1

Thermodynamique : principales grandeurs 1 D enitions

Monobare : Pe = cte. Isobare : P = cte. Isotherme : T = cte. Monotherme : Te = cte.

2 Tableau r ecapitulatif
W / W D enition W = Pe dV Q / Q Q = dU + P dV Q = U W dU / U dU = W + Q U = W + Q dS = dS / S dU P + dV T T dH V dP = T T nR ln(T V 1 )+ S0 S= 1 nR ln(P V ) + S0 = 1 nR = ln(T P 1 )+S0 1

G.P.

dU = CV dT = ncV,m dT

non Q.S. Q.S. G.P.

W = PB (VB VA )
B

W =
A

P dV VB VA Q = ncV,m dT + P dV = ncP,m dT V dP
B Q Q , S = T T A Qsource dSsource = Te

W = nRTA ln = nrTA ln

PB PA

R eversible

dS =

Monobare Isobare Q.S.+G.P Isotherme Q.S.+G.P

W = Pe dV

Q = H = Cp (TB TA ) Q = H = Cp (TB TA ) S = mCp ln TB TA

W = PA (VB VA ) W = nRT ln = nrT ln VB VA Q = W U = H = 0 VB VA ( R eversible + G.P. ) S = nR ln Qsour. Te

PB PA

Monotherme source Te Isochore Adiabatique G.P.+Q.S. W = U W =0 Q = U Q=0 nRT (P V ) = 1 1 PB VB PA VA = 1 U = ncV,m (TB TA )

dSsour. dSe

Se =

Qsour. Q = Te Te

U =