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e-
+ +
or:
H+ (aq) + H2O (l) H3O+ (aq)
This new bond is called a coordinate covalent bond since
both new bonding electrons come from the same atom
Hydronium Ion
Hydronium ion is the name for H3O+ and is often times
abbreviated as H+ (aq) they both mean the same thing.
What is the difference between a strong acid and a weak
acid?
Hydronium Ion
Hydronium ion is the name for H3O+ and is often times
abbreviated as H+ (aq) they both mean the same thing.
What is the difference between a strong acid and a weak
acid? Strong acids ionize 100% and weak ones do not!
Hydronium Ion
Hydronium ion is the name for H3O+ and is often times
abbreviated as H+ (aq) they both mean the same thing.
What is the difference between a strong acid and a weak
acid? Strong acids ionize 100% and weak ones do not!
A single arrow is used to represent the ionization of a strong
acid. Double arrows (Equilibrium) are used to represent
weak acids.
For example: HCl (g) H+ (aq) + Cl - (aq)
HF (g) H+ (aq) + F -
Hydronium Ion
Hydronium ion is the name for H3O+ and is often times
abbreviated as H+ (aq) they both mean the same thing.
What is the difference between a strong acid and a weak
acid? Strong acids ionize 100% and weak ones do not!
A single arrow is used to represent the ionization of a strong
acid. Double arrows (Equilibrium) are used to represent
weak acids.
For example: HCl (g) H+ (aq) + Cl - (aq)
HF (g) H+ (aq) + F -
According to Arrhenius, is water an acid or base?
HOH (l) H+ (aq) + OH – (aq)
Hydronium Ion
Hydronium ion is the name for H3O+ and is often times
abbreviated as H+ (aq) they both mean the same thing.
What is the difference between a strong acid and a weak
acid? Strong acids ionize 100% and weak ones do not!
A single arrow is used to represent the ionization of a strong
acid. Double arrows (Equilibrium) are used to represent
weak acids.
For example: HCl (g) H+ (aq) + Cl - (aq)
HF (g) H+ (aq) + F -
According to Arrhenius, is water an acid or base?
HOH (l) H+ (aq) + OH – (aq)
Bronsted Lowry
e.g.
H2O (l) + H2O (l) H3O+ (aq) + OH- (aq)
This is called the self-ionization (autoionizaion) of water.
Although the equilibrium lies far to the left it is very important to
take into consideration, especially for living systems.
Does anyone know how we write the equilibrium constant for
this reaction?
Autoionization of Water
The auto-ionization of water is described by the
equation:
H2O (l) + H2O (l) H3O+ (aq) + OH- (aq)
The equilibrium constant for this reaction is given by:
[H3O ][ OH ] [H3O ][ OH ]
K
[H2O ][H2O ] [H2O ]2
K[H2O ]2 [H3O ][ OH ]
1.00 g mole ml
ml
= 55.5 M
18.0 g 10-3 L
As [OH-] and [H+] are so small the [H2O] is not affected by their
formation. It is useful to define a new constant Kw such that:
1.00 g mole ml
ml
= 55.5 M
18.0 g 10-3 L
pH = 16
pH = 12
pH = 7
[H+] = 10-2
pH = 2
A pH Number line
Number lines have been used in history and math classes,
so to keep up we use them in chemistry classes.
pH = 16
pH = 12
pH = 7
[H+] = 10-2
pH = 2 [OH -] = 10-12
A pH Number line
Number lines have been used in history and math classes,
so to keep up we use them in chemistry classes.
pH = 16
pH = 12
pH = 7
pH = 16
pH = 12
pH = 7 [H+] = 10-7
[OH -] = 10-7
pH = 16
pH = 12
pH = 16
[H+] =10-12
pH = 12
[OH -] = 10-2
pH = 16
[H+] =10-12
pH = 12 [H+] < [OH -]
[OH -] = 10-2
basic
[H+] =10-12
pH = 12 [H+] < [OH -]
[OH -] = 10-2
basic
[H+] =10-12
pH = 12 [H+] < [OH -]
[OH -] = 10-2
basic
[H+] =10-12
pH = 12 [H+] < [OH -]
[OH -] = 10-2
basic
[H+] =10-12
pH = 12 [H+] < [OH -]
[OH -] = 10-2
basic
2HCl (aq) + CaCO3 (aq) CaCl2 (aq) + H2O (l) + CO2 (g)
2HC l (aq) + Sr(HCO3)2 (aq) SrCl2 (aq) + 2H2O (l) + 2CO2 (g)
Equations With Acids
Bases undergo a double replacement reaction with acids
called neutralization:
1. NaC2H3O2
1. NH4Cl
Salts
Salts are the ionic product of an acid base neutralization
reaction.
Acidic Salts are formed from a strong acid and a weak base.
Neutral salts are formed from a strong acid and strong base.
Basic salts are formed from a strong base and a weak acid.
Give the acid and base the following salts were formed from
and label the salts as acidic, basic, or neutral.
3. NH4Cl
Salts
Salts are the ionic product of an acid base neutralization
reaction.
Acidic Salts are formed from a strong acid and a weak base.
Neutral salts are formed from a strong acid and strong base.
Basic salts are formed from a strong base and a weak acid.
Give the acid and base the following salts were formed from
and label the salts as acidic, basic, or neutral.
3. NH4Cl
Salts
Salts are the ionic product of an acid base neutralization
reaction.
Acidic Salts are formed from a strong acid and a weak base.
Neutral salts are formed from a strong acid and strong base.
Basic salts are formed from a strong base and a weak acid.
Give the acid and base the following salts were formed from
and label the salts as acidic, basic, or neutral.
3. NH4Cl
Salts
Salts are the ionic product of an acid base neutralization
reaction.
Acidic Salts are formed from a strong acid and a weak base.
Neutral salts are formed from a strong acid and strong base.
Basic salts are formed from a strong base and a weak acid.
Give the acid and base the following salts were formed from
and label the salts as acidic, basic, or neutral.
3. NH4Cl
Salts
Salts are the ionic product of an acid base neutralization
reaction.
Acidic Salts are formed from a strong acid and a weak base.
Neutral salts are formed from a strong acid and strong base.
Basic salts are formed from a strong base and a weak acid.
Give the acid and base the following salts were formed from
and label the salts as acidic, basic, or neutral.
3. NH4Cl
Salts
Salts are the ionic product of an acid base neutralization
reaction.
Acidic Salts are formed from a strong acid and a weak base.
Neutral salts are formed from a strong acid and strong base.
Basic salts are formed from a strong base and a weak acid.
Give the acid and base the following salts were formed from
and label the salts as acidic, basic, or neutral.
[H+] = ?
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
[H+] = 0.1
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
[H+] = 0.1
pH = ?
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
Ca(OH)2 (aq)
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
Ca(OH)2 (aq)
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
[OH - ] = ?
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
[OH - ] = 0.2
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
[OH - ] = 0.2
pOH = ?
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
[OH - ] = 0.2
pOH = - log[OH-]
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
[OH - ] = 0.2
[OH - ] = 0.2
[OH - ] = 0.2
[OH - ] = 0.2
NaF (aq)
Acid, Base, and Salt Hydrolysis
0.1 Initial concentration
Now react each of the ions with water. Cannot form strong
bases from weaker
Na+ + HOH NaOH + H+ ones, thus N.R.
s.b.
Acid, Base, and Salt Hydrolysis
HCl + NaOH NaCl + HOH
s.a. s.b.
NaCl (aq) Na+ (aq) + Cl- (aq) Neutral!
Now react each of the ions with water. Cannot form strong
bases from weaker
Na+ + HOH NaOH + H+ ones, thus N.R.
s.b.
Acid, Base, and Salt Hydrolysis
HCl + NaOH NaCl + HOH
s.a. s.b.
NaCl (aq) Na+ (aq) + Cl- (aq) Neutral!
Now react each of the ions with water. Cannot form strong
bases from weaker
Na+ + HOH NaOH + H+ ones, thus N.R.
s.b.
Now react each of the ions with water. Cannot form strong
bases from weaker
Na+ + HOH NaOH + H+ ones, thus N.R.
s.b.
Now react each of the ions with water. Cannot form strong
bases from weaker
Na+ + HOH NaOH + H+ ones, thus N.R.
s.b.
A buffer consists of a weak acid and the salt of its conjugate base,
or a weak base and the salt of its conjugate acid.
Examples:
HF + NaOH NaF + HOH
w.a. c.b.
Despite the possibility of pH increases or decreases, the body
maintains a nearly constant pH of 7.4. The body uses buffers to
maintain this remarkable feat.
A buffer consists of a weak acid and the salt of its conjugate base,
or a weak base and the salt of its conjugate acid.
Examples:
HF + NaOH NaF + HOH
w.a. c.b.
1.0 L
HF (g) NaF (s)
HF + OH- F- + HOH
Titration
Titration is an experimental procedure to
determine the concentration of an
unknown acid or base.
The figure on the left shows the
glassware for a titration experiment. A
buret clamp holds the buret to a ring
stand and below the buret is a flask
containing the solution to be titrated,
which includes an indicator. The
purpose of the indicator is to indicate
the point of neutralization by a color
change.
The picture on the left shows the
tip of a buret, with air bubble,
which is not good, and also shows
the stop-cock. Note the position
of the stop-cock is in the “off”
position. This picture shows the
color of the phenolphthalein
indicator at the end-point. In this
experiment a 23.00 mL aliquot of
0.1000 M NaOH titrant is added to
5.00 mL of an unknown HCL
NaOH + HCl NaCl + HOH solution. The acid solution in the
beaker starts out clear and
becomes pink when all of the HCL
has been consumed.
Titration
How can we calculate the concentration of acid
in the beaker?
Titration
How can we calculate the concentration of acid in the
beaker?
Normal procedure, yes, a conversion. Steps 1-4, again!
How can we calculate the concentration of acid in the
beaker?
Normal procedure, yes, a conversion. Steps 1-4,
again!
0.100 mole NaOH 10-3 L solution 23.00 mL soln mole HCl mL HCl soln.
L NaOH solution mL solution mole NaOH 10-3 L HCl soln.
How can we calculate the concentration of acid in the
beaker?
Normal procedure, yes, a conversion. Steps 1-4, again!
0.100 mole NaOH 10-3 L solution 23.00 mL soln mole HCl mL HCl soln.
L NaOH solution mL solution mole NaOH 10-3 L HCl soln. 5.00 mL
How can we calculate the concentration of acid in the
beaker?
Normal procedure, yes, a conversion. Steps 1-4, again!
0.100 mole NaOH 10-3 L solution 23.00 mL soln mole HCl mL HCl soln. =
L NaOH solution mL solution mole NaOH 10-3 L HCl soln. 5.00 mL
0.460 M HCl
Indicators
Indicators are weak organic (carbon containing) acids of
various colors depending on the formula of the acid.
Below is a generic acid.
HA H+ + A-
colorless pink
HA H+ + A-
colorless pink
1. Describe the color change when a strong acid is added? Less pink
2. Describe the color change when a strong base is added?
Indicators
Indicators are weak organic (carbon containing) acids of
various colors depending on the formula of the acid. Below is
a generic acid.
HA H+ + A-
colorless pink
1. Describe the color change when a strong acid is added? Less pink
2. Describe the color change when a strong base is added? Darker pink
Indicators
Indicators are weak organic (carbon containing) acids of
various colors depending on the formula of the acid.
Below is a generic acid.
HA H+ + A-
colorless pink
1. Describe the color change when a strong acid is added? Less pink
2. Describe the color change when a strong base is added? Darker pink
3. Describe the color change when the pH is lowered?
Indicators
Indicators are weak organic (carbon containing) acids of
various colors depending on the formula of the acid.
Below is a generic acid.
HA H+ + A-
colorless pink
1. Describe the color change when a strong acid is added? Less pink
2. Describe the color change when a strong base is added? Darker pink
3. Describe the color change when the pH is lowered? Less pink
Indicators
Indicators are weak organic (carbon containing) acids of
various colors depending on the formula of the acid.
Below is a generic acid.
HA H+ + A-
colorless pink
1. Describe the color change when a strong acid is added? Less pink
2. Describe the color change when a strong base is added? Darker pink
3. Describe the color change when the pH is lowered? Less pink
4. Describe the color change when the pH is raised?
Indicators
Indicators are weak organic (carbon containing) acids of
various colors depending on the formula of the acid.
Below is a generic acid.
HA H+ + A-
colorless pink
1. Describe the color change when a strong acid is added? Less pink
2. Describe the color change when a strong base is added? Darker pink
3. Describe the color change when the pH is lowered? Less pink
4. Describe the color change when the pH is raised? Darker pink
Color versus pH of Many Different indicators
How can we make an indicator?
How can we make an indicator?
Step One Step Two Step Three