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DivYesh Patel
DIAMAGNETISM
Diamagnetic materials create an induced
magnetic field in a direction opposite to an
externally applied magnetic field.
They are repelled by the applied magnetic field.
Shielding electrons
same
Electrons are added
in the Valence shell 2
same 1
0
Na Mg Al Si P S Cl
SHIELDING EFFECT
Down increases 7
Another layer of 6
electrons is added 5
and the shielding 4
between the valence Energy
Levels
3
shell and the nucleus
increases 2
0
F Cl Br I At
PAULI EXCLUSION PRINCIPLE
Reference: pg. 203
The Pauli Exclusion Principle states that each
electron (waveform) has a unique set of
quantum numbers
No two electrons can have the same values for
all quantum numbers
HUNDS RULE
If two or more degenerate (same
energy) orbitals are available, one
electron goes in each till they are all
half full
Hund's rule states that:
Every orbital in a sublevel is singly occupied
before any orbital is doubly occupied.
All of the electrons in singly occupied orbitals
have the same spin (to maximize total spin).
ORDER OF FILLING: THE AUFBAU
PRINCIPLE
This principle states that in addition to adding
protons and neutrons to the nucleus, one simply
adds electrons to the hydrogen-like atomic
orbitals
THE AUFBAU SHORTCUT: FOLLOW THE
RED ARROWS
Write the orbitals in columns as shown
Draw red diagonal arrows
Follow the arrows as you fill the orbitals
Name Date Contribution
A. van den Broek 1911 - Proposed that the atomic weight of an element was
approximately equal to the charge on an atom. This charge
could be used to number the elements with the periodic
table and later termed the atomic number.
Conclusions:
TRAJECTORY state descriptor of Newtonian physics,
EVOLUTION OF THE STATE Use Newton's second law
PRINCIPLE OF CAUSALITY Two identical systems with the
same initial conditions, subject to the same measurement will yield
the same result.
BASICS OF QUANTUM MECHANICS
- QUANTUM POINT OF VIEW -
Quantum particles can act as both particles and
waves WAVE-PARTICLE DUALITY
Quantum state is a conglomeration of several
possible outcomes of measurement of physical
properties Quantum mechanics uses the
language of PROBABILITY theory (random
chance)
An observer cannot observe a microscopic system
without altering some of its properties. Neither
one can predict how the state of the system will
change.
QUANTIZATION of energy is yet another
property of "microscopic" particles.
Photoelectric Effect
Einstein proposed that light delivers its energy in chunks; light consists of
little particles, or quanta, called photons, each with an energy of Planck's
constant times its frequency.
E=hf
h: Plancks constant
F: Frequency of Radiation h = 6.6 x 10-34 J.s.
E: Energy
ATOMIC SPECTRA
Objectives
1. Determine the emission spectrum of Hydrogen and other elements.
2. Calculate the expected wavelengths of H using the Rydberg equation.
3. Determine the composition of unknown solutions using flame tests.
4. Determine the absorption spectrum of colored solutions and solids.
Animation of the
dispersion of white
light as it travels
through a triangular
prism.
Original Studies Of Light Used Only One Prism
In fact, his main contribution was to show that after the sunlight
had been broken down into its components by one prism, if a
narrow ray of the light from the first prism was passed through
another prism there would be no further breakdown.
Classification of Electromagnetic Radiation
3. Measure the line spectrum of the gas tubes set up in Room 201.
4. Compare your results with literature values.
PART C: Flame Test (Organic Compounds)
Beilstein Test
If a clean copper wire is coated with a halogen-containing
compound and placed in a flame, the presence of the halogen
is revealed by a green to blue color.
Observe and record the color of the flame for each known sample.
Then determine the unknown compound based on the comparison
between its flame color and those of the known samples.
PART D: Absorption spectrum of colored solutions and solids.
Sample Solution
Which color
is being transmitted
by this sample?
Which color
is being absorbed
by this sample?
QUANTUM MECHANICS
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QUANTUM MECHANICS
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DE BROGLIE RELATION
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QUANTUM MECHANICS
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Lecture Outlines, 745
QUANTUM MECHANICS
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QUANTUM MECHANICS
rights reserved.
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In 1927, Davisson
and Germer was
demonstrated that a
beam of electrons,
just like X rays,
could be diffracted byPres
a crystal. entat
ion
of
Lect
ure
Outli
nes,
QUANTUM MECHANICS
h
(Dx)(mDvx )
4p
When m is large (for example, a baseball) the
uncertainties are small, but for electrons, high
uncertainties disallow defining an exact orbit.
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QUANTUM MECHANICS
Although we cannot precisely define an electrons
orbit, we can obtain the probability of finding an
electron at a given point around the nucleus.
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CLASSICAL WAVE EQUATION
1 u u 2 2
2 u ( x, t ) cos(2p t )y ( x)
v t
2 2
x
y 4p
2 2 2
y ( x) 0
x 2
v 2
y 4p
2 2
since v=l 2 y ( x) 0
x 2
l
y ( x) A cos(2p x / l )
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SCHRODINGER EQUATION
mv 2
E V ( x), rearrange to give mv={2m[E-V ( x)]}1/ 2
2
h h
de Broglie relation l
mv {2m[E-V ( x)]}1/ 2
2y 4p 2 2y 2m[E-V ( x)]
classical wave eqn. 2 y ( x) 2 y ( x) 0
x 2
l x (h / 2p ) 2
(h / 2p ) 2 2y
Schrodinger eqn. - V ( x)y ( x) Ey ( x)
2m x 2
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POSTULATES OF QUANTUM MECHANICS
Single valued
Continuous
Continuous first derivative
Quadratically integrable
Y Yd must be finite
*
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THE VARIATIONAL ENERGY
Evar
Eexact
Y*Yd
Schrodinger equation
(h / 2p ) 2 2 1 2
Hy Ey , H kx
2m x 2 2
y 0 ( x) exp( x 2 / 2),
p
1/ 4
y 1 ( x) (2 1/ 2 x) exp( x 2 / 2)
4p
1/ 4
y 2 ( x) (2 x 2 1) exp( x 2 / 2)
4ofpLecture
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HYDROGEN-LIKE ATOM
Nucleus with charge Ze at origin,
Electron with charge -e at (x,y,z) or (r, , )
Schrodinger equation for hydrogen-like atom
Hy Ey ,
(h / 2p ) 2 2 2 2 Ze 2
H x 2 y 2 z 2 4p r
2m 0
(h / 2p ) 2 2 2 1 Ze 2
H L2
2m r 2
r r 2mr 2
4p 0 r
2
1 2
L (h / 2p ) 2 cot
2 2
2 2
sin
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WAVEFUNCTIONS FOR HYDROGEN-LIKE
ATOMS
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WAVEFUNCTIONS FOR HYDROGEN-LIKE
ATOMS
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The wave function for
the lowest level of the
hydrogen atom is shown
to the left.
Letter K L M N ...
n 1 2 3 4
It
can have values from 0, 1, 2, 3, . . . to a
maximum of (n 1).
l 0 1 2 3 ...
Lette s p d f
r
n 1 2 3 4
95
Periodic Trends in EA
96
3. IONIZATION
ENERGIES
energy required to remove an electron
a gas phase atom in its electronic ground
M(g) M+(g) + e-
I1 > 0
first ionization energy
(photon)
M+(g) M2+(g) + eI- 2 >0
second ionization energy
M2+(g) 3+ -
M (g) + eI3 > 0
I1 > I2 > I3
d shell
insertion
IONIZATION ENERGY
IONIZATION ENERGY
Why?
2
Z
I . E. A
eff
2
n
2500
n=1
IONIZATION ENERGY(kJ/mol)
n=2
2000
n=3
1500
n=4
1000
500
0 0
11 2 133 144 155 166 177
2
18
8 9
GROUP NUMBER
1. closed shells are energetically most st
DERIVATION OF
IONIZATION
ENERGIES
noble gases have the highest ionization e
BASICS OF QUANTUM MECHANICS
- PARTICLE-WAVE DUALITY -
The behavior of a "microscopic" particle is very
different from that of a classical particle:
in some experiments it resembles the behavior of a
classical wave (not localized in space)
in other experiments it behaves as a classical particle
(localized in space)
Corpuscular theories of light treat light as
though it were composed of particles, but can not
explain DIFRACTION and INTERFERENCE.
Maxwell's theory of electromagnetic radiation can
explain these two phenomena, which was the
reason why the corpuscular theory of light was
abandoned.
BASICS OF QUANTUM MECHANICS
- PARTICLE-WAVE DUALITY -
Waves as particles:
Particles as waves
Double-slit experiment, in which instead of using a light source, one uses the
electron gun. The electrons are diffracted by the slit and then interfere in the
region between the diaphragm and the detector.
Aharonov-Bohm effect
VARIATION INCHEMICAL PROPERTIES
OF THE REPRESENTATIVE ELEMENTS
IE and EA enable us to understand types of
reactions that elements undergo and the types of
compounds formed.
GENERAL TRENDS IN CHEMICAL PROPERTIES
Hydrogen (1s1)
Grouped by itself
Phosphorus, P4
All diatomic
Do not exist in elemental form in nature
Form ionic salts
Form molecular compounds with each other
GENERAL TRENDS IN CHEMICAL PROPERTIES
Group 8A elements (ns2np6, n
2)
All monatomic
Filled valence shells
Considered inert until 1963
when Xe and Kr were used to
form compounds
No major commercial use
GENERAL TRENDS IN CHEMICAL PROPERTIES
Comparison of Group 1A and Group 1B
Elements
Have single valence electron
Properties differ
Group 1B much less reactive than 1A
High IE of 1B - incomplete shielding of nucleus by
inner d - outer s electron of 1B strongly
attracted to nucleus
1B metals often found elemental in nature
(coinage metals)
PROPERTIES OF OXIDES ACROSS A PERIOD