01

GUEZOURI A. Lyce Maraval - Oran

-
- 1 :
.............. .................. ........... ......... .
- 2
:

)(aq

= I2(aq) + 2 SO4

)S2O82 (aq

)(aq

2I

( .
.
(
( .
( I2 .
3 C6H8O6 . C6H6O6
.
4 Cr2O7 2(aq) + H+(aq) + .. = Cr3+(aq) + H2O(aq) :
5
( .
(
. . .6
(
(
7 .
-

8 )(

Ox/Red

) MnO4 (aq) / Mn2+ (aq ) . MnO4 (aq) / MnO2 (s

.
1

 - 1 ) MnO4 (aq) / Mn2+(aq

.
- 2 ) ) ( MnO4 (aq) / MnO2 (s MnO4 MnO2 ) (
) . O2/ H2O (
.
- 3 ) MnO4 (aq) / Mn2+ (aq
) MnO4 (aq) / MnO2 (s
9 H2O2 H2O2 2 H2O2(l) = 2H2O(l) + O2(g) :
: ) (S0 3,10 g H2O2 . 100 mL
- 1 ). (S0
- 2 ) (S C = 9,13 .10-2 mol/L . 200 mL
3 O2(g) / H2O2(aq) : ) H2O2(aq) / H2O(l
.
10 )( )( :
I2
11 V0 = 25 mL ) . (S0
)) (I ( .
)) (2 Na+(aq) , S2O32(aq . CR = 5 .10 3 mol/L

.
VE = 20,4 mL .
:

)2 S2O32(aq) + I2(aq) = S4O62 (aq) + 2 I(aq

- 1 .
- 2( .
(
( .
- 3 C0 . V0 , CR , VE
- 4 C0 1 L ). (S0
M = 127 g/mol
2

 1,450 g CnH2nO 3,575 g

- 12
. Cu2O
:
)CnH2nO(aq) + 2 Cu2+(aq) + 5 OH(aq) = Cu2O(S) + CnH2n-1O2 (aq) + 3 H2O(l
.
-1

(
(

- 2 .
- 3(
( .
13 C . C6H8O6
. C
V = 500 mL
). (S
VR = 25 mL ). (S
. .

VE = 14,5 mL . C2 = 10 2 mol/L
C6H8O6(aq) + I2(aq) = C6H6O6(aq) + 2 H+(aq) + 2 I(aq) :
1 .
- 2( .
(
3 ). (S
4 . C
14
. .
) (SO2 2 m3 250 mL
). (S
) (S ) (S0 C0 = 10 4 mol/L .
2 MnO4(aq) + 5 SO2(aq) + 2 H2O(l) = 2 Mn2+(aq) + 5 SO4 2 (aq) + 4 H+(aq) :
1

Ox/Red

MnO4(aq) / Mn2+(aq) : )SO4 2 (aq) / SO2(aq

.
- 2 .
- 3(
(
( . 5 n(MnO4) = 2 n(SO2) :
- 4( . VE = 8,8 mL
3


( ). (S
5 ) 20 g / m3 (SO2 2.10 5 g . SO2
( SO2 1 m3 .
(