(Sensitization workshop for the Logistics, Warehouse and Procurement Department) By Ibrahim Dibal Public Health Engineering Assistant (Graduate Chemical Engineer From ABU Zaria) OUTLINE Introduction to chlorine. Common causes of chlorine incidents in the warehouse. Hazards associated with chlorine handling.. Chlorine storage and handling. Safety and signs in the warehouse. Introduction to Chlorine. Calcium hypochlorite Ca(OCl) for drinking water drinking water disinfection is most commonly encountered as ; Chlorinated lime or bleaching powder High test hypochlorite (HTH) Calcium hypochlorite in tablet form Both Chlorinated lime or High test hypochlorite (HTH) are both white powder in forms. Chlorinated lime or bleaching powder typically contains 20-35 per cent available chlorine. High test hypochlorite (HTH) typically contains 65-70 per cent available chlorine and it is more stable. Calcium hypochlorite is generally unstable and all forms lose potency with time. Common causes of chlorine incidents in the warehouse. Lack of awareness of the properties of the dangerous substances. Human error, due to lack of training and other human factors. Inappropriate storage conditions with respect to the hazards of the substances. Inadequate design, installation or maintenance of buildings and equipment. Exposure to heat from a nearby fire or other heat source. Poor control of ignition sources, including smoking and smoking materials, hot work, electrical equipment etc. Horseplay, vandalism and arson. Hazards associated with chlorine handling. Short-Term Health Effects Contact can severely irritate and burn the eyes and skin. Breathing Calcium Hypochlorite can irritate the nose, throat and the lungs causing coughing or shortness of breadth. Chronic Health Effects Repeated Exposure may cause bronchitis to develop with cough, phlegm and shortness of breath. Chlorine storage and handling. For chlorine handling the personnel has to have a Personal Protective Equipment (PPE); Body protection (Gloves and clothing) Eyes protection (Goggles) Respiration protection (Gas masks) For Storage; Chlorine-generating products should be stored in their original packaging. The recipient (container) should be air-tight, non-metallic or properly painted/enameled. Shelter these products from heat, light and humidity, and store them in restricted access areas (Chlorine is dangerous chemical especially for children). Never store chlorine-generating products together with organic matter, nor with combustibles because of high risk of fire or explosion. Storage places should be equipped with proper ventilation at ground level. Chlorine Safety Precautions. Any chlorine-generating product may be fatal if inhaled or swallowed. It is harmful if absorbed through the skin as it causes severe irritation. In case of contact with eyes, rinse immediately with plenty of clean running water and seek medical advice. Never mix Calcium Hypochlorite with anything but water. Never mix Calcium Hypochlorite with NaDCC because toxic and explosive gas may be generated. Chlorine reacts with metals, leading to a high chlorine consumption. Hence never prepare chlorine in metallic containers (unless properly enameled). Personal Protective Equipment Safety signs in the warehouse. PRACTICALS ON CHLORINE HANDLING
20 Minutes practical activity on chlorine handling.