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Lecture 13
Dielectric Properties of
Ceramic Materials 1
1. Barsoum, Fundamental Ceramics, McGraw-Hill, 2000, pp.513–543
2. Richerson, Modern Ceramic Engineering, Dekker, 1992, pp.251–256.
3. Callister, Materials Science and Engineering- An Introduction.
Topics to discuss .......
Materials that are good insulator but are not inert to an applied
electric field are called dielectric materials.
The total charge that has passed through the circuit and is now
stored on the capacitor plates is given by the equation
Q = ò I dt
For different applied voltage V, the stored charge Q, which is
proportional to the applied voltage, can be written as
Q =CV
here the constant C is known as the capacitance and defined as
A
C
l
A
C = permittivity of the material between the plates
l
The relation between the
applied voltage V and the
stored charge Q is still
linear, but with a larger
slope than that for vacuum.
e
k¢ = It is a measure of how much charge a solid
can store relative to vacuum
e0
Since is always greater than 0, k’min = 1 when = 0.
k 0 A
A
C k Cvac
l l
To summarize,
éQ ù CV 0V
s vac = ê ú 0E
ë A ûvac A l
E = applied electric field
Q k 0V
die vac pol
A die l
pol = excess charge per unit surface area
present on the dielectric surface which occur
due to polarisation of dielectric
The polarization of the
dielectric, the surface charge D0 = 0 E
P = s pol
According to
electromagnetic theory, the
dielectric displacement D E=V/d
is defined as the surface
charge on the metal plate
D = e0 E + P D0 = 0 E + P
D = displacement (C/m2)
E = applied electric field, (V/m)
P = polarization (C/m2) of material
In vacuum, P = 0, and
D0 = e0 E
Thus, to summarize:
D = e0 E + P
D = e0 E + P k ¢e0 E = s vac + s pol
k ¢e0 E s vac + s pol
P = k¢e0 E - e0 E = k¢ -1 e0 E ( ) e0 E
=
s vac
s pol
P = c die e0 E k ¢ =1+
s vac
s pol
k ¢ -1=
s vac
Microscopic Approach
P =q d
If the total number dipole formed per unit volume is N, then the
total polarization
P = N m = Nqd
Fundamental equation to understand
P
a = C m2 V–1 or F m2
Eloc = local electric field
to which the atom/ion
N Eloc is subjected
For dilute gas as dielectric medium, the molecules are far apart,
for which Eloc = E, and
Na
k ¢ -1 =
e0
In solid dielectrics, polarization of surrounding media will affect
the magnitude of local electric field.
E
(
Eloc = k¢ + 2
3
)
Then, we have
k 1 N
k 2 3 0
Clausius–Mossotti Relation
which provide the link between the macroscopic
property k’ and the microscopic property .
(Only applies to linear dielectrics)
Polarization Mechanisms
Electronic polarization
Dipolar (or, orientation) polarization
Ionic (atomic) polarization
Space charge polarization
Electronic Polarization
Occurs in all dielectric materials.
Electrons surrounding each molecule are shifted/displaced very
slightly towards the +ve electrode, and nucleus to –ve electrode.
Very small polarization resulted, compared to those obtained by other
mechanisms.
Polarization disappears when electric field removed.
a e » 4p e 0 r0
3
Zi e
E= 0
+ S0
Electronic polarizability is d E
+ +
proportional to the volume
Z i me
of an atom or ion
(a) (b) (c)
Orientation or Dipolar Polarization
Electronic polarization
occurs very rapidly. So it
stays even at high
frequencies.
At very high frequencies,
none of the mechanisms
is capable of following
the field, and the relative
dielectric constant
approaches 1.0.
Temperature Effect