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Hi FRIENDS !! Today we will learn about naming of alkenes and its physical properties.. LETS BEGIN OUR JOURNEY!!
intro
I am POLYSTREN E
WE ARE FROM
ALKENE GROUP
About ALKENE
Alkene is classified as unsaturated hydrocarbon Contain at least one carbon carbon double bond General formula, CnH2n (n=1,2,3,.) For example, C2H4 - ethylene
WHAT is MY NAME??? There are a lot of my name that you can identify. Interesting right? Well, lets see the steps that you should use to give my name Step 1 Step 2
Step 3
SOLUBILITY
Insoluble in water, But soluble in nonpolar solvent
Chemical structure and functional group can affect the polarity of alkenes compounds
POLARITY
Thus, it creates a weak dipole along the substituent weak alkenly carbon bond
cis - cannot cancel out. Thus, has net dipole and has higher boiling point than trans
Boiling points of alkenes depends on more molecular mass (chain length). Hmm, giraffe Did you know why the boiling point increased with increasing molecular mass?
0o0oThe more intermolecular mass is added, the higher the boiling point.
Intermolecular forces of alkenes gets stronger with increase in the size of the molecules.
But, how about the alkenes that have same molecular mass but differ in their structure? For that compounds, we should looks it surface area. the more branched alkenes, the more lower its boiling points.
O0o0To predict relative boiling points, we should look for differences in (1) hydrogen bonding, (2) molecular weight and surface area and (3) dipole moments. .
One things we should consider in determine the boiling points of the compounds is its hydrogen bond. If it has hydrogen bond, then it has the highest boiling points. Same goes with dipole moments.
Compound
Ethene Propene Trans-2-Butene Cis-2-butene Cis 1,2-dichlorobutene Trans 1,2dichlorobutene 1-Pentene
Among of the following solvent, which solvent will make alkenes dissolve?
1. What is the physical state of butene at room condition? 2. Did 2,3-dimethylhexene dissolves in water? Why? 3. Why the boiling points of octene is differ from butene?
O0o0 we need to do We are LOST some activity to go away from here.. !!!
activity
1. Alkenes do not have functional group 2. Alkenes consist of carbon-carbon T double bond 3. The general formula for alkene is T CnH2n 4. In naming the IUPAC name for alkenes,1st step is list the number of substituents according to their F position in carbon chain 5. In alkenes, there is E-Z system T
6. HC
C=C
H
COOH CHOH
(E)-2-hydroxymethyl-2-butenoic acid
7. Branched alkenes provided lower boiling t point compared to straight chain alkenes 8. Alkenes is polar molecule f f 9. Alkenes soluble in water 10. Alkenes provide higher polarity than t alkanes 11. Alkenes is less reactive than alkanes f
activity
CH2
1,4-hexadiene
CH2CH3 CH2CH3 Br
5-bromo-3-sec-butyl-1pentene
CH3CH
CHCH2CH
CH2
4-bromo-1-ethylcyclo hexene
CH3
Br CH2CH2CHCHCH2CH3 CH CH2
2,3-dimethyl-2-butene
2-methyl-1,4cyclohexadiene
CH3
CH3 CH2CH3
CH3 CH2CHCH2CH = C
CH2CH
1,5-dimethylcyclopentene
CH3 cis-5-methyl-2-hexene
CH3 CH3
trans-5,7-dimethyl-3nonene
activity
b) Write out the full name, numbering the substituents according to their position in the chain and list them in alphabetical order.
c) Number the carbons of the parent chain so the double bond carbons have the lowest possible numbers.
d) Name the parent hydrocarbon by locating the longest carbon chain that contains the double bond and name it according to the number of carbons with the suffix -ene.
Answer D, C, A, B
Arrange the following alkenes with increasing boiling points and explain why.
2-methylpentene, 1-hexene, 2,3-dimetylbutene
ANSWER
2,3-dimetylbutene < 2-methylpentene < 1-hexene To predict relative boiling points, we should look for differences in (1) hydrogen bonding, (2) molecular weight and surface area and (3) dipole moments. All of the compounds have same molecular mass and do not have hydrogen bonds. So, we look into its surface area. Because 2,3-dimetylbutene is most branched than others, thus it has the lowest boiling points. Between 2-methylpentene and 1-hexene, 1-hexene is not branched, therefore it has the highest boiling point among others.
WELL DONE SON. YOU DID IT !! NOW YOU CAN THANKS GO HOME.. FRIENDS
FOR HELPING US
YEYY!!! THANK YOU OLD MAN.. NOW WE CAN MEET MY FAMILY AGAIN..
Good bye friends!!! I hope you all understand better about naming of alkenes and its properties..
REVISION
Steps of naming an alkene Physical properties 1. Appearances 2. Density 3. Solubility 4. Polarity 5. Boiling Point 6. Melting Point