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OF AN ATOM
Instructor: Dr. Mehr Nigar
Classical Description of an atom
When r → 0 F(r) → ∞
F = m (dv/dt) = m(d2r/dt2)
For rinitial = 10 Å
r = 0 at t = 10-10 s!!!
Qualitatively the electron should plummet into the nucleus in 0.1 nano seconds!!!
Newtonian Mechanics? F = ma
Water Waves
Sound Waves
Amplitude, Wavelength and
Frequency:
Amplitude is defined as the deviation from the average level, it can be positive or
negative.
10 m x
12 m
1. 10 m
2. 12 m
3. 5m
4. 6m
Light Waves
At t = 0
At t = 1/f
(one period)
Long
Short
Wavelengths
Wavelengths
Low Frequencies
High
Frequencies
Applications of Flourescence
Fluorescent Paint
Quantum Dots
Frequency of the emitted light is proportional to the size of the quantum dot.
Superposition of Waves
Applications of Destructive
Interference
Noise Cancellation Headphones:
y = mx + b
Slope (m) = 6.626 x 10-34 Js
Planck had observed this number much earlier as a fitting constant to explain
Black body radiation.
Einstein’s Relations:
Einstein predicted that a graph of the maximum kinetic energy
versus frequency would be a straight line, given by the linear
relation:
KE = hf - Φ
…Therefore light energy comes in multiples of hv
Ei = K.E +
K.E = Ei -
If a beam of light with energy = 7.0 eV (1 eV = 1.602 x
10-19 J) strikes a gold surface, what is the maximum
kinetic energy of the ejected electrons.
1) K.E. = 12.1 eV
2) K.E. = 5.1 eV
3) K.E. = 1.9 eV
4) K.E. = 7.0 eV
5) No electrons will be ejected.
Ei = Incident Energy
If f f0 No electrons are ejected! f0 = threshold frequency
= Work Function
If f f0 Electrons are ejected!
Energy of a photon:
Energy of a photon must be equal to or greater than the work
function of a metal, for an electron to be ejected.
Each photon ejects a single electron, therefore the greater the number of incident
photons the higher the number of ejected electrons.
Intensity of light (energy/sec) is proportional to the # of photons emitted/sec.
High intensity means more photons/sec, Unit of Intensity = W = Js-1
NOT more E / photon
Summary of Terminology:
Photons: also called light, electromagnetic radiation, may be described in
terms of energy, or f.
E = 7.82 x 10-19J, the UV lamp does have enough energy to eject an electron from Zn surface.
E = 2.84 x 10-19J, the laser pointer does NOT have enough energy to eject an electron from Zn
surface.
3) What is the total number of photons emitted by the laser pointer in 60 seconds if intensity (I) =
1.00mW
# of photons emitted if the laser pointer is used for 60 s = 2.1 x 1017 photons.
K.E = Ei -
K.E = hc/ -
Solar Cells: act like a battery when exposed to light. Individual solar
cells produce voltages of about 0.6 volts but higher voltages and
large currents can be obtained by appropriately connecting many
solar cells together
Read more:
<a href="http://science.jrank.org/pages/5169/Photoelectric-Effect-
Applications.html">Photoelectric Effect - Applications</a>