Académique Documents
Professionnel Documents
Culture Documents
Laser Ablation
In the laser ablation process, a pulsed laser vaporizes a
graphite target in a high-temperature reactor while an
inert gas is inserted into the reactor. Nanotubes develop
on the cooler surfaces of the reactor as the vaporized
carbon condenses.
Properties
Strength
Electrical
Thermal
Defects
One-Dimensional Transport
Toxicity
Strength Properties
Carbon nanotubes have the
strongest tensile strength of any
material known.
Tensile
It also hasYoung's
the
highest
modulus
Elongation at of
Material
Strength
Modulus (TPa)
Break (%)
(GPa)
elasticity.
~1 (from 1 to
5)
13-53E
16
Armchair
SWNT
0.94T
126.2T
23.1
Zigzag
SWNT
0.94T
94.5T
15.6-17.5
Chiral SWNT
0.92
SWNT
MWNT
Stainless
0.8-0.9E
150
~0.2
~0.65-1
15-50
Electrical Properties
Thermal Properties
All nanotubes are expected to be very good thermal
conductors along the tube, but good insulators laterally
to the tube axis.
It is predicted that carbon nanotubes will be able to
transmit up to 6000 watts per meter per Kelvin at room
temperature; compare this to copper, a metal well-known
for its good thermal conductivity, which transmits 385
watts per meter per K.
The temperature stability of carbon nanotubes is
estimated to be up to 2800 oC in vacuum and about 750oC
in air.
Defects
Defects can occur in the form of atomic
vacancies. High levels of such defects can
lower the tensile strength by up to 85%.
Because of the very small structure of
CNTs, the tensile strength of the tube is
dependent on its weakest segment in a
similar manner to a chain, where the
strength of the weakest link becomes the
maximum strength of the chain.
One-Dimensional Transport
Due to their nanoscale dimensions, electron
transport in carbon nanotubes will take place
through quantum effects and will only propagate
along the axis of the tube. Because of this special
transport property, carbon nanotubes are
frequently referred to as one-dimensional.
Applications
Nanotubes hold the promise of
creating novel devices, such as
carbon-based single-electron
transistors, that significantly smaller
than conventional transistors.
Quantum Computing
Nanotubes and other Fullerenes can
be filled with molecules that have
either an electronic or structural
property which can be used to
represent the quantum bit (Qubit) of
information, and which can be
associated with other adjacent
Qubits.
Health Hazards
According to scientists at the National
Institute of Standards and Technology,
carbon nanotubes shorter than about 200
nanometers readily enter into human lung
cells similar to the way asbestos does, and
may pose an increased risk to health.
Carbon nanotubes along with the majority
of nanotechnology, are an unexplored
matter, and many of the possible health
hazards are still unknown.
References
http://www.news-medical.net/news/22799.aspx
Chae, H.G.; Kumar, S. (2006). "Rigid Rod Polymeric Fibers".
Journal of Applied Polymer Science 100:791-802: 791.
doi:10.1002/app.22680.
Hong, Seunghun; Sung Myung (2007). "Nanotube
Electronics: A flexible approach to mobility". Nature
Nanotechnology 2: 207208. doi:10.1038/nnano.2007.89
Meo, S.B.; Andrews R. (2001). "Carbon Nanotubes:
Synthesis, Properties, and Applications". Crit. Rev. Solid
State Mater. Sci. 26(3):145-249: 145.
doi:10.1080/20014091104189.
Kolosnjaj J, Szwarc H, Moussa F (2007). "Toxicity studies of
carbon nanotubes". Adv Exp Med Biol. 620: 181204. PMID
18217344
Ebbesen, T. W.; Ajayan, P. M. (1992). "Large-scale synthesis
of carbon nanotubes". Nature 358: 220222.