[NO3-] [HNO2] [Ce3+] [Ce4+] Volumen Ce4+ Ecelda, V

0.0025 0.0225 5 0.713

0.0047 0.0188 10 0.723
0.0066 0.0155 15 0.73
0.01 0.01 25 0.741
0.0139 0.0034 40 0.759
0.0158 0.00032 49 0.791
0.015904 0.00016 49.5 0.8
0.015923 0.0001284 49.6 0.803
0.015942 9.62E-05 49.7 0.807
0.015962 6.41E-05 49.8 0.812
0.015981 3.20E-05 49.9 0.821
0.01599 1.60E-05 49.95 0.83
0.015998 3.20E-06 49.99 0.85
50 0.908
0.03199 6.40E-06 50.01 1.022
0.031987 3.20E-05 50.05 1.063
0.031974 6.39E-05 50.1 1.081
0.031949 1.28E-04 50.2 1.099
0.031923 1.92E-04 50.3 1.109
0.031898 2.55E-04 50.4 1.117
0.031873 3.19E-04 50.5 1.123
0.031746 6.35E-04 51 1.14
0.02963 5.93E-03 60 1.2
0.0266 1.33E-02 75 1.223
0.02424 1.94E-02 90 1.235
∆E ∆V ∆E/∆V Vmedio1 ∆²E ∆V² Vmedio2
0.01 5 0.002 7.5 -0.003 0 10
0.007 5 0.0014 12.5 0.004 5 16.25
0.011 10 0.0011 20 0.007 5 26.25
0.018 15 0.0012 32.5 0.014 -6 38.5
0.032 9 0.00355556 44.5 -0.023 -8.5 46.875 1.4
0.009 0.5 0.018 49.25 -0.006 -0.4 49.4
1.2
0.003 0.1 0.03 49.55 0.001 0 49.6
1
0.004 0.1 0.04 49.65 0.001 -7.1054E-15 49.7
0.005 0.1 0.05 49.75 0.004 7.10543E-15 49.8 0.8

Ecelda
0.009 0.1 0.09 49.85 1.11022E-16 -0.05 49.8875 0.6
0.009 0.05 0.18 49.925 0.011 -0.01 49.9475
0.4
0.02 0.04 0.5 49.97 0.038 -0.03 49.9825
0.058 0.01 5.8 49.995 0.056 0 50 0.2

0.114 0.01 11.4 50.005 -0.073 0.03 50.0175 0

0 10 20
0.041 0.04 1.025 50.03 -0.023 0.01 50.0525
0.018 0.05 0.36 50.075 0 0.05 50.1125
0.018 0.1 0.18 50.15 -0.008 -7.1054E-15 50.2
0.01 0.1 0.1 50.25 -0.002 7.10543E-15 50.3
0.008 0.1 0.08 50.35 -0.002 0 50.4
0.006 0.1 0.06 50.45 0.011 0.4 50.6
0.017 0.5 0.034 50.75 0.043 8.5 53.125
0.06 9 0.00666667 55.5 -0.037 6 61.5
0.023 15 0.00153333 67.5 -0.011 0 75
0.012 15 0.0008 82.5 -0.012 -15 41.25

7.5 17.5 27.5

10
8
6
4
2
0
0 10
-2
10
8
6
4
2
0
0 10
-2
-4
-6
-8
-10
 Ecelda vs Vol
1.4

1.2

0.8
Ecelda

0.6

0.4

0.2

0
0 10 20 30 40 50 60 70 80 90 100
Volumen Ce4+

primera derivada

7.5 17.5 27.5 37.5 47.5 57.5 67.5 77.5 87.5

segunda derivada
10
8
6
4
2
0
0 10 20 30 40 50 60 70 80
-2
10
8
6
4
2
0
0 10 20 30 40 50 60 70 80
-2
-4
-6
-8
-10