1

Thermodynamique : principales grandeurs

1 Definitions
Monobare : Pe = cte.
Isobare : P = cte.
Isotherme : T = cte.
Monotherme : Te = cte.

2 Tableau recapitulatif
W / W
Definition

W = Pe dV

Q / Q
Q = dU + P dV
Q = U W

Q.S.

dU = W + Q
U = W + Q

dU = CV dT = ncV,m dT

G.P.

non Q.S.

dU / U

dS / S
dU
P
+ dV
T
T
dH
V
dP
=
T
T
nR
ln(T V 1 )+S0
S=
1
nR
ln(P V ) + S0
=
1
nR
=
ln(T P 1 )+S0
1
dS =

W = PB (VB VA )
Z B
W =
P dV
A

G.P.

W = nRTA ln
= nrTA ln

VB
VA

PB
PA

Q = ncV,m dT + P dV
= ncP,m dT V dP
Z B
Q
Q
, S =
T
T
A
Qsource
dSsource =
Te
dS =

Reversible

Monobare

W = Pe dV

Q = H = Cp (TB TA )
Q = H = Cp (TB TA )

Isobare
Q.S.+G.P

W = PA (VB VA )

Isotherme
Q.S.+G.P

W = nRT ln
= nrT ln

VB
VA

Q = W

S = mCp ln

U = H = 0

PB
PA

Isochore

U = ncV,m (TB TA )

Q=0

Adiabatique
G.P.+Q.S.

Se =
Q = U

W = U

nRT
(P V )
=
1
1
PB VB PA VA
=
1

U =

VB
VA
( Reversible + G.P. )

dSe

W =0

TB
TA

S = nR ln

dSsour.

Monotherme
source Te

Qsour.
Te

Qsour.
Q
=
Te
Te