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Contents:
What is a catalytic converter ?
History. Why has it been needed to introduce ? How does it reduce pollution ? Types - On the basis of function. Technical details. Advantages. Disadvantages. References.
Catalytic converters are also used on generator sets, mining equipment, trucks , buses , trains, and other engine-equipped machines. A catalytic converter provides an environment for a chemical reaction wherein toxic combustion by-products are converted to lesstoxic substances.
History
First widely introduced on seriesproduction automobiles in the US market for the 1975 model year to comply with tight regulations on auto exhaust, catalytic converters are still most commonly used in motor vehicle exhaust systems .
Cont
The idea is to create a structure that exposes the maximum surface area of catalyst to the exhaust stream, while also minimizing the amount of catalyst required, as the materials are extremely expensive. Some of the newest converters have even started to use gold mixed with the more traditional catalysts.
Cont.
Reduction Catalyst :-
The reduction catalyst is the first stage of the catalytic converter. It uses platinum and rhodium to help reduce the NOx emissions. When an NO or NO2 molecule contacts the catalyst, the catalyst rips the nitrogen atom out of the molecule and holds on to it, freeing the oxygen in the form of O2. The nitrogen atoms bond with other nitrogen atoms that are also stuck to the catalyst, forming N2. For example:
Cont
Oxidation catalyst :-
It is the second stage of the catalytic converter. It reduces the unburned hydrocarbons and carbon monoxide by burning (oxidizing) them over a platinum and palladium catalyst. This catalyst aids the reaction of the CO and hydrocarbons with the remaining oxygen in the exhaust gas.
For example:
Cont
There are two main types of structures used in catalytic converters -- honeycomb and ceramic beads. Most cars today use a honeycomb structure.
Cont
Two-way catalytic converters :
This type of catalytic converter is widely used on diesel engines to reduce hydrocarbon and carbon monoxide emissions. A two-way catalytic converter has two simultaneous tasks: Oxidation of carbon monoxide to carbon dioxide: 2CO + O2 2CO2 Oxidation of unburnt hydrocarbons to carbon dioxide and water: 2CxHy + (2x+y/2)O2 2xCO2 + yH2O
Technical details.
The catalytic converter consists of several components: The core, or substrate. In modern catalytic converters, this is most often a ceramic honeycomb, however stainless steel foil honeycombs are also used. The purpose of the core is to "support the catalyst" and therefore it is often called a "catalyst support".
Cont
The catalyst itself is most often a precious metal. Platinum is the most active catalyst and is widely used. However, it is not suitable for all applications because of unwanted additional reactions and cost. Palladium and Rhodium are two other precious metals that are used. Platinum and rhodium are used as a reduction catalyst, while platinum and palladium are used as an oxidization catalyst.
Advantages:
1. The most significant advantage of using Catalytic Converter is the pollution control which has come up as a boon to every lives. Reducing the toxicity of the emission gases which are carcinogenic in nature, it has saved the environment a lot. 2. Size & Shape of it is not too gigantic , hence easy to incorporate in the vehicles. 3. No requirement of fuel and also no need of continuous maintenance.
Disadvantages:
1. Catalytic converters are an integral part of the vehicles emission system. They are designed to work within a very limited band of exhaust gas concentration, too rich or too lean and the life of the converter will be reduced. 2. Recycling is not possible. Once it gets damaged it has to be changed and a new one has to be used in case of vehicles. 3. Cost factor is a headache as it consists of costly catalysts like- platinum, gold, rhodium etc.
References:
Handbook of Heterogeneous catalyst Edited by G.Ertl & h.Kniizinger (2005) www.catalyticconverter.org
www.howstuffworks.com
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