Determination of calorimeter constants

In the process of temperature change, the mixture of cold water and hot water
is stirred so that when the measurement will be obtained the temperature
decrease, without any stirred cold water and hot water will be homogeneous.
The results showed that temperature changes within 10 minutes at intervals of
1 minute, 35ᵒC, 35ᵒC, 35ᵒC, 35ᵒC, 34ᵒC, 33ᵒC, 33ᵒC, 33ᵒC, 33ᵒC, 33ᵒC,
respectively, obtained a constant temperature of 33ᵒC.
Reaction: H2O + H2O 2H2O
This proves that the heat dissociates from the hot water marked by the
decrease in temperature, whereas the cold water absorbs the heat which is
indicated by the rise in temperature. In this thermochemical experiment also
serves to maintain tempeatur.
From the data it obtains, it can be used to determine the calorimeter constant
by using the formula ΔQ absorb = ΔQ off, from the calculation result obtained
the calorimeter value is 100.8 J / C
Determination of acid-base caloric
From the observation it is found that the mixed temperature is lower, the
temperature of the solution should be higher, this is because the temperature is
absorbed by the calorimeter and may be in stirring and closing calorimeter less
tightly. The temperature is consecutive that is
41ᵒC,40ᵒC,40ᵒC,39ᵒC,38ᵒC,38ᵒC,38ᵒC,37ᵒC,37ᵒC,37ᵒC and get constant
temperature 37ᵒC The reaction occurring in this experiment was NaOH + HCl
NaCl + H2O and from the data obtained H 82069.2 J / mol and so on, the
temperature grew increasingly longer and included an exothermic reaction but
due to several factors already mentioned, the temperature decreased and into
the endoderm reaction. Determination of the second acid-neutralizing heat
content using 10 mL of NaOH solution (strong base) and 10 mL of CH3COOH
(weak acid) solution both had an initial temperature of 28 ᵒC. The mixing
method is the same as the first neutralization calorie determination. In this
mixing there is a reaction: CH3COOH + NaOH CH3COO¯Naᶧ + H2O.
In this reaction, CH3COOH partially dissociates in water to form CH3COO¯
and Hᶧ, while NaOH, whereas NaOH dissociates completely in water and forms
Naᶧ and Hᶧ, the CH3COONa¯ salt formed is alkaline. The mixture CH3COOH
and NaOH is a system that receives heat and calorimeter as heat release.
After the solution is mixed in the calorimeter, the temperature change within 5
minutes at 0.5 min intervals results in the following 36ᵒC, 36ᵒC, 36ᵒC, 36ᵒC,
36ᵒC, 36ᵒC, 35ᵒC, 35ᵒC, 35ᵒC, 35ᵒC, the temperature constant is 36ᵒC, from
the data as capital to determine the value of calor neutralization with the
formula Q = m.c1.Δt + c.Δt and obtained the value of ΔH of 75631.68 J / mol
reaction towards the endothermic and his enthalpy increases ΔH = +
Determination of third neutralizing heat, we used 10 ml of HCl
(strong acid) with 10 ml of NH4OH solution (weak base) of the
same initial temperature of 28ᵒC. Mixing is equal to second
neutralization calorific determination. After the solution is mixed in
the calorimeter and observed the temperature change for 5
minutes at 0.5 minute interval indicates the temperature
decreases, it should be in accordance with the theory of
temperature determines the fixed number but in our experiment
at 4th minute and 5th the temperature decreases, this because the
closure of the calorimeter is less dense and the thermometer
attached to the base of the calorimeter so that it affects the
temperature, but the temperature is not too far. From the data in
get ΔH equal to 72475,2 J / mol. Included into the endothermic
reaction.
What distinguishes the determination of heat on the three
experiments is the value of the solution velocity and the heat of its
kind
• Conclusion
1. In a chemical reaction that occurs when determining trial provisions
calorific calorimeter and determining counteraction to prove that any
reaction is accompanied by a change in the second trial
energi.Karena occurred absorption and release of heat, and the
temperature changes that will surely lead to a change of energy.
2. Heat changes can be proven through simple experiments, such as in
acid neutralization experiments or determination of calorimeter
determination.
3.Tetapan calorimeter can be determined using colorimetric method,
used in this experiment H2O with the aim to meet asaz black, the hot
water temperature of 50ᵒC, will take off the heat and statutes
calorimeter value can dihitung.Dengan absorbency formula Q = Q
values obtained freelance calorimeter constant of 100.8 J / C.
4. Changes in reaction enthalpy can be done by various methods one
using kalorimeter.Sebelumnya in seek first heat acid neutralizing
different bases, the first mixture is HCl-NaOH with the same volume
and temperature in getting ΔH amounted to 82 069, 2 J / mol. And
in the mixture of CH3COOH -NH4OH the ΔH value was 75631.81 J
/ mol, and in the third mixture HCl-NH4OH was obtained H by
72475.2 J / mol