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Topics of Discussion
Carbohydrate classification
Carbohydrate chemistry (structure
and stereoisomer)
References
Modern Carbohydrate Chemistry (Roger W.
Binkey), Marcel Dekker,Inc
Carbohydrates in Food (Ann-Charlotte Eliason),
Marcel Dekker,Inc
Foods Experimental Perspectives (Margaret
McWilliams), Prentice Hall
Others:
http://www.chem.qmul.ac.uk/iupac/2carb/
(Nomenclature of Carbohydrates)
Food Theory and Applications (Jane Bowers),
MacMillan Publ. Co.
The Role of Carbohydrate
One of the most classes of chemical
compounds
The molecules in which energy from the sun
is stored by photosynthesis.
An essential structural component of living
cells; includes simple sugars with small
molecules as well as macromolecular
substances.
The Role of Carbohydrate
ALDOSES
CHO CHO CHO CHO CHO CHO
CH2OH CH2OH
ALDOSES
CH2OH CH2OH CH2OH CH2OH
KETOSES
=
H OH = HO H
C CHO C
HC HCOH HC
-D-glucopyranose -D-glucofuranose
( -D-glucose) ( -D-fructose)
CHO CH2OH
HCH2OH
HCOH C=O HOCH2 O CH2OH
HO O H
HOCH H HOCH
OH H H HO
HOCH HCOH H OH
H OH
HCOH HCOH
H OH OH H
CH2OH CH2OH
D-Galactose D-Fructose
Nomenclature
6
HCH2OH =D
In -D-glucopyranose, the H
5 O H
“pyranose” portion of the H
4 1
name refers to the pyranoid OH H
Stereochemistry at C1 is H
5 O H
H
given by 4 1
OH H
Prefix: “gluco” OH OH
3 2
If the configuration at H OH
=
C1 is inverted, -D-
-D-glucopyranose
glucopyranose is formed ( -D-glucose)
Nomenclature
6 O 1 CH2OH
A five-membered ring: HOCH2
furanose 5 2
H HO
The D designator H OH
specifies the 4 3
configuration at C5 (the OH H
Amylopectin
Structure of Amylopectin