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COMPOSITION
Adrian C Todd
Introduction
Depends on location.
What is Petroleum ?
What is Petroleum ?
In gaseous state
Natural Gas
In liquid state
Condensates
Petroleum oil
Crude oil
In solid state
Tar, Asphalts
What is Petroleum ?
Classification of Hydrocarbons -
Hager, Dorsey
Marsh gas
Gaseous
Petroleum
Fluid
Hydrocarbons
Natural gas
Crude oil
Mineral tar
Viscous
Bituminous
Asphaltite
Brea
Gilsonite
Solid
Cereous
Coal
Lignite
Subbituminous
Bituminous
Semibituminous
Anthracite
Kerogen
Bitumous shale
Petroliferous
Mineral Wax
Origins of Petroleum
SOURCE
MECHANISM
Gases
CH4 ( Bacteria)
Origins of Petroleum
MIGRATION
Origins of Petroleum
Various hypotheses
Depositional environment
Migration path
Compositions
Compositional model
a multicomponent description in terms of
hydrocarbons.
Compositional Model-Hydrocarbons
Chemistry of Hydrocarbons
Hydrocarbons
Aromatic
Aliphatic
Alkanes
(Paraffins )
Alkenes
Alkynes
Unstable
Cyclic Aliphatics
( Napthenes )
Chemistry of Hydrocarbons
Alkanes or Paraffinic Hydrocarbons
Largest series with open chain molecules and
saturated bonds.
Carbon a valence of 4
Formula
CnH2n+2
Iso Butane
CH3CH2CH2CH3
CH3CHCH3
B.Pt-31.1oF
CH3
B.Pt-10.9oF
Unsaturated Hydrocarbons
Termed olefins
Two types
alkenes
e.g ethylene
CH2=CH2
alkynes
e.g, acetylene
CH-CH
Stable Hydrocarbons
Paraffins
Napthenes
Aromatics
Napthene Series
Formula
CnH2n
Very stable
Aromatics
Aromatic-napthenic crudes
Asphalts
Not a series
Highly viscous to semi-solid brown-black
hydrocarbons.
Non-hydrocarbon compounds
Small in volume, less than 1%,can have significant influence on processing and
quality of products.
Sulphur: and associated products 0.04 - 5 wgt%. Include sulphur and hydrogen
sulphide which is very toxic. Mercaptans. On combustion produce undesirable
SO2and SO3.
Nitrogen: less than 0.1%. Complex compounds. Gaseous reduces thermal quality.
For the oil refiner the composition is the key to determine the
chemical products which can be extracted or processed from the
material.
Petroleum engineer wants as simple a description as possible to
determine physical properties as a function of T&P.
Compositional Model
Compositioanl description based
on paraffin
series, CnH2n+2
Described up to a limiting C
number. Components greater than
limiting C number are lumped
together as a C+ component
Compositional Model
Compositional Model
Reservoir fluid
C1 C2 C3 C4 C5 C6 C7+
Reservoir Development
Plan
Dynamic
Early agreement to
reservoir description
speeds development
Reservoir Description
Compositional Model
Reduced to 4 or 5 components.
General Analysis
Reservoir Fluid
Types
Condensate Gas
Heavy hydrocarbons dissolved
General Analysis
Refractive Index
Fluorescence