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Introduction to
Multicomponent Distillation
1
Calculation difficulties
Binary
problems:
straightforward
solution
Variable
Feed rate, F
L0/D or V/B or QR
9
Column pressure and Qcol = 0 are already specified.
Also assume column pressure is fixed and the column is adiabatic
neither
bottom
nor
distillate
Off-the-Shelf Solutions
Fortunately, numerical design packages, such
as Aspen Plus, Aspen Hysys /UniSim have been
developed to perform the rigorous solution of
multi-component distillation systems.
However, as a design engineer, one always
needs to know the underlying theory and
methods of calculation to enable one to make
decisions about the validity of these offthe
shelf packages and to verify the results.
Fractional recoveries
Key components
Non-key components
Splits distributing and
non-distributing systems
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FR i dist
FR i bot
Dx i dist
Fz F, i
Bx i bot
Fz F, i
Dx D, i
Fz F, i
Bx B, i
Fz F, i
FR i dist
1 FR i bot
FR i bot
1 FR i dist
Decreasing volatility
14
Relative volatility is defined as the ratio of the K values for two components,
which is trivial for a binary system.
The choice of the reference component depends upon the problem, but in
general it will be the HK component since it is less volatile than the LK
component.
18
propane
nbutane
npentane
nhexane
Designation
Light NonKey
Light Key
Heavy Key
Heavy NonKey
21
Designation
Non-Key
Light Key
Non-Key
Heavy Key
22
Designation
Light NonKey
Key
NonKey
NonKey
23
Missing Keys
Methane
Ethane
Ethylene
Propylene
Propane
Designation
Methane
Ethylene
Ethane
Propylene
Propane
Light Non-Key
Light Key
Non-Key
Heavy Key
Heavy Non-Key
28
Eqs. (5-2)
For a ternary system, Eqs. (5-2) can be written three times, but these
equations must add to give Eq. (5-1). Thus, only two of Eqs. (5-2) plus
Eq. (5-1) are independent
Summation rules
30
Ternary mixture
6 unknowns: B, D, x2,dist, x3,dist, x1,bot and x3,bot
5 equations only: 3 mass balances and 2 summation
rules
Energy balance and equilibrium relationships will add
extra variables (vapor mole fractions, condenser and
reboiler duties)
Thus, one cannot start out by solving external mass and
energy balance equations.
For stage-by-stage calculation, need to know all
compositions at one end of the column.
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33
34
each
feed
stage
or
side-stream
Saturated liquid. F =
1.0 kmol/h. Feed stage
is number 10 above
the partial reboiler, and
there are 19
equilibrium stages plus
a partial reboiler. A
total condenser is
used. p = 101.3 kPa.
Relative volatilities: ben
= 2.25, tol = 1.0, cum = 0.21.
L/D = 1.0.
Temperature profile
Temperature profile decreases
monotonically from reboiler to
condenser
Behavior similar to binary
distillation case
If temperature plateaus then
there is a pinch point in the
column
37
Composition profiles
benzene recovery in the
distillate was specified as
99%
Benzene is the LK, and
toluene is the HK.
Thus, cumene is the HNK,
and there is no LNK
38
Composition profiles
Composition profiles
Recovery of toluene in distillate 99%.
primary maxima
secondary maxima
Since there is an LNK, we would expect
the LK curve to show maxima; and
since there is an HNK, we would expect
maxima in the HK concentration profile
Figure 5-6. Liquid composition profiles for distillation of benzene (LNK), toluene (LK),
xylene (HK), and cumene (HNK). Feed is 0.125 benzene, 0.225 toluene, 0.375 xylene,
and 0.275 cumene. Relative volatilities: ben = 2.25, tol = 1.0, xy = 0.33, cum = 0.21
40
Sandwich component:
Tend to accumulate in the middle section of the
distillation column
Can cause column flooding and/or
development of a second liquid phase
the
The order of volatilities is: propane > n-butane > n-pentane > n-hexane
quite high
44
Eq. 5-9a,b
or
The fractional recovery of n-butane in the distillate can be used to
write
Eq. 5-10
Eq. 5-11
Eq. 5-12
Eq. 5-13
Eq. 5-14b
45
=
=
=
=
Then
Now the individual distillate mole
fractions are
Equation 5-15
Check:
Bottoms can be found from Eqs. (5-8b), (5-9a), (5-11), (5-12), and (5-14b). The results are
xC3,bot = 0, xC4,bot = 0.0031, xC5,bot = 0.7708, xC6,bot = 0.2260, and B = 1246.6. Remember that
these are estimates based on our assumptions for the splits of the NK
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