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OBJETIVOS
Interpretar la ley cero de la termodinámica y el
estado de equilibrio térmico.
Diferenciar la energía térmica, calor y
temperatura, así como sus unidades.
Interpretar a la temperatura como un indicador
de la energía vibratoria de las moléculas de los
cuerpos.
Realizar cambio de escalas de temperature.
Interpretar a la densidad de los cuerpos y su
relación con la gravedad específica.
Diferenciar a los conceptos de presión absoluta,
presión atmosférica, presión gage, presión de
vacío.
Diferenciar el peso molecular y el peso atómico.
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Lista de Contenidos
• Ley cero de la termodinámica.
• Estado y Equilibrio
• Definición de energía térmica
• Temperatura-Escalas termométricas.
• Problema 01
• Presión-dispositivos.
• Ejemplo 01
• Problemas 02, Problemas 03, Problemas 04
• Densidad-gravedad específica.
• Ejemplo 02, Ejemplo 03
• Problema 05
• Peso molecular.
• Conclusiones
• Referencias
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The Zeroth Law of Thermodynamics
Thermal Equilibrium
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STATE AND EQUILIBRIUM
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Thermal Energy Defined
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HEAT DEFINED
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TEMPERATURE
Temperature – measure of
the average kinetic energy
of the particles in a sample
of matter.
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TEMPERATURE UNITS DEPEND OF
SCALES
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After Fahrenheit died in
1736, scientists
calibrated
his model of thermometer
using 212
degrees, the
temperature at which water
boils, as the
upper fixed point,
and 32 degree for water
freezing.
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The Celsius temperature scale
was invented by Anders Celsius
(1701-1744) a Swedish Astronomer
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Celsius Temperature Scale
• The Celsius scale often used by countries
using the metric system.
• It is based on water’s
freezing point
– et at 0o and its boiling
point – set at 100o.
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Kelvin temperature scale
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Kelvin temperature scale, has an absolute
zero below which
temperatures do not exist.
• Celsius to Fahrenheit
• Kelvin to Celsius
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Thermal equilibrium
• The state in which two bodies in physical contact with each
other have identical temperatures. (Not net transfer of
thermal energy or heat.
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State of matter is related to temperature
Solids, liquids, gases- states of matter determined by the
rate at which atoms or molecules move.
• Solids- tightly packed with fixed volume & shape
• Liquids – not as tightly linked with fixed volume, but not shape.
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• For gases with one type of atom
(monoatomic) temperature is
understood in terms of kinetic energy.
• For other kinds of substances,
molecules can rotate or vibrate, so
other types of energy is present.
Serway/Faughn Physics
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PROBLEMS 1
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PRESSURE
• Pressure is defined as a normal force exerted by a
fluid per unit area.
• Normally, we speak of pressure when we deal with a
gas or a liquid. The counterpart of pressure in solids is
normal stress. Note, however, that pressure is a scaler
quantity while stress is a tensor. Since pressure is
defined as force per unit area, it has the unit of
newtons per square meter (N/m2), which is called a
pascal (Pa). That is,
1 Pa = 1 N/m2
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PRESSURE UNITS
• The pressure unit pascal is too small for most pressures
encountered in practice. Therefore, its multiples kilopascal
(1_kPa=103 Pa) and megapascal (1 MPa = 106 Pa) are commonly
used. Three other pressure units commonly used in practice,
especially in Europe, are bar, standard atmosphere, and
kilogram-force per square centimeter:
• 1 bar = 105 Pa = 0.1 MPa = 100 kPa
• 1 atm = 101,325 Pa = 101.325 kPa = 1.01325 bars
• 1 kgf/cm2 = 9.807 N/cm2 = 9.807 3 104 N/m2 = 9.807 3 104 Pa
• = 0.9807 bar
• = 0.9679 atm
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APPLICATION
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GAGE PRESSURE-VACUUM PRESSURE
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Absolute, gage, and vacuum pressures
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EXAMPLE 01
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PROBLEMS 2
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PROBLEMS 3
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PROBLEMS 4
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DENSITY AND SPECIFIC GRAVITY
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EXAMPLE 02
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SOLUTION
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EXAMPLE 03
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PROBLEMS 5
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MOLECULAR WEIGHT AND MOLAR MASS
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MOLECULAR FORMULA
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EXAMPLE
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Conclusiones
El estudiante comprendió los fundamentos básicos de la
termodinámica a través de sistemas y volumen de control, sus
propiedades, los procesos termodinámicos, los estados de
equilibrio, uso de unidades, así como su importancia en la
ingeniería.
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Referencias
• Cengel Yunus, México, McGraw-Hill, 2015. 621.4021 C43 2015
• Physics -Serway/Faughn
• Zemansky Mark, Calor y termodinámica. México, Pearson,
2005. 530 Z64
• Claus Borgnakke and Richard E. Sonntag, Fundamentals of
Thermodynamics, Wiley, 2012
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MSc. Ing. Alejandro Vera Lázaro
avlazaro@usat.edu.pe
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