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CH15M040
M Tech
Advisor
Prof. S Ramanathan
Dept of Chemical Engineering
IIT Madras
Contents
Objective
Experiments
Results
Future work
References
Objective
To find Corrosion Resistance of SS304 using Electro Chemical Techniques
such as Tafel, EIS and Linear Polarization.
Results
potential, V
-0.1
Icorr = 4.2487 µA
Ecorr = -0.2700 V
-0.2 ba = 0.0100
bc = 8.5091
-0.3
-0.4
-0.5
-15 -10 -5 0 5
10 10 10 10 10
|i T|, A/cm2
Electrochemical Impedance spectroscopy
-12000
V-0.29
-10000
0.19
0.09
-0.01
-8000
-0.11
-0.21
-Z"Ω -cm2
-6000 -0.31
-0.41
-0.51
-4000
-2000
R(QR(CR))
Contd..
Q
Rsol Rp
Rct
C
0.19 564.458126
0.09 19248.50388
-0.01 23041.96173
-0.11 23073.66638
-0.21 10904.24054
-0.31 3718.373922
-0.41 1619.479983
-0.51 1050.152545
Rp Comparison using EIS and Linear Polarization
60000
50000
40000
Rp Ω-Cm2
30000
EIS_Rp
Linear Polarization Rp
20000
10000
0
-0.6 -0.5 -0.4 -0.3 -0.2 -0.1 0 0.1 0.2 0.3 0.4
Vdc, V
-10000
Corrosion Inhibitor Coatings
Trial 1
Trial 2
Duration: 1800 s
15 mm
15 mm
15 mm
15 mm
2 mm 2 mm 2 mm 2 mm
Contact angle
Corrosion Studies
Measurements
Tafel
EIS
Linear Polarization
Tafel and EIS of bare sample
Tafel_WO_bare Tafel_W_Bare
5
5
4 4
log(I), A
log(I), A 3 3
2 2
1 1
0 0
-1 -0.8 -0.6 -0.4 -0.2 0 0.2 0.4 -1 -0.8 -0.6 -0.4 -0.2 0 0.2 0.4 0.6
-1 -1
E, V
E, V
-2
-2
EIS_WO_Bare EIS_W_Bare
-12000.00
-12,000.00
-10000.00
-10,000.00
-8000.00
-8,000.00
-Z"Ω -cm2
-Z"Ω -cm2
-6000.00 -6,000.00
-4000.00 -4,000.00
-2000.00 -2,000.00
0 3,000 6,000 9,000 12,000 15,000
0.00 0.00
0 3000 6000 9000 12000
Z' Ω-cm2
Z' Ω-cm2
Future Work
An experimental study of crevice corrosion behaviour of 316L stainless steel in artificial seawater, Baoping
Cai, Yonghong Liu *, Xiaojie Tian, Fei Wang, Hang Li, Renjie Ji, 19 June 2010
Electrochemical corrosion characteristics of type 316L stainless steel in hot concentrated seawater, S.S. Xin,
M.C. Li , 15 December 2013
A Simple Process for Fabricating Organic/TiO2 Super-Hydrophobic and Anti-Corrosion Coating Chunyan
Mo1, Yansheng Zheng1,2,*, Falong Wang1,Qian Mo1, 28 July 2015
Thermal effect on superhydrophobic performance of stearic acid modified ZnO nanotowers, N. Saleema *, M.
Farzaneh, 11 October 2007
Solubility of Stearic Acid in Various Organic Solvents and Its Prediction using Non-ideal Solution Models,
Rudi Heryanto,a,b Masitah Hasan,a* Ezzat Chan Abdullaha and Andri Cahyo Kumoro a,c, 1 Aug 2007