Académique Documents
Professionnel Documents
Culture Documents
SOLID STATE
Crystals
Crystal structure basics unit cells symmetry lattices
Objectives
By the end of this section you should: be able to identify a unit cell in a symmetrical pattern know that there are 7 possible unit cell shapes be able to define cubic, tetragonal, orthorhombic and hexagonal unit cell shapes
Why Solids?
most elements solid at room temperature atoms in ~fixed position simple case - crystalline solid Crystal Structure Why study crystal structures? description of solid comparison with other similar materials classification correlation with physical properties
More crystals
Early ideas
Crystals are solid - but solids are not necessarily crystalline Crystals have symmetry (Kepler) and long range order Spheres and small shapes can be packed to produces regular shapes (Hooke, Hauy)
Group discussion
Kepler wondered why snowflakes have 6 corners, never 5 or 7. By considering the packing of polygons in 2 dimensions, demonstrate why pentagons and heptagons shouldnt occur.
Definitions
1. The unit cell The smallest repeat unit of a crystal structure, in 3D, which shows the full symmetry of the structure
Think about the shapes that these define - look at the models provided.
Choice of origin is arbitrary - lattice points need not be atoms - but unit cell size should always be the same.
This is NOT a unit cell even though they are all the same - empty space is not allowed!
All M.C. Escher works (c) Cordon Art-Baarn-the Netherlands. All rights reserved.
Examples
The sheets at the end of handout 1 show examples of periodic patterns. On each, mark on a unit cell. [remembering that there are a number of different (correct) answers!]
Summary
Unit cells must link up - cannot have gaps