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Suspended Growth:
• Activated sludge
• Oxidation ditch/pond
• Aerated lagoon, stabilization pond
Activated Sludge
Denitrification
NO3- + organics CO2 + N2
Process adaptations
Air
Anoxic Aerobic
Phosphate removal
BPR plants
Air
Wastewater
Anaerobi
Anoxic Aerobic
c
Excess biomass disposal
Production
Separation
Further biological treatment – (an)aerobic
Dewatering
Drying – solar or gas heated
Disposal/ beneficial use – soil amender/fertilizer
or fuel
The cost of biomass disposal amount to about half the cost of wastewater treatment.
Aeration, if used, almost up to half of the rest of the cost. If no aeration, the capital cost
, including the cost of land, could be very high.
Typical steps in modern wastewater treatment
Type of Activated Sludge
dX SX
X m
dt Ks S
dX dS
Y
dt dt
dS dX 1 m SX
so : .
dt dt Y Y ( K s S )
ACTIVATED SLUDGE WITHOUT CELL
RECYCLE
Mean Cell Residence Time, θc
Mean cell residence time (MCRT, θc) is the mass of cells in
the system divided by the mass of cells wasted per day.
Consider the system:
VX V
c
QX Q
For no recycle systems, θc = θh
At steady state, the amount of
solids wasted per day must equal
the amount produced per day:
VX VX X
c
dX dS dS
V Y V Y
dt dt dt
Mass Balance on Microorganisms:
Accumulation = input – output – process
dX dS
V QX o QX Y V k d XV
dt dt
In steady state condition (dX/dt) V = 0, and QX0 = 0
m SX
0 QX V k d XV dS
m SX
Ks S dt Y( Ks S )
dibagi VX
Q m S
0 kd
V Ks S
1 S K s ( 1 k d c)
m kd S
c Ks S c ( m kd ) 1
Ks
Jika kd diabaikan S
1
kd
m c 1
c
Example
A CSTR without cell recycle receives an influent with 600
mg/L BOD at a rate of 3 m3/day. The BOD in the effluent must
be 10 mg/L. The kinetic constants are: Ks = 500 mg/L and μm
= 4 days-1. How large should the reactor be?
Ks
S
m c 1
K s S 500 10
Solve for θc: c 12.75 days
S m 10 * 4
V
c
Q
V = θc Q = 12.75 (3) = 38.25 m3
Given the conditions in the previous example, What
would the percent reduction in substrate be if the
reactor volume was 24 m3?
V 24
c 8 days
Q 3
Ks 500
S 16.1 mg/L
m c 1 4 * 8 1
VX
c
Qw X r
X0 = Xe = 0
dX
kondisi stady state : V 0
dt
X r Qw 1
kd kd
XV c
The substrate removal velocity, q, can also be expressed as: q = μ/Y
S
since m
Ks S
By substitution: q 1 m S
Y Ks S
Since q = μ / Y c Y ( So S )
h
1 X 1 k d c
c
qY
1 Reactor volume:
kd
c c Y ( So S )
V Q
X 1 k d c
Solids Separation
• The success of the activated sludge process depends on the efficiency
of the secondary clarifier, which depends on the settling
characteristics of the sludge (biosolids).
• Some system conditions result in sludge that is very difficult to
settle. In this case the return activated sludge becomes thin (low
MLSS) and the concentration of organisms in the aeration tank goes
down. This produces a higher F/M ratio (same food input, but fewer
organisms) and a reduced BOD removal efficiency.
• One condition that commonly causes this problem is called bulking
sludge. Bulking sludge occurs when a type of bacteria called
filamentous bacteria grow in large numbers in the system. This
produces a very billowy floc structure with poor settling
characteristics.
Sludge Volume Index, SVI
(volume of sludge after 30 min. settling, ml) x 1000
SVI =
mg/L suspended solids
m SX h Y ( S o S )( K s S )
So S h
Y (K s S ) m SX
X = (S0 – S) / ( θh q )
= (300 – 15) / [0.129(0.28)] = 7890 mg/L
QSo V 1 m S
F c h kd
M V .X Q c K s S
• Mencari kd dan Y dari percobaan lab.:
( So S ) k d 1 1
slope
1
X h Y Y h (So S ) Y
X h
TANPA kd
intercept
RECYCLE Y
1
h
• Mencari Ks dan μm dari percobaan lab.:
h K 1 1
S s S Slope
1 k d h m m h
S
m
1 k
d h
Ks
intercept
m
S
2. DENGAN RECYCLE:
Qw X ( Q Qw ) X e
kd
VX
( So S ) kd 1 1
Y
(So S ) c Y ( So S ) X h Y Y c
X h h c Y ( So S )
X 1 k d c X
1 h 1 k d c
kd
c
1 m S
kd c K 1
S c Ks S S s S
m
Ks S 1 k d c m m
K s ( 1 k d c )
S
QSo V c ( m kd ) 1
F h
M V .X Q
• Mencari ke danY dari percobaan lab.:
( So S ) kd 1 1
slope
1
X h Y Y c (So S ) Y
X h
RECYCLE kd
intercept
Y
1
c
• Mencari Ks dan μm dari percobaan lab.:
c K 1 1
S s S Slope
1 k d c m m c
S
m
1 k
d c
Ks
intercept
m
S
Parameters Recycle Non-Recycle
Sludge age &
Equations of hydraulic residence V V
c h c h
ACTIVATED time Q Q
SLUDGE Hydraulic residence
PROCESS time c Y ( So S ) Y ( So S ) 1
h h
X 1 k d c kd X kd
Microorganism in
system c Y ( So S ) Y ( So S )
X X
h 1 k d c 1 k d c
Substrate in system
K s ( 1 k d c ) K s ( 1 k d c )
S S
c ( m kd ) 1 c ( m kd ) 1
Determining kd & Y
( So S ) kd 1 1 ( So S ) kd 1 1
X h Y Y c X h Y Y h
For recycle system, Determining Ks & m
c K 1 h K 1
if k d is ignored : S s S S s S
1 k
d c m m 1 k d h m m
Y ( S o S )( K s S ) F-M ratio
h QSo QSo
m SX F
M
F
M
V .X V .X
Recycle Ratio
R=Qr/Qo
Mass Balance at Junction
• Microorganism
Qo X o Qr X r ( Qo Qr ) X
Xo = 0
Qo Qr X r Qo X r Qr X
1 R
Qr X Qr X Qo X r X
• Substrate
Qo S o Qr S r ( Qo Qr )S e
Qo S o Qr S r
Se
Qo Qr
• Sludge Production
• Oxygen Requirement
Y’ = oxygen coeff, mass
OR Y' S R k' d VX On oxygen/mass substrate
utilized = 1 – 1,42 Y
kd‘ = endogenous respiration
coeff, mass oxygen/
mass cell-day = 1,42 kd
On = oxygen for nitrification
= mass N x 3.84
Soal-soal
• Suatu percobaan proses lumpur aktif dalam skala
laboratorium yang dioperasikan secara Batch, dengan
waktu aerasi 24 Jam dan diketahui nilai MLVSS = 70
% dari nilai MLSS. Hitunglah nilai Y dan kd dengan
acuan masa MLVSS. Data hasil percobaan :
No. Xo (MLSS) Xt (MLSS) So (BOD5) St (BOD5)
Reaktor (mg/L) (mg/L) (mg/L) (mg/L)
1 450 790 725 95
2 860 1160 725 89
3 1650 1960 725 77
4 3670 3875 725 70
Suatu kawasan pemukiman dengan jumlah penduduk 8000 jiwa dilayani dengan
sistem IPAL terpusat. Kapasitas air buangan sebesar 225 L/orang.hari dan rata-
rata BOD sebesar 425 mg/L. Konsentrasi NH3-N sebesar 25 mg/L dan teroksidasi
sebesar 95 %. Susunan sel C5H7NO2. Removal BOD pada pengendap I diperkirakan
sebesar 32 %. Jika diinginkan reaktor utama adalah proses Lumpur Aktif, dengan
nilai :
Y = 0,81 kg VSS/ kg BOD; ke = 0,07/hari ; Y’ = 0,73 kg O2/kg BOD;
ke’ = 0,16 kg O2/kg VSS; X = 2500 mg MLSS/L ; Xr = 10.000 mg/L
MLVSS/MLSS = 0,7, umur lumpur = 10 hari , waktu tinggal hidrolik = 8 jam.
Hitunglah :
• Konsentrasi BOD effluen.
• Produksi lumpur
• Kebutuhan Oksigen.
• Debit resirkulasi yang diperlukan
Air limbah industri rumah tangga diolah dengan Proses lumpur aktif.
Karakteristik air buangan dan Parameter perencanaan ditentukan sbb:
• Q = 6.000 m3/hari.