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Outline
Introduction
Motivation
Experiments
Results
Mechanism
Conclusions
Water
water unavailable for drinking; 1%
Fluoride contamination
19 states are
affected and
66.6 million
Approximately
220 million people are at
people are atrisk
risk
et.2012
al., 2008
Source: Amini
CGWB,
Minerals
Ex: Fluorspar (CaF2)
Industrial effluents
Water
Fish
1 2 mg/kg
Drinking water
Guideline value
Standard
F- concentration, cF
(mg/L)
World Health
Organization (WHO),
2011
1.5
Desirable limit
Permissible limit
1.5
Fluorosis
http://www.flickr.com/photos/indiawaterportal/4606099994/
https://1phil4everyill.wordpres
s.com/tag/dental-fluorosis/
http://www.drchetan.com/dentalfluorosis-clinical-features-treatment.html
Non skeletal
fluorosis (1
1.5 mg/L)
Dental
fluorosis ( 1
1.5 mg/L)
Complete
deformation and
paralysis ( > 4.0
mg/L)
Is fluorosis curable?
Any form of fluorosis is irreversible
With the use of F- safe water there is considerable
relief from pain
Methods of defluoridation
Precipitation and coagulation
Membrane processes
Adsorption and ion-exchange
Solar distillation
Condensing
glass cover
Water layer
Stable
colloidal
dispersion
Solar radiation
adsorbate
adsorbent
Flocs
Coagulant addition
Distillate
channel
Precipitated flocs
Sources: Ayoob et al., 2008; Maliyekkal et al.2010; Sampathkumar et al., 2010; Bhatnagar et al., 2011
Choice of adsorbents
Commercial activated alumina (AA)
Particle diameter, dp = 0.4 0.8 mm
Surface area, as = 200 m2/g
Hybrid nanosorbent
+
N(H3C) 3
N(H3C) 3
Dispersed hydrous
zirconium oxide
nanoparticles
Sources: Prof. Arup K SenGupta (Private communication); SenGupta and Padungthon, 2013; Padungthon et al., 2014;
Experimental setup
Parameter values
bed diameter, D = 18 mm
bed height, H = 10 cm
empty bed contact time, EBCT 5 minutes
pre-soaking in de ionised (DI) water for 24 h
Reject water
(SRW)
Normal water
(SNW)
F- water
(SFW)
pH
5.5
5.5
6.0
F- (mg/L)
Cl- (mg/L)
5
600
5
200
5
--
SO42- (mg/L)
200
50
--
HCO3- (mg/L)
1050
100
--
NO3- (mg/L)
200
100
--
Na+ (mg/L)
Ca2+ (mg/L)
400
300
70
110
6.1
--
K+ (mg/L)
Mg2+ (mg/L)
40
100
-20
---
Sources: Su and Suarez, 1997; Wijnja and Schulthess, 1999; Ryazanov and Dudkin, 2004; Ayoob et. Al., 2008;
ZrOOH2+ZrOOH + H+
ZrOOH ZrOO-+ H+
Equilibrium reactions with FZrOOH2+ + F-ZrOF + H2O
ZrOOH + F-ZrOF + OH Equilibrium reactions with NO3ZrOOH + NO3-ZrONO3+ OH-
Conclusions
Defluoridation of RO reject is possible but to a lesser extent
than SFW because of high concentrations of ions
Increase in the concentration of co-ions decreases Fadsorption drastically
HAIX has a better adsorption capacity than AA
HAIX also removes NO3- but to a lesser extent than to F Presence of HCO3- effects F- adsorption by competing for
sites rather than just changing the pH
Thank
you
Queries?
No adsorption of NO3- on AA
Possible reactions on AA
Equilibrium
reactions on alumina
AlOH2+AlOH + H+
AlOH AlO-+ H+
Equilibrium reactions with FAlOH2+ + F-AlF + H2O
AlOH + F-AlF + OH Equilibrium reactions with HCO3- and CO32AlOH + CO32-AlOCO2-+ OHAlOH + HCO3-AlOCO2-+ H+ + OHAlOH2+ + HCO3- AlOCO2- + H2O + H+
Sources: Su and Suarez, 1997; Wijnja and Schulthess, 1999; Ryazanov and Dudkin, 2004; Ayoob et. Al., 2008;
Donnan principle
Water
A+, B-
Resin
R-Na+
B-
(a)
Water
A+ , B -
Resin
R+ClA+
RNa
(b)
R+
Cl-
B-
A+
H2O
H2O
Nitrate contamination
Effect of soaking on AA
V/Vb
ts (h)
Guideline values
Standard
pH
NO3concentration, cN
(mg/L)
World Health
Organization
(WHO), 2011
No health based
guideline
50
Desirable limit
6.5 8.5
45
Permissible limit
6.5 8.5
45
Indian standards
(BIS), 2012