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Petroleum Geochemistry
Lesson 06
Rock-Eval Pyrolisis
Rock-Eval
- Information of hydrocarbon potential.
- Specially the composition of kerogen
types.
- S1, S2, S3 Rock-Eval pyrolysis
parameters are derived from the areas
of the P1, P2, P3 peak respectively.
- A commercial instrument for the
anhydrous pyrolysis of source rocks and
sediments.
- Developed by the Institute Francais du
Petrol (IFP).
(a). S1
- Amount of hydrocarbons already generated
by source rock, in unit mg/g.
- This value are strongly affected by migrated
hydrocarbons and contamination.
(b). S2
(c). S3
- Amount of carbon dioxide released during
pyrolisis.
- It is proportional to the oxygen present in
the kerogen and is measured in mg/g.
Pyrolisis
- Process of heating a rock or kerogen
sample in the laboratory to generate
hydrocarbon by thermal decomposition.
- The heating can be either in the
presence of water hydrous pyrolisis or
the absence of water anhydrous
pyrolysis.
- Rock-Eval is commonly instrument which
performances anhydrous pyrolisis.
Potential
(Quantity)
TOC
(%)
S1
Poor
<0.5
<0.5
Fair
Good
0.5-1
1-2
0.5-1
1-2
S2
Bitumen
(ppm)
HC
(ppm)
<2.5
<500
<300
2.5-5
5001000
300600
5-10
10002000
6001200
12002400
>2400
V. Good
2-4
2-4
10-20
20004000
Excellent
>4
>4
>20
>4000
S2/S3
Atomic
H/C
Main product at
peak maturity
HI
>600
>15
>1.5
Oil
II
300-600
10-15
1.2-1.5
Oil
II/III
200-300
5-10
1.0-1.2
Oil/Gas
III
50-200
1-5
0.7-1.0
Gas
IV
<50
<1
<0.7
None
Descriptio TOC
n
(%)
Source
rock
2.60
S1
S2
S3
Tmax
(oC)
0.8
9
18.0
1
0.8
9
440
S3
PI
HI
OI
SOM
(mg/g)
0.0
5
69
2
34
2.0
S2
S1
HI = S2/TOC x 100
OI = S3/TOC x 100
PI = S1/(S1+S2)
Description
TOC
(%)
S1
Gilsonite
contaminati 4.25 2.13
on
S2
S3
Tmax
(oC)
23.8
5
1.71
427
PI
HI
SOM
OI
(mg/g)
0.08
56
1
40
S3
S1
S2
40.0
Description
TOC
(%)
S1
Out-of-place
15.0
hydrocarbon 2.85
5
s
S2
S3
3.48 6.95
Tmax
(oC)
421
PI
HI
OI
bimodal
S2
S3
S1
Description
TOC
(%)
S1
Diesel 1
15.2
contaminati 5.05
6
on
S2
S3
Tmax
(oC)
6.27
10.8
9
314
PI
HI
OI
bimodal S2
Description
TOC
(%)
S1
Diesel 2
18.8
contaminati 3.00
1
on
S2
S1
S3
11.9
4.65
3
Tmax
(oC)
439
PI
HI
OI
S3
S1
Atomic
H/C
1,50
Gas
increasing evolution
1,00
0,50
0
0,10
Atomic O/C
0,20
HYDROGEN INDEX
(HI)
S2/TOC x 100
S3/TOC x 100
Description
TOC
S1
S2
S3
Tmax
1950
Calcareous shale,
layered, dark-grey
3.54
1.77
23.81
1.21
422
1975
Calcareous shale,
massive, dark-grey
3.56
0.28
2.96
1.21
427
2007
1.04
0.04
0.55
2.43
0.09
0.56
0.62
432
0.38
0.05
0.25
0.51
432
0.61
3.61
4.08
0.12
415
0.52
0.04
0.14
0.45
422
2073
Calcareous shale, black,
shaly
2076
Calcareous shale,
medium grey
2090
Siltstone, brown (oily)
2146
Massive clay, medium
grey
Description
TOC
S1
S2
S3
Tma
x
PI
HI
OI
23.8
1
1.21
422
0.07
673
34
1.21
427
0.09
83
34
0.55
53
0.62
432
0.14
23
26
0.51
432
0.17
66
134
0.12
415
0.47
669
20
0.45
422
0.22
27
87
1950
Calcareous shale,
layered, dark-grey
3.54
1.77
1975
Calcareous shale,
massive, dark-grey
3.56
0.28
Massive shale,
medium grey
1.04
Calcareous shale,
black, shaly
2.43
Calcareous shale,
medium grey
0.38
Siltstone, brown
(oily)
0.61
2007
2073
2076
2090
2146
2.96
0
0.09
0.56
0.05
0.25
3.61
4.08
0.52
Massive clay,
medium grey
0.04
0.04
0.14