CLASSICAL METHODS OF

QUANTITATIVE ANALYSIS

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 Presented By:
ATIA TAHIR
Submitted to
Mam Naushaba, Mam Humaira & Mam Tooba.
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 ANALYSIS

QUANTITATIVE QUALITATIVE

1- Neutralization Reaction
2- Complex Formation Reaction
3- Precipitation Reaction
4- Redox Reaction
 Topic of my presentation include redox Reaction in this experiment I am
going to deal with the most Important redox Titration Method that is
IODOMETRIC TITRATION.

IODOMETIC IS OF TWO TYPE:-

1st Type Iodimetry:-

The direct iodometric Titration Method refers to using iodine

as the oxidizing agent are called iodimetry.

2nd Type Iodometry:-

The indirect iodometric Titration method using iodide ion as

a reducing agent are called iodometry.
Chemical Reagents:
Chemical Name Chemical Formula State
Potassium Dichromate K2Cr2O7 Solid

Sodium thiosulphate Na2S2O3.5H2O Solid

Potassium Iodide KI Solid
Sodium Bicarbonate NaHCO3 Solid
Hydrochloric Acid HCl Solution
Sulfuric Acid H2SO4 Solution
Starch Solution

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 Primary Standard Substance:
K2Cr2O7

Secondary Standard Substance:-

Na2S2O3.5H2O
 Chemical Equations:
Standardization of Na2S2O3.5H2O:
Hydrolysis of K2Cr2O7 :
HO
2
1.K2Cr2O7 2K+ + Cr2O7-2
Reduction of Cr2O7-2 into Cr+3 :
2. Cr2O7-2 +14H+ +6e- 2 HO
2Cr+3 + 7H2O
Ionization of KI in Aqueous Solution:
3. KI K + + I-
Oxidation of I- :
4. 3(2I- I2+2e-
Balancing of No. of Electrons (in Equation 4)
5. 6I- 3I2 + 6e-
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 Net Equation (adding Equation 2 and 5 )
6. Cr2O7-2+6I-+14H+ 2Cr+3+7H2O+3I2
Ionization of Na2S2O3.5H2O in aqueous Solution:
7. Na2S2O3.5H2O 2Na+ + S2O3-2 + 5H2O
Oxidation of S2O3-2 :
8. 2S2O3-2 S4O6-2+2e-
Reduction of I2 :
9. I2+2e- 2I-
Net Equation (adding 8 and 9)
10. I2+ 2S2O3-2 2I-+S4O6-2
 Analysis of sample solution:
Ionization of H2O2 in aqueous solution:
11.H2O2 H2O 2H + + O2-2
Reduction of O2-2 into H2O:
12.4H + + O2-2 + 2e- 2H2O
Oxidation of I- into I2 :
13. 2I- I2+ 2e-
Net Equation (adding 12 and 13)
14. 4H + + O2-2 + 2I- I2+ 2H2O
Reaction of NaHCO3 with HCl:
15. NaHCO3 + HCl NaCl +CO2+ H2O
 OBSERVATIONS:-
Weight of K2Cr2O7= xg/100.0ml
Molar mass of K2Cr2O7= 294.1918g/mol
Weight of Na2S2O3.5H2O= yg/250ml
Molar mass of Na2S2O3.5H2O= 248.1826g/mol
Weight of Sample= zg
Atomic Weight of H2O2= 34.0147g/mol

STANDARDIZATION OF NA2S2O3.5H2O SOLUTION

Volume of standard K2Cr2O7=10.0ml
Indicator: Starch
Volume of Na2S2O3.5H2O Solution Consumed:
 S No Initial Final Difference Concordant
Reading Reading

ml ml ml ml
1 a b c c
2 b d c

ANALYSIS OF SAMPLE SOLUTION:-

Volume of Sample Solution=10.0 ml
Indicator: Starch
Volume of Standard Na2S2O3.5H2O consumed:
S No Initial Final Difference Concordant
Reading Reading

ml ml ml ml
1 d e f
2 e g f f
 PROCEDURE
STANDARDIZATION OF Na2S2O3.5H2O
SOLUTION:
Take a known volume of standard K2Cr2O7 solution in
an iodometric flask. Add NaHCO3 along with 4M HCl.
Now Add KI and Cover the flask and keep in dark for 5
minutes.
Titrate the brown content of flask against
Na2S2O3.5H2O until it becomes pale yellow. Add
starch and titrate again until blue color turns sea
green.

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 Determination of molarity of prepared
standard K2Cr2O7 solution
Molarity of prepared standard K2Cr2O7= Weight of
K2Cr2O7 x 1000/ Molar mass x Volume
Molarity of prepared standard K2Cr2O7= a x 1000
Molar mass x Volume
Molarity of prepared standard K2Cr2O7= p M

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 Determination of weight of Na2S2O3.5H2O to
prepare its q M
Weight of Na2S2O3.5H2O=Molarity x Molar mass x
Volume/1000
Weight of Na2S2O3.5H2O= q x Molar mass x
Volume
1000
Weight of Na2S2O3.5H2O= b g/250.0ml
 Standardization of prepared Na 2S2O3.5H2O
solution
1000ml standard K2Cr2O7 contains p mol of K2Cr2O7
1ml standard K2Cr2O7 contains p/1000 mol of K2Cr2O7
10.0 or 25.0ml standard K2Cr2O7 contains p x 10.0 or
25.0/1000 mol of K2Cr2O7 = r mol of
K2Cr2O7

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 1 K2Cr2O7= 6 Na2S2O3.5H2O
1mol of K2Cr2O7 reacts with 6 mol of Na2S2O3.5H2O
r mol of K2Cr2O7 reacts with 6xr mol of
Na2S2O3.5H2O = s mol
of Na2S2O3.5H2O
f ml of Na2S2O3.5H2O solution contains s mol of
Na2S2O3.5H2O
1ml of Na2S2O3.5H2O solution contains s/f mol of
Na2S2O3.5H2O
 1000ml Na2S2O3.5H2O solution contains s x1000/f mol of
Na2S2O3.5H2O = t mol of Na2S2O3.5H2O
So, the concentration of prepared Na2S2O3.5H2O=t M
Analysis of Sample Solution:
Determination of No. of mol of H2O2present in
sample solution:
1000ml of standard Na2S2O3.5H2O solution contains t mol
of Na2S2O3.5H2O
1ml of standard Na2S2O3.5H2O solution contains t/1000
mol of Na2S2O3.5H2O
j ml of standard Na2S2O3.5H2O solution contains j x t/1000
mol of Na2S2O3.5H2O = u mol of Na2S2O3.5H2O

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 2Na2S2O3.5H2O = 1 H2O2
10.0 or 25.0ml sample solution contains v mol of H 2O2
1ml of sample solution contain v/10.0or25.0 mol of
H2O2
250.0ml of sample solution contain v
x250.0/10.0or25.0 mol of H2O2 = w mol of H2O2

Determination of weight of H2O2 present in 250.0

ml sample solution
Weight of H2O2= No of mol of H2O2 x Molar mass of
H2O2
Weight of H2O2= w x 34.0146
Weight of H2O2= y g/250.0ml 21
 Result:
The no.of mol of H2O2 present in the given
sample solution is found to be W mol/250.0 ml.

The weight of H2O2 present in the given sample

solution is found to be Y g/250.0 ml.

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