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Presented by:
S.R. Michael Harrison Suraj Tiwari Sriram
Guided By:
S. Siluvaimuthu
INTRODUCTION
Biodiesel
Sources of bio-diesel
Types of oil sources
ESTERIFICATION OF BIODIESEL
Aim Principle Reaction Chemicals required Apparatus required Procedure
AIM
Base (NaOH) catalyzed esterification of Biodiesel [Fatty acids Triglyceride carboxylic acids] using Methanol (CH3OH). Esterification: Conversion of Carboxylic acids [CH3COOH] to Ester [CH3COOCH3] by the treatment with alcohol[CH3OH].
Principle
Carboxylic acids contain the carboxyl group on carbon. In ester, the hydrogen in the carboxyl group replaced by an alkyl group.
Principle(contd.)
O H3C O H
O H3C O R
Reaction
Esterification H+ (catalyst)
Base catalyst
O R OH Alcohol OH
O R R O Ester
oxylic Acid
Chemicals required
Vegetable Oil (Edible / Non-edible) eg:Neem Oil,Soyabean Oil
Alcohol - Methanol (CH3OH) / Ethanol (CH3CH2OH) Alkali - Sodiumhydroxide (NaOH) / Pot. hydroxide (KOH)
Apparatus required
Mechanical stirrer Heating mantle Round bottom flask
Thermometer
Condenser
Separating funnel
Apparatus required(contd.)
Measuring jars Beakers Funnels
Procedure
Step 1: Activation of alcohol:
Sodium Hydroxide is dissolved in alcohol by vigorous stirring to form alkoxide in a closed vessel NaOH + CH3OH ------- CH3ONa + H2O
Sod.Hydroxide Methanol Sodium alkoxide
Step 2: TRANSESTERIFICATION / Alcoholysis Alcohol catalyst mixture is mixed with Oil Oil & Methanol ratio 10:1 by weight] Reaction mixture is heated for 70o C for 3 hours to speed up the esterification process
CH2OCOR1 | CH- OCOR2 + 3CH3OH ----Alkaline---- | Catalyst CH2 OCOR3 Triglyceride Methanol R1COOCH3 CH2 OH | R2COOCH3 + CH OH | R3COOCH3 CH2 OH Biodiesel Glycerol
Step 3: Separation of alcohol: Methyl ester (BIODIESEL) and Glycerol are allowed to settle by gravity in a separating funnel The denser glycerol settle down, while the Biodiesel forms the upper layers. The two layers are separated Both layer contains equal amount of Methanol that has to be removed
Step 4: Methyl ester wash: Methyl ester (BIODIESEL) contains unused catalyst and Methanol To remove this, Methyl ester is neutralized with H2SO4(30%) to deactivate the catalyst Then, washed with hot water to remove the catalyst and washing is continued until the pH of washed water is in the range of 6 7 Washed ester is dried using silica gel Methanol can be removed by distillation
Neutralization
A key characteristic of both acids and bases is that they react in a way to neutralize or remove the properties of the other. These are double replacement reactions. Eg : 2 HCl (aq)+Mg(OH)2 (aq) -------MgCl2 (aq)+2 H2O (l) Acid + Base a Salt + water
Flow chart
Refining area
Redwood Viscometer
Definition "A viscometer (also called viscosimeter) is an instrument used to measure the viscosity of a fluid. For liquids with viscosities which vary with flow conditions, an instrument called a rheometer is used. Viscometers only measure under one flow condition."
Redwood Viscometer
Description of Procedure: The inner cylinder is filled to the marker level and the outer cylinder filled so as to have sufficient height to give good heat transfer. The surrounding water is heated with an electrical heating coil. Heat is transferred to the inner cylinder by rotation of the blades of the agitator. The first reading is taken by removing the stopper from the orifice. The recorded values were the water and test liquid temperatures and the time to collect 50cc of the liquid being recorded. Both the beginning and end temperatures are noted. The collected 50cc of liquid must be put back into the inner cylinder and the used cylinder inverted to empty completely. The level of the sample is checked as, if more of the liquid is needed it would be added. The temperature is then raised and the agitator is used again continuously. This is done until the liquid is brought within 1 degree of the water temperature. The same parameters were again measured. This procedure is repeated for 5 samples in total (at least).
Benefits of Bio-diesel
Reduce the burden on non-renewable fossil fuel sources. Utilization of degraded land with minimal water requirement. Biodiesel produces less pollution than conventional fossil fuel sources. Increase of rural economy and living industries. Increase in nutrients to soil, decrease in soil erosion.
CONCLUSION
A large part of Indias population, mostly in rural areas, does not have access to energy services. The enhanced use of renewables (mainly biofuels) in rural areas is closely linked to poverty reductions because greater access to energy services can: Improve access to pumped drinking water. Potable water can reduce hunger by allowing for cooked food (95 per cent of food needs cooking); Reduce the time spent by women and children on basic survival activities (gathering firewood, fetching water, cooking, etc.); Allow lighting which increases security and enables the night time use of educational media and communication at school and home; and Reduce indoor pollution caused by firewood use, together with a reduction in deforestation.