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Element
B
Boron
Al
Aluminium
Ga
Gallium
In Indium
49
Tl
Thallium
simple electron
config.
2,3
2,8,3
2,8,18,3
2,8,18,18,3
2,8,18,32,1
8,3
electron config.
[He]
2s22p1
[Ne]
3s23p1
[Ar]3d1
4s24p1
[Kr]4d10
5s25p1
[Xe]4f145d10
6s26p1
Atomic Wt.
10. 8
26. 98
69. 7
114. 8
204. 0
+3
+3
+1, +3
+1, +3
+1, +3
melting pt./oC
2300
661
30
156
304
boiling pt./oC
3659
2467
2400
2080
1457
density/gcm-3
2.3
2.7
5.9
7.3
11.9
atomic radius/ A
0.88
1.43
1.22
1.63
1.70
oxidation states
13
31
81
M3+ radius/ A
1st IE/ kJmol-1
na
0.57
0.62
0.92
1.05
801
577
579
558
589
2nd IE/kJmol-1
2420
1820
1980
1820
1970
3rd IE/kJmol-1
3660
2740
2960
2700
2870
11/24/16 2.04
electronegativity
1.61
1.81
1.76
3
1.80
Chemical Reactivity.
As previously mentioned, the ionization potential of Gp 13
elements decreases with increase of atomic number, hence the
chemical reactivity increases in the same direction (that is, with
increase of ionic size)
11/24/16
Reason
As one moves down the group, the atomic size of elements goes on
increasing whereas the ionization energy decreases. As a result, the
strength of M-O bond goes on decreasing accounting for the
increase in basic character down the group or conversely explains
the decrease in acidic character.
Aluminium and gallium hydroxides show amphoteric behavior.
10
H 3 BO3 100
C HBO2 red
heat
B2 O3
Orthoboric acid
Metaboric acid
Orthoboric acid H3BO3 behaves as a weak monobasic acid that acts, not
as a proton donor, but as a Lewis acid accepting OHOH
B
HO
OH -
HO
OH
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Triangular Planar
HO
OH
11
Boric acid and borates form very stable complexes with diols or
polyols. The acidity of boric acid is increased by complexing and
the addition, for example, of glycerol, allows the acid to be titrated
directly with NaOH.
3H3BO3
C
glycerol
O
B
O
pKa= 6. 84
B2H6 +6H11/24/16
2O 2B(OH)3 +6H2
13
silent
electric
discharge
B2 H6 +6HCl
B
H
The two bridge hydrogen atoms are in a plane perpendicular to the rest
of the11/24/16
molecule and prevent rotation between the two boron atoms.
14
H
N:
B
H
:N
..
B
H
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Borazine
H
-
BN+
H
C
C
H
Benzene
15
11/24/16
16
2s
2p
sp2
2s
2p
11/24/16
sp2
17
The B atom in the BX3 molecule can readily accept a lone pair of
electrons from a donor atom such as O, N, P or S.
11/24/16
18