Arias Ordoñ ez Daniela

Integrantes
Peñ a Varon Camilo

Datos Especie Formula

Fase Gaseosa di-t-butil peró xido C8H18O2
M_A 146.2 Acetona C3H6O
R [atm.L/mol.K] 0.082 Etano C2H6
R [J/mol.K] 8.3145
T_o [K] 298.15
X 0.4
W_A [lb/h] 45
W_A [g/h] 20411.55 Tabla esteq
T [°F] 285 i Formula
T [°C] 140.56 A C8H18O2
T [K] 413.71 B C3H6O
P [KPa] 500 C C2H6
P [atm] 4.93
Log A 15.33
E_a [J/mol] 152300

X T[K] k [1/h] C_A [mol/L] -r_A [mol/L.h]

0 413.71 4.543.E-01 0.145 0.0661
0.01 420.22 9.025.E-01 0.139 0.1254
0.02 426.75 1.758.E+00 0.133 0.2336
0.03 433.29 3.361.E+00 0.127 0.4272
0.04 439.85 6.311.E+00 0.122 0.7675
0.05 446.41 1.164.E+01 0.116 1.3557
0.06 452.99 2.113.E+01 0.111 2.3564
0.07 459.59 3.775.E+01 0.107 4.0326
0.08 466.19 6.641.E+01 0.102 6.7986
0.09 472.81 1.151.E+02 0.098 11.2986
0.1 479.44 1.967.E+02 0.094 18.5196
0.11 486.09 3.317.E+02 0.090 29.9550
0.12 492.75 5.519.E+02 0.087 47.8358
0.13 499.42 9.069.E+02 0.083 75.4547
0.14 506.11 1.472.E+03 0.080 117.6152
0.15 512.81 2.362.E+03 0.077 181.2464
0.16 519.52 3.747.E+03 0.074 276.2358
0.17 526.24 5.881.E+03 0.071 416.5455
0.18 532.98 9.132.E+03 0.068 621.6935
0.19 539.73 1.404.E+04 0.065 918.6998
0.2 546.50 2.137.E+04 0.063 1344.6184
0.21 553.28 3.222.E+04 0.061 1949.8034
0.22 560.07 4.815.E+04 0.058 2802.0819
0.23 566.88 7.130.E+04 0.056 3992.0404
0.24 573.70 1.047.E+05 0.054 5639.6656
0.25 580.54 1.525.E+05 0.052 7902.6180
0.26 587.38 2.203.E+05 0.050 10986.4562
0.27 594.25 3.157.E+05 0.048 15157.1745
0.28 601.12 4.492.E+05 0.046 20756.4585
0.29 608.01 6.345.E+05 0.044 28220.1098
0.3 614.92 8.899.E+05 0.043 38100.1337
0.31 621.83 1.239.E+06 0.041 51091.0282
0.32 628.76 1.715.E+06 0.040 68060.8485
0.33 635.71 2.358.E+06 0.038 90087.6604
0.34 642.67 3.221.E+06 0.037 118502.0154
0.35 649.64 4.374.E+06 0.035 154936.1042
0.36 656.63 5.905.E+06 0.034 201380.2450
0.37 663.64 7.927.E+06 0.033 260247.3561
0.38 670.65 1.058.E+07 0.032 334446.0321
0.39 677.68 1.405.E+07 0.030 427462.7961
0.4 684.73 1.855.E+07 0.029 543454.0250
DH°fi_298,15K [KJ/mol] Cp^GI_400K [J/mol.K] Coeficiente
-341 276.78 -1
-217.1 92.06 2
-83.82 65.46 1

𝐴→2𝐵+𝐶
Tabla estequiométrica
Coeficiente y_io Q_i
1 1 1
2 0 0
1 0 0

F_Ao/-r_A [L] DV [L] V_acum [L]

2112.90034 DV reque
1112.95898 1.613.E+01 16.13
597.59838 8.553.E+00 24.68 16
326.82673 4.622.E+00 29.30
181.91611 2.544.E+00 31.85 14
102.98077 1.424.E+00 33.27
59.24824 8.111.E-01 34.08 12
34.62169 4.693.E-01 34.55
10
20.53566 2.758.E-01 34.83
DV [L]

12.35675 1.645.E-01 34.99 8

7.53870 9.948.E-02 35.09
4.66078 6.100.E-02 35.15 6
2.91861 3.790.E-02 35.19
1.85030 2.384.E-02 35.22 4
1.18704 1.519.E-02 35.23
2
0.77030 9.787.E-03 35.24
0.50542 6.379.E-03 35.25 0
0.33517 4.203.E-03 35.25 0 0.05 0.1
0.22457 2.799.E-03 35.25
0.15197 1.883.E-03 35.26
0.10383 1.279.E-03 35.26
0.07160 8.772.E-04 35.26
0.04983 6.071.E-04 35.26
0.03497 4.240.E-04 35.26
0.02476 2.986.E-04 35.26
0.01767 2.121.E-04 35.26
0.01271 1.519.E-04 35.26
0.00921 1.096.E-04 35.26
0.00673 7.969.E-05 35.26
0.00495 5.837.E-05 35.26
0.00366 4.306.E-05 35.26
0.00273 3.199.E-05 35.26
0.00205 2.392.E-05 35.26
0.00155 1.801.E-05 35.26
0.00118 1.364.E-05 35.26
0.00090 1.040.E-05 35.26
0.00069 7.972.E-06 35.26
0.00054 6.149.E-06 35.26
0.00042 4.770.E-06 35.26
0.00033 3.720.E-06 35.26
0.00026 2.918.E-06 35.26
 Cá lculos
DH°R_298,15K [KJ/mol] -177.02
DH°R_298,15K [J/mol] -177020
DCp_400K [J/mol.K]] -27.2
∑Q_i.Cp_i [J/mol.K] 276.78
d 2
e 2
A [1/s] 2.14E+15
A[1/h] 7.70E+18
C_Ao [mol/L] 0.145
F_Ao [mol/h] 139.61

DV requerido en función de la conversión

16

14

12

10
DV [L]

0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35 0.4

El volumen necesario para alcanzar una conversion del

40% en un reactor PFR es de 35,26 L a diferencia del
ejemplo que emplea un reactor de 41,44L debido a que
las condiciones de alimentacion y la temperatura de
entrada son distintas.
El volumen necesario para alcanzar una conversion del
40% en un reactor PFR es de 35,26 L a diferencia del
ejemplo que emplea un reactor de 41,44L debido a que
las condiciones de alimentacion y la temperatura de
entrada son distintas.
0.35 0.4