Presentasi Tugas ATK II

Oleh:
Angga Ardianto
1431410103
Question 25.33
 A synthesis gas at 500°C that analyzes 6,4% CO2 , 0,2% O2 ,
40% CO, 50,8% H2 ,and the balance N2 is burned with 40%
excess air which is at 25°C. The composition of the flue gas
wich is at 720°C is 13% CO2 , 14,3% H2O, 67,6% N2 , 5,1%
O2. What was the heat transfer to or from the combustion
process?
500°C 720°C
6,4% CO2 13% CO2
0,2% O2
40% CO
50,8% H2
Burner 14,3% H2O
67,6% N2
5,1% O2
2,6% N2

25°C
40%
excess
dry air
Basis 100 grmol Feed
 CO2 = 0,064 x 100 grmol = 6,4 grmol
 O2 = 0,002 x 100 grmol = 0,2 grmol
 CO = 0,4 x 100 grmol = 40 grmol
 H2 = 0,508 x 100 grmol = 50,8 grmol
 N2 = 0,026 x 100 grmol = 2,6 grmol
Reaksi
 Reaksi I
CO + ½ O2 CO2
40grmol ~ 20 grmol ~ 40 grmol
 Reaksi II
H2 + ½ O2 H2O
50,8 grmol ~ 25,4 grmol ~ 50,8 grmol
 O2 untuk reaksi sempurna = (20+25,4)grmol
= 45,4 grmol
 O2 disupply = 45,4 grmol x 1,4
= 63,56 grmol
 O2 masuk burner = (0,2+63,56) grmol
= 63,76 grmol
 Udara disupply= 1/21 x 63,56 grmol
= 302,67 grmol
 N2 disupply = (302,67-63,56)grmol
= 239,11 grmol
 N2 keluar burner = (239,11+2,6) grmol
= 241,71 grmol
 CO2 keluar burner = (40+6,4) grmol
= 46,4 grmol
 HO2 keluar burner = 50,8 grmol
 O2 keluar burner = (63,76-45,4)grmol
= 18,36 grmol
ΔH25T (KJ/grmol) IN
Data a,b,c didapat dari Appendix E Tabel E.1
ΔH25T (KJ/grmol) IN
ΔH25T (KJ/grmol) IN
ΔH25T (KJ/grmol) IN
ΔH25T (KJ/grmol) IN
Feed

ΔH°f didapat dari Appendix F Tabel F.1

ΔHin
In with Air
 ΔH25T (KJ/grmol) OUT
Data a,b,c didapat dari Appendix E Tabel E.1
ΔH25T (KJ/grmol) OUT
ΔH25T (KJ/grmol) OUT
ΔH25T (KJ/grmol) OUT
Out with Flue Gas
ΔHout
ΔH Total
 ΔH= ΣΔHout – ΣΔHin
=((-22123,946)-(-5484,183)) KJ
= -16639,763 KJ