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temu kesebelas
2013
Types of Metamorphic reactions
- With either progressing or retrogressing metamorphism,
various types of metamorphic reactions are proceeds e.g.:
1- Univarient reactions: reactions that plot as line or curve
on the P-T diagram and depend on temperature and
pressure only e.g:
Al2Si4O10(OH)2 Al2SiO5 + 3 SiO2 + H2O
Pyrophyllite Al-silicate + Qtz + fluid
Cont. Types of Metamorphic reactions
2- Divarient reactions: reactions
occur over wide range of P-T. This
because most minerals involved
in the reaction exhibit solid
solution (e.g garnet, mica,
plagioclase); therefore, the
reaction boundaries can changed
depend on the composition of
solid solution.
Calcite aragonite,
andalusite sillimanite,
Albite jadite + quartz
graphite diamond
Solid-Solid Net-Transfer Reactions
Differ from polymorphic
transformations: involve solids
of differing composition
Material must diffuse from one
site to another for the reaction
to proceed
4 (Mg,Fe)SiO3 + CaAl2Si2O8 =
Opx An Plag
Staurolite poikiloblast
Cont. Types of Metamorphic reactions
4- Dehydration reactions: reactions
that liberate H2O. This always occur in
the prograde reaction, i.e. with
increasing temperature e.g
chlorite + muscovite
orthoclase + andalusite +
H2O
Figure 26-5. T-XCO2 phase diagram for the reaction Cal + Qtz
= Wo + CO2 at 0.5 GPa assuming ideal H2O-CO2 mixing,
Figure 26-1. A portion of the equilibrium boundary for the calcite- calculated using the program TWQ by Berman (1988, 1990,
aragonite phase transformation in the CaCO3 system. After 1991). Winter (2001) An Introduction to Igneous and
Johannes and Puhan (1971), Contrib. Mineral. Petrol., 31, 28-38. Metamorphic Petrology. Prentice Hall.
Winter (2001) An Introduction to Igneous and Metamorphic
Petrology. Prentice Hall.
Cont. Types of Metamorphic reactions
-Sedimentary rocks
- Shales (Pelitic rocks)
- Sandstones (Arenaceous rocks and semipelitic rocks)
- Carbonate (Calcareous rocks)
- Marl rocks
- Igneous rocks
- Basic igneous rocks (metabasites)
- Ultramafic rocks
- Granitoid rocks
- Prior metamorphic rocks
Metamorphic Reactions
Isograds are reaction
lines
Exsolution
Some solid solutions
are unstable at lower
T, and exsolve as T
falls.