HC not condensable
at 20C (68F) and atmospheric pressure
These are the first four members of the
paraffin series (methane through n-butane)
Gas composed almost entirely of methane is
dry gas; if the proportion of ethane (C2H6) and
heavier molecules exceeds some arbitrary
value (conventionally 0.3 US gallons of
vapour / cubic feet of gas, or between 4 and
5%, in North America), the gas is called wet
gas
Natural Gas
Natural gases consisting largely or
wholly of methane may have any one of
three distinct origins
Petroleum gas: formed as a byproduct
of the generation of petroleum
Associated gas: accompanies oil
Non-associated gas: no longer accompanies
oil; formed by the thermocatalytic modification
of petroleum
Natural Gas
Bacterial gas: formed by the low-temperature
alteration of organic matter at or near the
earths surface
The amount of gas in solution increases with
increasing reservoir pressure, and exerts
great effect upon the oils physical
properties. This is also responsible for many
oil wells to flow their oil to the surface
without artificial assistance
If the gas content is sufficient to saturate the
oil under the existing conditions, the amount
unable to go into solution forms a free gas
cap above the oil
H 2S
Gases high in H2S occur typically in carbonatesulfate reservoirs and also contain higher than
normal concentrations of N & CO2
H2S Concentrations exceeding 100 ppm in gas/oil
Dangerous as it is highly corrosive to drilling
equipment, particularly in deep well with high
temperature
North American Basins (the Permian Alberta,
Tampico, and Reforma Campeche basin and Texas
Panhandle); Permian of Ural Volga region; Jura
Cretaceous of Aquitaine Basin in France 15 16
% H2S
Deep Smackover in Southeastern USA (Jurassic)
30 % routine, 80-90%
Deep carbonate reservoirs of Rocky Mt. Foothills
60-65% below 4000 m
Nitrogen
Nitrogen in crude oil is primarily related to the
asphalt content
0.2 % N considered high (as in Los Angeles,
Maracaibo (Venezuela), Tampico (Illinois) basins)
High N gases occur especially in Paleozoic strata
Up to 80 % San Juan Basin of New Mexico (He 3.0
7.5 % in addition)
Up to 90 % Eastern part of Rotliegendes (Western
Poland) Basin
Pennsylvanian gases 19 %
South Alberta gases 8 85 %
Pakistani gas field 28 % N + high CO2
Orenburg (USSR) Sour gas in the Permian
Reservoir (5.8 % N + 28 ppm Ar + 4.5 % H2S)
Oxygen Compounds
Oxygen compounds of definite structure in
crude oils are acids (in many fields in
southern USSR) and phenols
Natural gases may contain considerable
quantities of CO2
Paradox Basin in Utah (Carboniferous to
Triassic reservoirs) Up to 90%
Wyoming (Ordovician & Mississippian
carbonates) 80 %
Northern Mexico, Pakistan (some fields) ~
50 %
Organometallic compounds
Porphyrins are HC ring complexes containing N & a
metallic (V, Ni) nucleus
Porphyrin (traces 400 ppm in crude oils)
Correlation Index
Useful means of classifying oils on a
qualitative basis.
CI is a number whose magnitude indicates
certain characteristics of a crude oil
distillation
Paraffins: CI 0 (zero)
Benzene: CI 100
Lower the CI greater the concentration of
paraffins
Higher the CI greater the concentration of
naphthenic and aromatic HC
Viscosity of oil
Viscosity is the internal friction of a fluid, causing its
resistance to change of form. It is the ratio of stress to
shear per unit time; shear in liquid is not constant, but
is proportional to time
Viscosity = Force x Distance / Area x Velocity
MLT-2L / L2 LT-1 = ML-1T-1
CGS Unit Poise
Conventional Unit centipoise
[1 cP = 10-2 Poise, viscosity of water at 20C (68F)]
SI Unit mPas [1 cP 1 mPas]
Viscosity of oil
Saybolt Universal Second (SUS) number of
seconds needed for a steel ball to roll through a
standard volume of the fluid
SUS = viscosity in cP x 4.635 / relative density
Typical oil viscosities measured in SUS at STP are
from ~1000 to 50
Viscosity of oil
Viscosity vary directly with densities
Hence, viscosities of oil are a function of the number
of C atoms and of the amount of gas dissolved in
the oil
Viscosity of oil
Viscosities of light oils < 30 mPas
Typical values between 5.0 & 0.6 (gasoline) mPas
Heavy asphaltic oils 50,000 mPas (Miocene oil in the
Bolivar coastal field in western Venezuela)
Very heavy oil ~1,00,000 mPas (Cold Lake, Alberta)
>106 mPas (Athabasca)
HC having viscosities > 10,000 mPas are known as natural
tars
Pour Point
A useful indicator of viscosity of crude oils; the lowest temperature
at which the crude flows under prescribed, controlled conditions
Pour points > 40C (more than 100F) are relatively common among
crudes having high contents of paraffin wax
Middle eastern and African crudes flow at ~ - 36C
Oils with high pour points because of high wax contents have a
shiny appearance & are associated with formation waters with low
salinity
When oils with high pour point rise in the traps, their temperatures
are lowered and the waxes crystalise out, forming a residue of high
molecular weight paraffins & oil becomes lighter
Prolific basins in which the original oils were paraffinic and derived
oils, in younger strata are asphaltic include the Carpathian Basin
(Romania), & Niger delta basin (off Africa)
Pour Point
Both paraffinic & asphaltic crudes may undergo
prolific volatilization through surface or near
surface alteration that they become totally
dried-up, so viscous that they effectively solids.
The drying-up process is INSPISSATION.
Pour Point
Very waxy crudes
Uinta Basin (Western USA), Anaco trend (Eastern
Venezuela) Reconcavo Basin (Brasil), Mendoza Basin
(Argentina), Beatrice field (off Eastern Scottland),
Mangyshlak field (east of the Caspian Sea), several
fields in the Sirte Basin (Libya & Sudan); Remarkable
proportion of the fields in young sandstone reservoirs
in Eastern Asia & Australia, (many oils from West India
& Upper Assam Basin of North Eastern India contain 10
15 % wax), most crudes from China, Sumatra, and the
Gippsland off-shore basin in Australia.
Volume
Oil in reservoir contains dissolved gas, and the volume
of the solution depends upon the
formation gas-oil ratio
reservoir pressure
The gas that may be dissolved in oil under increasing
pressure increases the volume of the solution until the
saturation pressure (bubble point) is reached after
which the volume decreases with increased pressure
Volume
0.5 0.8 barrel of gas-free oil on the ground (stock
tank oil) may represent 1 barrel of oil in the
reservoir at the saturation pressure
The volume of liquid petroleum at constant pressure
increases with increasing temperature, but at a
much lower rate than gases
The solubility of gas in oil increases linearly with
pressure in accordance with Henrys law.
Heavy crudes have much less capacity to hold gas
Fluorescence
Fluorescence is observed under UV radiation (2537
3650 )
All oils exhibit more or less fluorescence (bloom)
Aromatic oils most fluorescent
Fluorescent colours of crudes range continuously from
yellow through green to blue
Fluorescence is used in the logging of wells to locate
oil showings in the cores, cuttings, and drilling mud
Fluorescence rapidly reduces by aging; this helps in
differentiating fresh oil from oil previously caught in the
drilling mud
Optical Activity
Most crudes have optical activity (the power to
rotate the plane of polarization of polarized light
Optical activity pertains to the presence of
cholesterin (cholesterol), an alcohol (C26H45OH)
Measured by a polariscope in degrees/mm
Average range 0 1.2 degrees
Plane rotated to the right dextrorotary
left levorotary
Odor
Paraffins, naphthenes, aromatics, S, H2S,
N-compounds have characteristics odor
Coefficient of expansion
For an increase in temperature of 1F for crude
oils, the coefficient of expansion varies between
0.00036 0.00096
For most crude oils 0.00040 to 0.00065
Average coefficient of expansion
Pennsylvania crude oils 0.000840
Baku crude oils 0.000817
Heavier crude oils (lower API) lower
coefficient & vice-versa
Calorific value