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2018
February 9, St. John’s
by Vahit SAYDAM
1. Objectives
• Observe the melting and solidification characteristics of paraffin
wax in a helical coil heat exchanger energy storage under different
operational conditions.
• Determine the effects of HTF flow rate, flow direction and, inlet
temperature on charging and discharging tests.
• Experimental Setup
• Charging and discharging tests
– The effect of HTF flow rate
– The effect of HTF inlet temperature on charging
– The effect of HTF flow direction
4
Experimental Setup
(a) (b)
Figure 1: (a) Schematic of the experimental setup; (b) Positions of thermocouples; T1: Side
bottom, T2: Center bottom, T3: Center middle, T4: Center Top, T5: HTF Inlet, T6: HTF Outlet
5
Charging
80
70
60
Temperature, °C
50 Inlet
Outlet
40
Center Top
30 A B C
Center Middle
20
Center Bottom
10
Side Bottom
0
0 25 50 75 100 125 150 175 200 225
Time, min
D E F
Figure 2: Charging with a flow rate of 4 LPM Figure 3: Pictures of charging with a
at 75°C inlet HTF temperature flow rate of 4 LPM at 75°C (A:30 min,
B:60 min, C:90 min, D:120 min, E:145
min, F: 170 min)
7
Discharging
80
Inlet
70
Outlet
60 Center Top
Temperature, °C
50 Center Middle
40 Center Bottom
Side Bottom
30
20 A B C
10
0
0 100 200 300 400
Time, min
Figure 5: Pictures of discharging
Figure 4: Discharging with a flow rate of 1 LPM at with a flow rate of 1 LPM at 75°C (A:0
20°C inlet HTF temperature min, B:30 min, C:150 min)
8
70
60
Temperature, °C
50
40
30
75°C
20
70°C
10
0
0 25 50 75 100 125 150 175 200 225 250 275
Time, min
50
40 4 LPM
30 2 LPM
20 1 LPM
10 0.5 LPM
0
0 50 100 150 200 250
Time, min
60 1.5 LPM
Temperature, °C
50 1 LPM
40 0.5 LPM
30
20
10
0
0 50 100 150 200 250 300 350
Time, min
70
60
Temperature, °C
50
40
30
Upward flow, 4 LPM
20
0
0 20 40 60 80 100 120 140 160 180 200
Time, min
40
30
20
10
0
0 50 100 150 200 250 300 350
Time, min
Charging at 75°C,
3
downward flow
Discharging at 20°C,
2
upward flow
1 Discharging at 20°C,
downward flow
0
0 1 2 3 4 5 6 7
Flow rate, LPM
Figure 11: Comparison of charging and discharging times for different operational
conditions
14
3. Nano-enhanced Phase Change Materials (NEPCM)
A B C D E F
Figure 11: A: Paraffin wax, B: MWCNTs (6-9 nm in diameter and 5µm in length), C: Aluminum
oxide particles(<50nm particle size), D: Graphene nanoplatelets(lateral dimensions of about 2-3
𝜇). E: Sodium oleate, F: Octadecylamine.
16
Sample preparation
Figure 13: KD2 Pro Figure 14: 3-D printed Figure 15: Environmental Chamber (Tenney
Thermal Conductivity mold for measurements Junior Test Chambers, Model T30RC)
Analyzer(Decagon in solid phase
Devices)
18
Thermal Conductivity Measurements
Figure 16: Thermal conductivity change in liquid phase (60°C) over time after sample
preparation
19
Thermal Conductivity Measurements
Table 2: Phase change temperature and latent heat of fusion of paraffin wax with
various nanoparticles at different mass fractions.
Figure 22: Stability observation of various nanoparticles in paraffin wax with sodium oleate
24
Stability study-Effect of using surfactants on Stability
• Effect of using Octadecylamine on the stability of nanoparticles
over thermal cycles
Figure 23: Stability observation of various nanoparticles in paraffin wax with octadecylamine
25
Stability study-Effect of boundary conditions on Stability
• Effect of bottom heating on the stability of nanoparticles over
thermal cycles #C melting for
2h
solidifying solidifying solidifying solidifying
for 30 min for 60 min for 90 min for 120 min
0
Figure 24:Solidification of 0.1 wt.% MWCNT-wax sample after melting on a hot plate at 150°C
26
4. Conclusions
• HTF inlet temperature has the greatest effect on the charging time.
• Switching the flow direction from upward to downward did not have a
significant influence on charging due to uniform temperature along the helical
coil at high flow rates.
• Discharging tests were longer than the charging tests due to poor conduction
heat transfer performance of paraffin wax.
• Mechanical(stirring and sonication) dispersion and surfactant usage did not
help attain stable homogenously dispersed NEPCM samples over
melting/solidification cycles.
• The highest thermal conductivity enhancement was obtained for 2 wt. %
MWCNT-wax sample by 13% at 35°C. The insignificant overall improvement of
thermal conductivity is due to particle deposition and instability associated
with bad dispersion quality.
• DSC study of NEPCM samples showed anomalous latent heat capacity results
without any trend. However, the presence of nanoparticles did have a negative
effect on the supercooling issue.
27
References
• Khodadadi, J. M., Fan, L., & Babaei, H. (2013). Thermal conductivity enhancement of
nanostructure-based colloidal suspensions utilized as phase change materials for thermal
energy storage: A review. Renewable and Sustainable Energy Reviews, 24, 418-444.
• Das, S. K., Choi, S. U., Yu, W., & Pradeep, T. (2007). Nanofluids: science and technology. John
Wiley & Sons.
• Tang, Q., Sun, J., Yu, S., & Wang, G. (2014). Improving thermal conductivity and decreasing
supercooling of paraffin phase change materials by n-octadecylamine-functionalized multi-
walled carbon nanotubes. RSC Advances, 4(69), 36584-36590.
• Sidik, N. A. C., Mohammed, H. A., Alawi, O. A., & Samion, S. (2014). A review on preparation
methods and challenges of nanofluids. International Communications in Heat and Mass
Transfer, 54, 115-125.
• Michaelides, E. E. S. (2014). Nanofluidics: thermodynamic and transport properties. Springer.
• Korti, A. I. N., & Tlemsani, F. Z. (2016). Experimental investigation of latent heat storage in a
coil in PCM storage unit. Journal of Energy Storage, 5, 177-186.
• Kabbara, M., Groulx, D., & Joseph, A. (2014). Experimental study of a latent heat storage unit
with a helical coil heat exchanger. In CSME International Congress 2014, Toronto, Canada.
29
Acknowledgements
This research study was funded by NL Innovation Council and
National Research Council of Canada.
Thank you!