The characteristic feature of woody cells is the special
nature of their cell walls. The gross structure and the
properties of the mature woody cell arise from the nature and organization of the chemical compounds which make up the wall and the systematic way in which the cell wall is constructed by the cytoplasm. Wood tissue is composed principally of a group of polymer substances that make up the cell walls. These compounds are mixed in the wall, which is directly reflected in the physical and mechanical properties of wood. In addition there are many different kinds of organic and inorganic materials which present in admixture with walls or cell lumens. Primary components A. Total polysaccharide fractions, expressed as holocellulose-- 60-85% 1. Cellulose—40-50% Long chain polymer with low solubility 2. Hemicellulose –20-30% Non cellulose polysaccharide; these are readily soluble in dilute alkali hydrolysable by dilute acids to component sugars and uronic acids. B. Lignin –15-30% Secondary components a. Tannins b. Volatile oils and resins c. Gum, latex, alkaloids, and other complex organic compounds including dyes and coloring materials d. Ash- usually less than 1 % The primary components basically established the chemical and physical nature of the cell wall. The most important single component is the cellulose, which has primary relation to the physical behaviour of the wood as a whole. The hemicellulose and lignin in the wall also important influences on the behaviour of the wood through volume and characteristics. Polysaccharide Fractions of the Cell Wall The polysaccharide fractions, i.e the polymers of the simple sugars, are isolated from the wood by first removing the soluble materials with either alcohol and water and then removing the lignin. The polysaccharide materials are separated into two fractions by treatment (1) the insoluble cellulose, and (2) a mixture of alkali soluble polymers of simple sugars known as hemicellulose. Holoellulose fraction is the combination of cellulose and hemicellulose in wood. A. Cellulose Cellulose is the most important single component in the woody cell wall in terms of volume and characteristics in wood. Cellulose has been characterized as a stable fibrous residue of woody and non woody tissue, resistant to attack by chemicals. B. Hemicellulose Hemicellulose constitute from 0.5 to 50 % of the polysaccharides in the cell wall substance and from 20 to 35 % of the total dry weight of the cell wall substance. The definition of hemicellulose is even less precise than that of most other plant constituents and is based mainly on chemical behaviour. Hemicellulose constitute that portion of the total polysaccharides in wood which for the most part is soluble in dilute alkali and hydrolyzes readily in dilute acid to form sugar and sugar acids. This hemicellulose fraction is composed of two general classes of substance (1) those collectively called xylans, whose molecules are formed by polymerization of the anhydro form xylose, arabinose, and 4 methyl glucoronie acid (2) hemicellulose called glactoglucomannans in softwoods.