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Clean Steel
SANTOSH KUMAR
MGR(SMS)
NINL
1
Contents
1. Introduction
2. Inclusion assessment
3. Inclusion Source & Control
4. Inclusion Modification
5. Conclusion
Introduction
1. Introduction
Steel cleanliness is the one unifying theme in all steel
1 Definition
1.1 Definition
Non-Metallic Inclusion: Non-metallic inclusions are
drawing
Nitroge
n
Oxygen
Surface
defects
Phospho
rus
Anisotropy
Sulfur
Fatigue
Bending
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3 Type of Inclusion
1.3 Type of Inclusion
Oxides: FeO, Al2O3, SiO2, MnO,
Cr2O3etc.
Sulfides: FeS, MnS, CaS, MgS,
Ce2S3etc.
Oxysulfides: MnS*MnO, Al2O3*CaS,
FeS*FeO etc.
Carbides: Fe3C, WC, Cr3C2, Mn3C,
Fe3W3C etc.
Nitrides: TiN, AlN, VN, BN etc.
4 Size of Inclusion
1.4 Size of Inclusion
Micro Inclusion: 1-100 m
Beneficial as they restrict grain growth, increase yield
strength and hardness
Act as a nuclei for precipitation of carbides and nitrides
MacroInclusion:>100 m
Harmful in nature so must be removed
C<30, N<40,TO<20
20
Tire Cord
10
15
100
N<40, TO<15
20
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Product
Automotive Sheet &
Deep drawing sheet
Ball Bearings
Line pipe
Wires
Heavy plate
100
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5 Morphology of Inclusion
1.5 Morphology of Inclusion
Globular shape
Platelet shaped
Dendrite shaped
Polyhedral Shaped
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5 Morphology of Inclusion
1.5 Morphology of Inclusion
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5 Morphology of Inclusion
1.5 Morphology of Inclusion
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5 Morphology of Inclusion
1.5 Morphology of Inclusion
6 Properties of Inclusion
1.6 Properties of Inclusion
Thermal Expansion:
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6 Properties of Inclusion
1.6 Properties of Inclusion
Density & Melting Point:
Compound of
Inclusion
FeO
MnO
SiO2
Melting Point(oC)
1369
1785
1710
Density at 20oC
(g/cm3)
5.8
5.5
2.2-2.6
Al2O3
2050
4.0
CrO2
2280
5.0
TiO2
1825
4.2
ZrO2
2700
5.75
(FeO)2.SiO2
1205
4.35
FeS
MnS
MgO
988
1620
2800
4.6
4.04
3.58
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6 Properties of Inclusion
1.6 Properties of Inclusion
Plastic Deformability:
Calcium aluminates and Al2O3 inclusions in steel are undeformable at temperatures of interest in steelmaking
Spinel type double oxide AOB2O3 are deformable at
temperature greater than 1200oC
(where A is Ca,Fe(l),Mg, Mn & B is Al, Cr )
Silicate are deformable at higher temperature.
FeO, MnO are plastic at room temp but gradually lose
plasticity above 400oC
Mns is highly deformable at 1000oC but slightly less
deformable above 1000oC
Pure silica is not deformable upto 1300oC
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0 Inclusion Assessment
2.0 Inclusion Assessment
Inclusion counts are performed to assess their
Image acquisition by
SEM
scattered
Back
Inclusion
electron
counting mode
by
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image analysis
0 Inclusion Assessment
2.0 Inclusion Assessment
0 Inclusion Assessment
2.0 Inclusion Assessment
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0 Inclusion Assessment
2.0 Inclusion Assessment
0 Inclusion Assessment
2.0 Inclusion Assessment
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2 Inclusion Formation
3.2 Inclusion Formation
There are three stages of inclusions formation:
1. Nucleation
Nucleiformedasaresultofsuper-saturationofthesolutionwiththesolutes
Thenucleationprocessisdeterminedbysurfacetensionontheboundary
inclusion-liquidsteel.
Thenucleationprocessismucheasierinthepresenceofotherphase(other
inclusions)inthemelt.
2. Growth
Growthofaseparateinclusioncontinuesuntilthechemicalequilibriumis
achieved(nosuper-saturation).
veryslowprocess
3. Coalescence and agglomeration
Motionofthemoltensteelduetothermalconvectionorforcedstirring
causescollisionsoftheinclusions,whichmayresultintheir
coalescence(mergingofliquidinclusions)oragglomeration(mergingof
solidinclusions)
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3 Distribution of Inclusion
3.3 Distribution of Inclusion
Besides of the shape of non-metallic inclusions their
3 Distribution of Inclusion
3.3 Distribution of Inclusion
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3 Distribution of Inclusion
3.3 Distribution of Inclusion
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4 Control of Inclusion
3.4 Control of Inclusion
Inclusion can be controlled at:
a) During liquid steel processing stage
b) During solid state processing
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4 Control of Inclusion
3.4 Control of Inclusion
i)
4 Control of Inclusion
3.4 Control of Inclusion
iii) Control of inclusion during teeming of steel
Shrouding of molten steel stream in order to avoid reoxidation.
Proper selection of tundish flux
Segregation during solidification to be avoided
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0 Inclusion Modification
4.0 Inclusion Modification
Depends on application, Inclusion Modification
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inclusion
It should be able to modify the composition so that
it becomes liquid.
It should be able to modify the shape i.e sharp
edges and corner of inclusion to spherical.
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Ca/Al
Al2O3
CaO.2 Al2O3
Melting Temp
(oC)
2050
1727
CaO. Al2O3
1595
0.74
12CaO.7Al2O3 1400
1.27
3CaO.Al2O3
1527
2.22
CaS
MnS
2000
1620
---
-0.37
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40
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Conclusion
5. Conclusion
It not always important to remove the
THANK YOU
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