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Chemical Equilibrium
Chapter 13
Table of Contents
13.1 The Equilibrium Condition
13.2 The Equilibrium Constant
13.3 Equilibrium Expressions Involving Pressures
13.4 Heterogeneous Equilibria
13.5 Applications of the Equilibrium Constant
13.6 Solving Equilibrium Problems
13.7 Le Châtelier’s Principle
Chemical Equilibrium
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Equilibrium Is:
• Macroscopically static
• Microscopically dynamic
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Changes in Concentration
N2(g) + 3H2(g) 2NH3(g)
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Chemical Equilibrium
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Concept Check
Concept Check
jA + kB lC + mD
l m
[C] [D]
K= j
[A] [B]k
• A, B, C, and D = chemical species.
• Square brackets = concentrations of species at equilibrium.
• j, k, l, and m = coefficients in the balanced equation.
• K = equilibrium constant (given without units). Return to TOC
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• K involves concentrations.
• Kp involves pressures.
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Example
P
2
Kp =
NH
3
K =
NH3 2
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Example
PN = 8.9 10 1 atm
2
PH = 2.9 10 3 atm
2
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Example
P
2
NH
Kp = 3
P P
3
N H
2 2
Kp =
2.9 10
2 2
8.9 10 1
2.9 10
3 3
Kp = K(RT)Δn
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Example
Kp = K RT
n
2 4
3.9 10 = K 0.08206 L atm/mol K 308K
4
K = 2.5 107
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Homogeneous Equilibria
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Heterogeneous Equilibria
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K = O2
3
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Concept Check
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Reaction Quotient, Q
• Apply the law of mass action using initial
concentrations instead of equilibrium
concentrations.
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Reaction Quotient, Q
• Q = K; The system is at equilibrium. No
shift will occur.
• Q > K; The system shifts to the left.
Consuming products and forming
reactants, until equilibrium is achieved.
• Q < K; The system shifts to the right.
Consuming reactants and forming
products, to attain equilibrium.
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Exercise
• Trial #1:
6.00 M Fe3+(aq) and 10.0 M SCN-(aq) are mixed at a
certain temperature and at equilibrium the concentration
of FeSCN2+(aq) is 4.00 M.
K =
FeSCN2
=
4.00 M
Fe SCN 2.00 M 6.00 M
3
K = 0.333
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Exercise
• Trial #2:
Initial: 10.0 M Fe3+(aq) and 8.00 M SCN−(aq) (same
temperature as Trial #1)
Equilibrium: ? M FeSCN2+(aq)
5.00 M FeSCN2+
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Exercise
• Trial #3:
Initial: 6.00 M Fe3+(aq) and 6.00 M SCN−(aq)
Equilibrium: ? M FeSCN2+(aq)
3.00 M FeSCN2+
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Exercise
Exercise (Answer)
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Concept Check
Concept Check
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3. Pressure:
a) The system will shift away from the added
gaseous component. If a component is
removed, the opposite effect occurs.
b) Addition of inert gas does not affect the
equilibrium position.
c) Decreasing the volume shifts the equilibrium
toward the side with fewer moles of gas.
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