The learners to: Determine if a molecule is polar or non-
polar given its structure . Specific & Learning Outcomes At the end of the lesson, the learners shall be able to: • Define electronegativity • Find the electronegativity of elements in the periodic table List of important terms that learners will encounter: •Electronegativity .Covalent bond •Valence electron . Miscible •Dipole . Immiscible Experiment Title: Polarity Experiment Materials: 1. Water 2. vinegar 3. Oil 4. Gasoline 5. Food coloring 6. Candle dye 7. Glass 8. Stirring rod Procedure • Mix the following samples well with a spoon and observe their reactions. Stir the mixture. • Adding color to the solutions will make it easier to see the different results. Be sure to use contrasting colors. 1. Water + vinegar 2. Water + oil 3. Water + gasoline 4. Oil + vinegar 5. Oil + gasoline •Samples with oil and gasoline should first be mixed with dishwashing liquid before disposing down the sink. •Why certain combinations mix better than others? •Group the samples together according to how well they mix. •Predict the results of the experiment as they mix oil and water. They should recall simple chores they do at home such as washing out oil from pans. •Introduce the two factors that determine the polarity of molecules. These are: •The polarity of the bonds between atoms which can be studied based on electronegativity, and •The geometrical shape of the molecule which can be predicted via the valence shell electron pair repulsion (VSEPR) theory. •Suggest that water and vinegar can be grouped together while oil and gasoline belong to another group. These substances can be classified as polar and non-polar substances. The difference in polarity explains why certain combinations mix and not others. Review Grade 9 chemistry discussions on properties of elements found in the periodic table such as boiling points, melting points, oxidation number. Point out that one of the properties found in the periodic table is the electronegativity of elements. • Electronegativity (EN) - Measure of the relative tendency of an atom to attract electrons to itself when chemically combined with another atom. The higher the value of electronegativity, the more it tends to attract electrons toward itself. • Polar covalent bonds occur when electron pairs are unequally shared. The difference in electronegativity between atoms is significant. Examples of compounds having polar covalent bonds are: • HCl EN of H = 2.1 EN of Cl = 3.0 ΔEN = 0.9 • HF EN of H = 2.1 EN of F = 4.0 ΔEN = 1.9 •Have the learners familiarize themselves with the periodic table. Let them find the EN value of several elements. Have them determine the most electronegative element and the least electronegative element. •Bond Polarity (20 minutes) The separation of charges makes the bond polar. It creates an electric dipole. Dipole refers to “two poles,” meaning there is a positive and a negative pole within a molecule. Elements with the higher EN value become the partial negative pole while elements with the lower EN value become the partial positive pole. This makes the molecule a polar molecule • Non-polar covalent bonds occur when electron pairs are shared equally or the difference in electronegativity between atoms is less than 0.5. Examples of substances having non-polar covalent bonds are: • H2 EN of H = 2.1 ΔEN = 0.0 ( NON-POLAR MOLECULE; not a dipole ) • Cl2 EN of Cl = 3.0 ΔEN = 0.0 (NON-POLAR MOLECULE; not a dipole) • F2 EN of F = 4.0 ΔEN = 0.0 ( NON-POLAR MOLECULE; not a dipole ) • HI EN of H = 2.1 EN of I = 2.5 ΔEN = 0.4 (POLAR MOLECULE; a dipole) Determine if the bond between elements are polar covalent or non-polar covalent. Seatwork: CH4 CF4 • Answer key • CH4 EN of H = 2.1 EN of C = 2.5 ΔEN = 0.4 Non polar covalent bond • CF4 EN of C = 2.5 EN of F = 4.0 ΔEN = 1.5 Polar covalent bond CF4 Give the general rule that “like dissolves like” or “like mixes with like.” This refers to substances being able to mix due to their same polarity. In the experiment, water and vinegar mixed because they are both polar substances while gasoline and oil are non-polar substances. Oil and water, oil and vinegar, gasoline and water, and vinegar and gasoline do not mix because their polarities are different. •Molecules are polar or non- polar based on the type of covalent bond. •One of the most practical manifestations of polarity is solubility and miscibility. Solubility refers to the ability of a solute to dissolve in a certain amount of solvent. Miscibility is the ability of two liquids to mix in all proportions. Quiz:
O2 HBr •O2 EN of O = 3.4 ΔEN = 0.0 Non polar covalent bond •HBr EN of H= 2.1 EN of Br = 2.8 ΔEN = 0.7 Polar covalent bond