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CHE 416
COURSE OUTLINE:CHE416
IDEAL REACTORS ASSUMPTIONS (IDEAL VS. REAL) MATERIAL BALANCE / PERFORMANCE OR DESIGN EQUATIONS COMPARISON OF IDEAL REACTORS NONISOTHERMAL OPERATION ENERGY BALANCE EQUATION APPLICATION TO DESIGN
OUTLINE:CHE416 CONTD.
REAL VERSUS IDEAL REACTORS SOURCE OF DEVIATIONS RESIDENCE TIME DSTRIBUTION RTD FUNCTIONS CONVERSIONS-1ST ORDER RXNS REACTOR MODELS
ATTENTIVE IN CLASS
RE-READ NOTES PRACTICE SOLVING QUESTIONS YOURSELF ASK QUESTIONS TO BE SURE YOU UNDERSTAND BE READY FOR WEEKLY TESTS
CA VS t,
CA VS t,p Fig
1
Advantages/Disadvantages of BR
is simple, needs little supporting equipments, high flexibility-high conversions through as high reaction time as desired ideal for small-scale experiments (kinetics studies).
Advantages/Disadvantages of BR2
Industrially, a single unit may be used for the manufacture of relatively small amounts of material (drugs, dyes, cosmetic articles)-not dedicated unit Disadvantages are idle periods (for loading, unloading, cleaning, heating etc).
Design equation of BR
Obtained from the law of conservation of matter. Written for any component in the system [ reactant, product, inert] Written in terms of limiting reactant ,A Written for the whole volume of reactor because of uniform conditions within it
dt N A0
0 X Ae
X Ae
dX A V (rA )
t N A0
dX A V (rA )
t C A0
X Ae
dX A V (rA )
This gives the time for a conversion of XA=XAe as a function of the: rate law and the initial concentration of A
f(x)
1 2 3
a=0
x=(a+b)/2
b=XAe
CSTR contd2.
mixing so perfect that concentration and temperature are spatially uniform within whole of reactor and correspond to those of the exit stream; operates in a steady mode wrt. time [at all times, Ci is same at any point] operates in a steady mode wrt. space Ci .is same at all points at any t]
CSTR
reactants *
contd.
reactor products continuously drawn from reactor Also called vat, backmix reactor, mixed flow reactor 100% back mixing
VCSTR=[FA0/(-rA)] x XAe
Plug/Piston/ slug flow reactor [PFR] Continuous Tubular Reactors (CTRs). Plug flow Tubular Reactors (PFTR)
FLUID Flows orderly
No Element Of Fluid Mixing With Or Overtaking Any Other Element Ahead Or Behind. May Be Lateral Mixing, No Diffusion Along The Flow Path (0% Of Backmixing).
Design equation2
FA-(FA+FA)-(-rA)V=0
-FA=(-rA)V FA/V=-(-rA) As V0 In terms of XA, dV =FA0 [dXA/(-rA)] Integrating,
Applications: PFR
Large-scale reactions Homogeneous or heterogeneous reactions Continuous production Most gas phase reactions Relatively Easy to maintain(no moving parts) Highest conversion per volume Difficult to control temperature within the reactor, hence hot spots for exothermic rxns As one long tube or as a tube bank
CSTRs in a series
FA0 CA0 FA2; CA2
FA1;
CA1
2 1
CA3
[XA3-XA2)/(-rA3)
[XA1-XA0)/(-rA1)
1/(-rA2) 1/(-rA1)
XA
XA0
XA1
XA2
XA3
BR vs. PFR
*
For any conversion, the ratio of volumes : VCSTR/VPFR increases with the reaction order. For any positive reaction order, the ratio of volumes VCSTR/VPFR increases with the conversion
positive nth order, the rate is maximum at high CA it slows progressively as the reactant is consumed
in autocatalytic reactions, the rate at the start is low (little product is present), it increases to a maximum as product is formed and then it drops again as reactant is consumed.
XA0
XA1
XA2 XA3
Same results as a single PFR with same Several CSTRs in series approaches performance of a single PFR with same total V