HYDROGEN SULFIDE

In the Oilfield
OVERVIEW
General H2S
Information
API Guidance
BLM Onshore Order
#6
Other Regulations
DOT
EPA
 WHAT IS H2S
Colorless gas
Flammable

Heavier than air

Extremely toxic

Rotten egg smell

Deadens sense of
smell
 WHY DOES H2S OCCUR
Biological breakdown of organic matter in
an anaerobic environment
 HEALTH EFFECTS
Low concentrations (<10ppm)
irritation of eyes, nose, throat and
respiratory system
Moderate concentrations
(10<x>30ppm) headache,
dizziness, nausea, coughing,
vomiting and difficulty breathing
High concentrations (>30ppm)
shock, convulsions, coma, death
 EXPOSURE LIMITS
ACGIH TLV (8hr)= 10 ppm
OSHA ceiling (15 min)= 20 ppm

OSHA peak (instantaneous) = 50

ppm
IDLH = 100 ppm

ATSDR MRL = 0.07 ppm (acute),

0.03 ppm (intermediate)
OTHER PHYSICAL PROPERTIES
Explosive
Reacts with water to form Sulfuric Acid

Tears
Lungs
Reacts with iron/steel to form Iron Sulfide
(extremely flammable)
Iron sponge
Burns to form Sulfur Dioxide (toxic gas)
May lead to metal fatigue
H2S PRODUCTION
AMERICAN PETROLEUM INSTITUTE
Recommended Practice 49 -Recommended Practice
for Drilling and Well Servicing operations Involving
Hydrogen Sulfide
Applies to well drilling, completion, servicing, workover,
downhole maintenance and plug & abandonment
procedures.
Establishes location classifications
Addresses personnel training, monitoring equipment,
personal protective equipment, contingency planning and
emergency procedures.
Also establishes Sulfur Dioxide requirements
LOCATION CLASSIFICATIONS
No Hazard Area
Condition 1 Area low hazard
<10 ppm
Condition 2 Area medium hazard
>10ppm, <30 ppm
Condition 3 Area high hazard
>30 ppm
WARNING SYSTEMS
Condition 1 Area
warning sign with green
flag or light
Condition 2 Area - warning
sign with yellow flag or
light; visual and audio
alarms
Condition 3 Area warning
sign with red flag or light;
visual and audio alarms
MONITORING
Equipment
Manufacturer certified for H2S and SO2
Accurate in a range from well below to well
above action levels (H2S = 10 ppm, SO2 = 2 ppm)
Mixture of fixed and portable monitors as needed
to protect workers
MONITORING EQUIPMENT
Used during all activities where a potential of H2S
and SO2 to exceed action levels exists.
Located in the following areas:
Bell nipple
Mud return line or shale shaker
Pipe-trip tank
Drillers station
Living quarters
Other areas of potential accumulation
Calibrated and functionally tested per manufacturer
WARNING SYSTEM ACTIVATION
Typical 2 level alarm
10 ppm
20 to 300 ppm
TRAINING
All personnel working in an area with potential of
H2S and SO2 to exceed action levels exists.
Minimum topics;
Hazards, characteristics and exposure symptoms
Sources
Detection equipment, warning signs and wind direction
awareness
Workplace procedures, location of safety equipment and
location of safe breathing areas
PPE
Emergency response
CONTINGENCY PLAN
May be required by certain federal, state or local
agencies.
Must contain:
Facility specific description and maps
Monitoring equipment locations
Safety equipment locations
Safe breathing area locations
Evacuation routes
Training and drill requirements
Emergency response procedures
BUREAU OF LAND MANAGEMENT

Onshore Oil and Gas Order No. 6, Hydrogen

Sulfide Operations
APPLICABILITY
All onshore Federal and Indian oil and gas
leases.
Drilling, completing, testing, reworking,
producing, injecting, gathering, storing, or
treating operations.
Involving zones which are known or could
reasonably be expected to contain H2S
present in concentrations equal to or greater
than 100 ppm.
REQUIREMENTS
Written H2S Drilling Operations Plan
submitted with APD
Written Public Protection Plan submitted
with APD, notification of production or when
radius of exposure criteria are met
Training Program available for review upon
request
All plans and programs available at site
REQUIREMENTS
H2S Drilling Operations Plan
Site diagrams showing all safety equipment,
topography, exit roads, briefing (safe breathing)
areas, flare lines and pits
Appropriate well control equipment, personal
protective equipment, H2S monitoring
equipment, visual and audio warning system,
appropriate mud system, appropriate
metallurgical plan and means of communication
from wellsite
REQUIREMENTS

Public Protection Plan

Drilling or production site where:
The 100 ppm radius of exposure is greater
than 50 feet and includes any occupied
residence, scholl, church, park, school bus
stop, place of business or other are where the
public could be reasonably expected to
frequent
REQUIREMENTS

Public Protection Plan

Drilling or production site where:
The 500 ppm radius of exposure is greater
than 50 feet and includes any part of a
federal, state, county or municipal road
maintained for public use
REQUIREMENTS

Public Protection Plan

Drilling or production site where:
The 100 ppm radius of exposure is equal to
or greater than 3,000 feet and includes any
facility or part of a federal, state, county or
municipal road maintained for public use.
RADIUS OF EXPOSURE
Pasquill-Gifford derrived equation:
X = [1.589)(H2S concentration)(Q)]0.6258

X = radius of exposure
H2S concentration = decimal equivalent of the
volume fraction of H2S in the gas stream
Q = maximum volume of gas determined to be
available for escape in cubic feet per day
ESCAPE RATE (Q)
Gas production facility = maximum daily
absolute open flow gas production rate
Oil production facility = (gas/oil ratio of
production) (maximum daily production
rate)
Exploration well = use the above from
producing wells from the target interval in
the area
PUBLIC PROTECTION PLAN

Must include:
responsibilities of key personnel and institutions
for alerting the public and requesting assistance;
list of telephone numbers and names of
response agencies or contractors, residents,
those responsible for occupants of public
buildings and those responsible for safety of
public roadways;
a plat of the 100 ppm and 500 ppm radius of
exposure showing all private and public buildings
and roads;
emergency response measures
PUBLIC PROTECTION PLAN

May be required to
include: public
education seminars,
mass alert systems
(including
telephone,
commercial radio or
television), and
public input
allowances
 OTHER REGULATIONS
OSHA
Process Safety Management
DOT
Pipeline Safety Requirements
EPA
Risk Management Plan requirements
SARA Title 3 requirements
STATE SPECIFIC