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Titrations
pH
pH
Titration
titration.
2
Acid-Base Reactions
Strong acid + strong base
HCl + NaOH ----> SALT WATER
Acid-Base Reactions
Interpret Graphs
CH3COOH(aq) + NaOH(aq)
CH3COONa(aq) + H2O(l)
7
Interpret Graphs
Acid-Base Titrations
Additional NaOH is added. pH
increases and then levels off
as NaOH is added beyond
the equivalence point.
Acid-Base Titration
Section 18.3
You
You titrate
titrate 100.
100. mL
mL of
of a
a 0.025
0.025 M
M solution
solution of
of
benzoic
benzoic acid
acid with
with 0.100
0.100 M
M NaOH
NaOH to
to the
the
equivalence
equivalence point.
point. What
What is
is the
the pH
pH of
of the
the
final
final solution?
solution?
HBz
HBz +
+ NaOH
NaOH --->
---> Na
Na++ +
+ Bz
Bz-- +
+ H
H22O
O
Kb = 1.6 x 10-10
C6H5CO2H = HBz
10
11
QUESTION:
QUESTION: You
Youtitrate
titrate100.
100.mL
mLof
of aa
0.025
0.025M
M solution
solutionof
of benzoic
benzoicacid
acid with
with
0.100
0.100M
M NaOH
NaOHto
tothe
theequivalence
equivalencepoint.
point.
pH
pH at
at
half-way
half-way
point?
point?
Benzoic
Benzoic acid
acid
++ NaOH
NaOH
pH
pH at
at
equivalence
equivalence
point?
point?
pH
pH of
of solution
solution of
of
benzoic
benzoic acid,
acid, aa
weak
weak acid
acid
Acid-Base Reactions
QUESTION: You titrate 100. mL of a 0.025 M
solution of benzoic acid with 0.100 M NaOH to
the equivalence point. What is the pH of the
final solution?
the
conjugate base Bz- in the solution
AFTER the titration, then calculate pH.
This is a two-step problem
1.
2.
stoichiometry of acid-base
reaction
equilibrium calculation
12
STOICHIOMETRY
PORTION
M * V = mol
1. Calc. moles of NaOH reqd
(0.100 L)(0.025 M) = 0.0025 mol HBz
This requires 0.0025 mol NaOH
2. Calc. volume of NaOH reqd
0.0025 mol (1 L / 0.100 mol) = 0.025 L
25 mL of NaOH reqd
13
STOICHIOMETRY PORTION
3.
3. Moles
Moles Bz
Bz-- produced
produced == moles
moles HBz
HBz == 0.0025
0.0025 mol
mol
4.
4. Calc.
Calc. conc.
conc. of
of Bz
Bz-There
There are
are 0.0025
0.0025 mol
mol of
of Bz
Bz-- in
in aa TOTAL
TOTAL
SOLUTION
SOLUTION VOLUME
VOLUME of
of
125 mL
[Bz-]
14
Equivalence Point
15
Most
Most important
important species
species in
in solution
solution is
is benzoate
benzoate ion,
ion,
Bz
Bz-.-. ItIt will
will react
react to
to form
form the
the weak
weak conjugate
conjugate base,
base,
benzoic
benzoic acid,
acid, HBz.
HBz.
-10
Bz-- + H22O HBz + OH-Kbb = 1.6 x 10-10
[Bz--]
[HBz]
[OH--]
I
0.020
0
0
-x
+x
+x
0.020 - x
16
Acid-Base Reactions
2
2
x
-10
-10
Kb
b 1.6 x 10 = 0.020- x
17
QUESTION:
QUESTION: You
Youtitrate
titrate100.
100.mL
mLof
of aa
0.025
0.025M
M solution
solutionof
of benzoic
benzoicacid
acid with
with
0.100
0.100M
M NaOH
NaOHto
tothe
theequivalence
equivalencepoint.
point.
What
What is
isthe
thepH
pHat
at half-way
half-waypoint?
point?
pH
pH at
at
half-way
half-way
point?
point?
Equivalence
Equivalence
point
point
pH
pH == 8.25
8.25
Acid-Base Reactions
18
[HBz]
[HBz]
[H
[H33O
O ]
] =
=
Kaa
K
[Bz
[Bz ]]
19
Figure 18.7
Key Concepts
20
BIG
BIG IDEA
IDEA
Reactions
Chemists use acid-base reactions
to determine the concentration of
an acid or a base in solution.
21