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Mass
Spectrometry;
Infrared
Spectroscopy;
Ultraviolet/Visible
Spectroscopy
The more stable the fragments, the more abundant they will be.
A peak at m/z value two units below the m/z value of the
carbocation is commonly observed.
3. The bonds most likely to break are the weakest bonds and
those that lead to formation of the most stable cation.
3075 sp2 CH
2950 sp3 CH
1650 and 890 terminal alkene with two substituents
absence of bands
1500–1430 and 720 fewer than four adjacent CH2 groups
© 2017 Pearson Education, Inc.
The IR Spectrum of Benzaldehyde
3050 sp2 CH
2810 and 2730 aldehyde
1600 and 1460 benzene ring
1700 partial single-bond character carbonyl
3300 OH group
2950 sp3 CH
2100 alkyne
3300 N—H
2950 sp3 CH
1660 amide carbonyl
1560 N—H bend
A=εcl
A = absorbance of the sample
The phenolate ion absorbs at 287 nm, but phenol does not.
© 2017 Pearson Education, Inc.
UV/Vis Spectroscopy Can Be Used
to Determine the Melting Temperature of DNA