0.

04NaOH
0.04Ethac.
Temp. =25⁰C Run 1 160
Time (sec) Conc of (NaOH) 1/Ca k=Slop
140
0 0.0288 34.72222 0.092846003 f(x) = 0.0928460026869187 x + 32.35134
R² = 0.999226375750367
30 0.0272 36.76471 120

60 0.0255 39.21569 100

90 0.0239 41.841
80
120 0.0226 44.24779
150 0.0213 46.94836 60
180 0.0202 49.50495 40
210 0.0194 51.54639
240 0.0185 20
54.05405
270 0.0176 56.81818 0
0 200 400 600
300 0.0169 59.1716
330 0.0161 62.1118
360 0.0154 64.93506
390 0.0149 67.11409
420 0.0143 69.93007
450 0.0137 72.9927
480 0.0131 76.33588
510 0.0126 79.36508
540 0.0122 81.96721
570 0.0118 84.74576
600 0.0114 87.7193
630 0.0111 90.09009
660 0.0108 92.59259
690 0.0105 95.2381
720 0.0101 99.0099
750 0.0098 102.0408
780 0.0096 104.1667
810 0.0093 107.5269
840 0.0091 109.8901
870 0.0088 113.6364
900 0.0086 116.2791
930 0.0084 119.0476
960 0.0082 121.9512
990 0.008 125
1020 0.0078 128.2051
1050 0.0077 129.8701
1080 0.0075 133.3333
1110 0.0073 136.9863
1140 0.0072 138.8889
1170 0.0071 140.8451
1200
1230
1260
1290
 = 0.0928460026869187 x + 32.3513428881367
= 0.999226375750367

200 400 600 800 1000 1200 1400

 0.04NaOH θ=Cbo/Cao
0.05Ethac. 1.25
Temp. =25⁰C Run 2

Time (sec) Conc of (NaOH) Xa θ-Xa θ(1-Xa)

0 0.0359 0 1.25 1.25

30 0.0323 0.10028 1.150 1.125
60 0.0292 0.18663 1.063 1.017
90 0.0265 0.26184 0.988 0.923
120 0.024 0.33148 0.919 0.836
150 0.022 0.38719 0.863 0.766
180 0.0203 0.43454 0.815 0.707
210 0.0187 0.47911 0.771 0.651
240 0.0174 0.51532 0.735 0.606
270 0.0161 0.55153 0.698 0.561
300 0.0149 0.58496 0.665 0.519
330 0.0139 0.61281 0.637 0.484
360 0.0131 0.63510 0.615 0.456
390 0.0122 0.66017 0.590 0.425
420 0.0115 0.67967 0.570 0.400
450 0.0108 0.69916 0.551 0.376
480 0.0102 0.71588 0.534 0.355
510 0.0096 0.73259 0.517 0.334
540 0.0091 0.74652 0.503 0.317
570 0.0086 0.76045 0.490 0.299
600 0.0081 0.77437 0.476 0.282
630 0.0076 0.78830 0.462 0.265
660 0.0072 0.79944 0.451 0.251
690 0.007 0.80501 0.445 0.244
720 0.0066 0.81616 0.434 0.230
750 0.0064 0.82173 0.428 0.223
780 0.0061 0.83008 0.420 0.212
810 0.0057 0.84123 0.409 0.198
840 0.0054 0.84958 0.400 0.188
870 0.0052 0.85515 0.395 0.181
900 0.0049 0.86351 0.386 0.171
930 0.0047 0.86908 0.381 0.164
960 0.0046 0.87187 0.378 0.160
990 0.0044 0.87744 0.373 0.153
1020 0.0041 0.88579 0.364 0.143
1050 0.0039 0.89136 0.359 0.136
1080 0.0038 0.89415 0.356 0.132
1110 0.0036 0.89972 0.350 0.125
1140 0.0035 0.90251 0.347 0.122
1170 0.0034 0.90529 0.345 0.118
1200 1.00000 0.250 0.000
1230 1.00000 0.250 0.000
1260 1.00000 0.250 0.000
1290 1.00000 0.250 0.000
 Run 2

Ln( ( θ-Xa )/ ( θ(1-Xa) )) k*Ca0*(θ-1)=Slop k

0.000 0.00093 0.103637

0.022
0.045
0.069
0.095
0.119
0.143
0.169
1.200
0.193
0.220
1.000 f(x) = 0.000930141648814633 x − 0.0264724977055585
0.248 R² = 0.998725023914942
0.275
0.800
0.299
0.328
0.600
1/CA

0.354
0.382
0.400
0.408
0.437
0.463
0.200
0.492
0.523
0.000
0 200 400 600 800 1000 1200 1400
0.557 t (sec)
0.586
0.602
0.635
0.653
0.682
0.723
0.756
0.780
0.818
0.845
0.859
0.889
0.937
0.971
 0.989
1.028
1.048
1.069
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
0.03NaO
θ=Cbo/Cao
H
0.04Etha
1.33333333333333
c.
Temp.
Run3
=25⁰C
Time
Conc of (NaOH) Xa θ-Xa θ(1-Xa)
(sec)
0 0.0267 0 1.333 1.333
30 0.0245 0.0824 1.2509 1.22
60 0.0226 0.1536 1.1798 1.13
90 0.0208 0.2210 1.1124 1.04
120 0.0193 0.2772 1.0562 0.96
150 0.0178 0.3333 1.0000 0.89
180 0.0166 0.3783 0.9551 0.83
210 0.0155 0.4195 0.9139 0.77
240 0.0144 0.4607 0.8727 0.72
270 0.0136 0.4906 0.8427 0.68
300 0.0127 0.5243 0.8090 0.63
330 0.012 0.5506 0.7828 0.60
360 0.0112 0.5805 0.7528 0.56
390 0.0106 0.6030 0.7303 0.53
420 0.01 0.6255 0.7079 0.50
450 0.0095 0.6442 0.6891 0.47
480 0.009 0.6629 0.6704 0.45
510 0.0084 0.6854 0.6479 0.42
540 0.008 0.7004 0.6330 0.40
570 0.0076 0.7154 0.6180 0.38
600 0.0073 0.7266 0.6067 0.36
630 0.0069 0.7416 0.5918 0.34
660 0.0065 0.7566 0.5768 0.32
690 0.0063 0.7640 0.5693 0.31
720 0.0059 0.7790 0.5543 0.29
750 0.0056 0.7903 0.5431 0.28
780 0.0054 0.7978 0.5356 0.27
810 0.0052 0.8052 0.5281 0.26
840 0.005 0.8127 0.5206 0.25
870 0.0047 0.8240 0.5094 0.23
900 0.0045 0.8315 0.5019 0.22
930 0.0043 0.8390 0.4944 0.21
960 0.0041 0.8464 0.4869 0.20
990 0.004 0.8502 0.4831 0.20
1020 0.0038 0.8577 0.4757 0.19
1050 0.0036 0.8652 0.4682 0.18
1080 0.0035 0.8689 0.4644 0.17
1110 0.0033 0.8764 0.4569 0.16
1140 0.0032 0.8801 0.4532 0.16
1170 0.003 0.8876 0.4457 0.15
1200 0.0029 0.8914 0.4419 0.14
1230 0.0028 0.8951 0.4382 0.14
1260 0.0027 0.8989 0.4345 0.13
1290 0.0026 0.9026 0.4307 0.13
 Run3

Ln( ( θ-Xa )/ ( θ(1-Xa) ))

0 k*Ca0*(θ-1)=Slop k
0.022 0.00093840 0.105439
0.044
0.069
0.092
0.118
0.142 1.4
0.166
0.194 1.2
0.216 f(x) = 0.000938403585698803 x − 0.0340202783610883
R² = 0.998271712812973
0.243 1
Ln( ( θ-Xa )/ ( θ(1-Xa) ))

0.267
0.297 0.8
0.322
0.349 0.6
0.373
0.400 0.4
0.435
0.2
0.460
0.488
0
0.509 0 200 400 600 800 1000 1200 1400
t(sec)
0.541
0.575
0.593
0.632
0.664
0.686
0.710
0.735
0.775
0.803
0.834
0.866
0.883
0.919
0.957
0.977
1.020
1.042
1.090
1.116
1.142
1.170
1.199
 0.04NaOH
0.04Ethac.
Temp. =35⁰C 4th Run
Time (sec) Conc of (NaOH) 1/Ca k=Slop
0 0.0355 28.16901 0.215351925
250
30 0.0299 33.44482
60 0.0262 38.16794
200 f(x) = 0.215351924993649 x + 19.956
90 0.0235 42.55319 R² = 0.996548027267735
120 0.0212 47.16981
150 0.0192 52.08333 150
180 0.0175 57.14286
210 0.016 62.5 100
240 0.0147 68.02721
270 0.0135 74.07407 50
300 0.0125 80
330 0.0115 86.95652 0
360 0.0107 93.45794 0 100 200 300 400
390 0.01 100
420 0.0094 106.383
450 0.0088 113.6364
480 0.0083 120.4819
510 0.0078 128.2051
540 0.0074 135.1351
570 0.0071 140.8451
600 0.0067 149.2537
630 0.0064 156.25
660 0.0061 163.9344
690 0.0059 169.4915
720 0.0057 175.4386
750 0.0055 181.8182
780 0.0052 192.3077
810 0.0051 196.0784
840 0.0049 204.0816
870 0.0048 208.3333
900 0.0046 217.3913
f(x) = 0.215351924993649 x + 19.9565425313165
R² = 0.996548027267735

100 200 300 400 500 600 700 800 900 1000
 0.04NaOH
0.04Ethac.
Temp. =45⁰C 5th Run 250
Time (sec) Conc of (NaOH) 1/Ca k=Slop
0 0.0355 28.16901 0.209651715 200 f(x) = 0.209651714604839 x + 29.343319578574
30 0.0299 33.44482 R² = 0.998237937435096
60 0.0243 41.15226
150
90 0.0206 48.54369
120 0.018 55.55556
100
150 0.016 62.5
180 0.0146 68.49315
210 0.0133 75.18797 50
240 0.0123 81.30081
270 0.0115 86.95652 0
0 100 200 300 400 50
300 0.0107 93.45794
330 0.01 100
360 0.0095 105.2632
390 0.009 111.1111
420 0.0086 116.2791
450 0.0081 123.4568
480 0.0078 128.2051
510 0.0074 135.1351
540 0.0072 138.8889
570 0.0069 144.9275
600 0.0066 151.5152
630 0.0064 156.25
660 0.0059 169.4915
690 0.0056 178.5714
720 0.0055 181.8182
750 0.0053 188.6792
780 0.0051 196.0784
810 0.005 200
840 0.0049 204.0816
9651714604839 x + 29.3433195785743
237937435096

200 300 400 500 600 700 800 900

 k T 1/T Ln(k)
0.10064052011 298 0.0033557047 -2.2962
0.21535192499 308 0.0032467532 -1.535482
0.2096517146 318 0.0031446541 -1.562308
Slope=-E/R E Ko
-3516.479395 29237.62657 15171.53595
0
0.0031 0.00315 0.0032 0.00325 0.0033 0.00335 0.0034

-0.5

-1
Ln(k)

-1.5 f(x) = − 3516.47939492614 x + 9.62717631658187

R² = 0.739242931885164

-2

-2.5
1/T
 T= 25 C T=35 C T=45 C
k1 k2 k3 k4 k5
15171.535953 0.0928 0.10364 0.10544 0.2154 0.2097

0.00335 0.0034
 0.03NaOH θ=Cbo/Cao

0.04Ethac. 1.33333333333333

Temp.
Run3
=25⁰C

θ-Xa θ(1-Xa) Time (sec) Conc of (NaOH) Xa Ln( ( θ-Xa )/ ( θ(1-Xa) ))

1.333 1.333 0 0.0267 0 0

1.2509 1.22 30 0.0245 0.0824 0.022
1.1798 1.13 60 0.0226 0.1536 0.044
1.1124 1.04 90 0.0208 0.2210 0.069
1.0562 0.96 120 0.0193 0.2772 0.092
1.0000 0.89 150 0.0178 0.3333 0.118
0.9551 0.83 180 0.0166 0.3783 0.142
0.9139 0.77 210 0.0155 0.4195 0.166
0.8727 0.72 240 0.0144 0.4607 0.194
0.8427 0.68 270 0.0136 0.4906 0.216
0.8090 0.63 300 0.0127 0.5243 0.243
0.7828 0.60 330 0.012 0.5506 0.267
0.7528 0.56 360 0.0112 0.5805 0.297
0.7303 0.53 390 0.0106 0.6030 0.322
0.7079 0.50 420 0.01 0.6255 0.349
0.6891 0.47 450 0.0095 0.6442 0.373
0.6704 0.45 480 0.009 0.6629 0.400
0.6479 0.42 510 0.0084 0.6854 0.435
0.6330 0.40 540 0.008 0.7004 0.460
0.6180 0.38 570 0.0076 0.7154 0.488
0.6067 0.36 600 0.0073 0.7266 0.509
0.5918 0.34 630 0.0069 0.7416 0.541
0.5768 0.32 660 0.0065 0.7566 0.575
0.5693 0.31 690 0.0063 0.7640 0.593
0.5543 0.29 720 0.0059 0.7790 0.632
0.5431 0.28 750 0.0056 0.7903 0.664
0.5356 0.27 780 0.0054 0.7978 0.686
0.5281 0.26 810 0.0052 0.8052 0.710
0.5206 0.25 840 0.005 0.8127 0.735
0.5094 0.23 870 0.0047 0.8240 0.775
0.5019 0.22 900 0.0045 0.8315 0.803
0.4944 0.21 930 0.0043 0.8390 0.834
0.4869 0.20 960 0.0041 0.8464 0.866
0.4831 0.20 990 0.004 0.8502 0.883
0.4757 0.19 1020 0.0038 0.8577 0.919
0.4682 0.18 1050 0.0036 0.8652 0.957
0.4644 0.17 1080 0.0035 0.8689 0.977
0.4569 0.16 1110 0.0033 0.8764 1.020
0.4532 0.16 1140 0.0032 0.8801 1.042
0.4457 0.15 1170 0.003 0.8876 1.090
0.4419 0.14 1200 0.0029 0.8914 1.116
0.4382 0.14 1230 0.0028 0.8951 1.142
0.4345 0.13 1260 0.0027 0.8989 1.170
0.4307 0.13 1290 0.0026 0.9026 1.199
3

k*Ca0*(θ-1)=Slop k

0.00093840 0.10544