rz [mol/ Lnk LnCx LnCy

T(°C) Cx [mol/L] Cy [mol/L]

(L*min)]
20 0.1 0.75 0.00189 1 -2.30258509 -0.28768207
20 0.25 0.5 0.00163 1 -1.38629436 -0.69314718
20 0.5 0.25 0.00081 1 -0.28768207 -2.30258509
20 0.75 0.1 0.00025
30 0.1 0.75 0.00306 1 -2.30258509 -0.28768207
30 0.25 0.5 0.00263 1 -1.38629436 -0.69314718
30 0.5 0.25 0.00132 1 -0.28768207 -2.30258509
30 0.75 0.1 0.00041
40 0.1 0.75 0.0048 1 -2.30258509 -0.28768207
40 0.25 0.5 0.00413 1 -1.38629436 -0.69314718
40 0.5 0.25 0.00206 1 -0.28768207 -2.30258509
40 0.75 0.1 0.00064
50 0.1 0.75 0.00732 1 -2.30258509 -0.28768207
50 0.25 0.5 0.0063 1 -1.38629436 -0.69314718
50 0.5 0.25 0.00315 1 -0.28768207 -2.30258509
50 0.75 0.1 0.00098

Entalpía de Temperatura de
Peso molecular Temperatura de Densidad
formación a Cp [cal/mol] congelación
[g/mol] ebullición [°C] [g/cm3]
25°C [kcal/mol] [°C]
0.2238T -
X 50 -10 -2 130 1
59.057
Y 75 -25 0.3566T - 91.41 -3 120 1
0.4254T -
Z 200 -40 -5 110 1
101.89
Agua 18 -68 18 0 100 1
 Lnrz K
-6.27117845 LnK -4.66867156 0.00938473 lnk
-6.41917526 a 0.5071628 -4.66867156
-8.29404964 b 1.51111742 -4.21920405
K -3.75777503
-5.78934036 LnK -4.21920405 0.01471035 -3.33912927
-5.94077143 a 0.49537455
-7.7993534 b 1.49294764
K
0 1/T vs LnK
-5.33913936 LnK -3.75777503 0.0233356 0.00305 0.0031 0.00315 0.0032 0.00325 0.0033
-0.5
-5.48947787 a 0.4994397
-1
-7.35404238 b 1.4994397
K -1.5

-4.91714495 LnK -3.33912927 0.03546783 -2

-5.06720565 a 0.49837236 -2.5
-6.92795799 b 1.4963425 -3
-3.5 f(x) = − 4214.79714398977 x + 9.6995943517
-4 R² = 0.999649344485958

-4.5
-5
 T 1/T Inter 9.6996
293.15 0.00341122 EA 8374.8076
303.15 0.0032987 A 16311.0815
313.15 0.00319336 a 0.5
323.15 0.00309454 b 1.5

1/T vs LnK
.00315 0.0032 0.00325 0.0033 0.00335 0.0034 0.00345

4214.79714398977 x + 9.69959435176278
999649344485958
Volumen (L) 300 nx0 ny0
Ti (°C) 17 600 1200
Cx0 mol/L 2 Cx Cy
Cy0 mol/L 4 (600-600f)/ (1200-400f)/
300 300
Inter 9.6996
EA 8374.8076 𝑑𝑐𝑥=(−600)/300 𝑑𝑓
A 16311.0815
a 0.5
b 1.5 𝑑𝑓/𝑑𝑡=(3∗300)/600 𝑘𝐶𝑥∗𝐶𝑦

Balance de Masa
𝑑𝑓/𝑑𝑡=3 300/600 𝑘 (600−600𝑓)/300 (1200−400𝑓)/300
 Balance de
𝑑𝑓/𝑑𝑡=3 300/600∗𝑘∗(600−60

0
Volumen (L) 300
Ti (°C) 17
Cx0 mol/L 2
Cy0 mol/L 4

Inter 9.6996
EA 8374.8076
A 16311.08146037
a 0.5 𝑑𝑇/𝑑𝑡=(∆𝐻𝑟/𝑣_𝑙 𝑛
b 1.5 (𝑑𝑓_𝑙)/𝑑𝑡)/(∑24_(𝑖
𝐶_(𝑝.𝑖) ) )
Entalpía de Temperatura
Temperatura
Peso molecular formación a de Densidad
Cp [cal/mol] de ebullición
[g/mol] 25°C congelación [g/cm3]
[°C]
[kcal/mol] [°C]
0.2238T -
X 50 -10 -2 130 1
59.057
0.3566T -
Y 75 -25 -3 120 1
91.41 ∆𝐻_(17°𝐶)=∆𝐻_𝐹+∫_
0.4254T -
Z 200 -40 -5 110 1
101.89
Agua 18 -68 18 0 100 1
∆𝐻_𝐹=∆𝐻_𝑝𝑟𝑜𝑑
𝑣𝑜𝑠

∆𝐻_(17°𝐶)=20000+∫24_290.15^298.15▒
Masa x 30000
Volumen x 30000
Masa y 90000 Cp -657.20964
Volumen Y 90000 ∆𝐻_(17°𝐶) 19342.7904
Volumen H2O 180000
Moles H20 10000

𝑑𝑇/𝑑𝑡=((19342.7904 )/(−3) 600∗3 300/600∗𝑘∗((600−600𝑓)/300)^0.5∗((1200−400𝑓)/300)^1.

 Balance de Masa
𝑡=3 300/600∗𝑘∗(600−600𝑓)/300∗(1200−400𝑓)/300

𝑑𝑇/𝑑𝑡=(∆𝐻𝑟/𝑣_𝑙 𝑛_𝑙^0
(𝑑𝑓_𝑙)/𝑑𝑡)/(∑24_(𝑖=1)^𝑛▒(𝑛_𝑖
𝐶_(𝑝.𝑖) ) )

17 25 °C

290.15 298.15 K

∆𝐻_(17°𝐶)=∆𝐻_𝐹+∫_298.15^290.15▒∑▒𝐶𝑝

∆𝐻_𝐹=∆𝐻_𝑝𝑟𝑜𝑑𝑢𝑐𝑡𝑜𝑠−∆𝐻_𝑟𝑒𝑎𝑐𝑡𝑖
𝑣𝑜𝑠

ΔHf 20 kcal/mol

00+∫24_290.15^298.15▒ 〖 3(0.2238𝑇−59.057)+2(0.3566𝑇 - 91.41)+1.5(0.4254𝑇 - 101.89 〗 )𝑑𝑇

Balance de Energia

0.5∗((1200−400𝑓)/300)^1.5)/(((600−600𝑓)(0.2238𝑇 - 59.057))+((1200−400𝑓)(0.3566𝑇 - 91.41))+(300𝑓)(0.4254𝑇 - 101.89)+(1

(300𝑓)(0.4254𝑇 - 101.89)+(18)(10000))
 Inter 9.6996 Balance de Masa
EA 8374.8076
𝑑𝑓/𝑑𝑡=3 300/600 𝑘 (600−600𝑓)/300 (1200−400𝑓)/300
A 16311.08146
a 0.5
b 1.5
Volumen (L) 300 Balance de Energia
Ti (°C) 17
Cx0 mol/L
𝑑𝑇/𝑑𝑡=((19342.7904 2 )/(−3) 600∗3 300/600∗𝑘∗((600−600𝑓)/300)^0.5∗((1200−400𝑓)/300)^1.5)/(((600−600𝑓)(0.2238𝑇 -
Cy0 mol/L 4
Cp -657.20964
∆𝐻_(17°𝐶) 19342.79036
Intervalo 0.01

t f T df/dt dT/dt
T,f
0 0 290.15 0.090657702 -1.77132041
0.01 0.000906577 290.132287 0.090495234 -1.76825022 1.2
0.02 0.001811529 290.114604 0.090333284 -1.76518956 1
0.03 0.002714862 290.096952 0.090171849 -1.76213839
0.8
0.04 0.003616581 290.079331 0.090010926 -1.75909665
0.05 0.00451669 290.06174 0.089850514 -1.75606432 0.6

f
0.06 0.005415195 290.044179 0.089690611 -1.75304135 0.4
0.07 0.006312101 290.026649 0.089531213 -1.7500277
0.2
0.08 0.007207413 290.009149 0.089372318 -1.74702331
0.09 0.008101137 289.991678 0.089213925 -1.74402816 0
0 10 20 30
0.1 0.008993276 289.974238 0.089056031 -1.7410422
tiem
0.11 0.009883836 289.956828 0.088898633 -1.73806539
0.12 0.010772822 289.939447 0.088741729 -1.73509769
f
0.13 0.01166024 289.922096 0.088585318 -1.73213906
0.14 0.012546093 289.904775 0.088429396 -1.72918945
0.15 0.013430387 289.887483 0.088273962 -1.72624884
0.16 0.014313126 289.87022 0.088119014 -1.72331716
0.17 0.015194317 289.852987 0.087964548 -1.7203944
0.18 0.016073962 289.835783 0.087810564 -1.71748051
0.19 0.016952068 289.818608 0.087657058 -1.71457544
0.2 0.017828638 289.801463 0.087504029 -1.71167917
0.21 0.018703679 289.784346 0.087351474 -1.70879164
0.22 0.019577193 289.767258 0.087199392 -1.70591283
0.23 0.020449187 289.750199 0.08704778 -1.70304269
0.24 0.021319665 289.733168 0.086896636 -1.70018119
0.25 0.022188631 289.716167 0.086745959 -1.69732828
0.26 0.023056091 289.699193 0.086595745 -1.69448394
0.27 0.023922048 289.682249 0.086445993 -1.69164811
0.28 0.024786508 289.665332 0.0862967 -1.68882078
0.29 0.025649475 289.648444 0.086147866 -1.68600189
 0.3 0.026510954 289.631584 0.085999487 -1.68319141
0.31 0.027370949 289.614752 0.085851562 -1.68038931
0.32 0.028229465 289.597948 0.085704089 -1.67759555
0.33 0.029086505 289.581172 0.085557065 -1.67481009
0.34 0.029942076 289.564424 0.085410489 -1.67203289
0.35 0.030796181 289.547704 0.085264358 -1.66926392
0.36 0.031648825 289.531011 0.085118672 -1.66650315
0.37 0.032500011 289.514346 0.084973427 -1.66375054
0.38 0.033349746 289.497708 0.084828622 -1.66100606
0.39 0.034198032 289.481098 0.084684255 -1.65826966
0.4 0.035044874 289.464516 0.084540323 -1.65554132
0.41 0.035890278 289.44796 0.084396826 -1.65282099
0.42 0.036734246 289.431432 0.084253761 -1.65010865
0.43 0.037576783 289.414931 0.084111126 -1.64740427
0.44 0.038417895 289.398457 0.08396892 -1.6447078
0.45 0.039257584 289.38201 0.08382714 -1.64201921
0.46 0.040095855 289.36559 0.083685785 -1.63933847
0.47 0.040932713 289.349196 0.083544852 -1.63666555
0.48 0.041768162 289.33283 0.083404341 -1.63400041
0.49 0.042602205 289.31649 0.083264248 -1.63134302
0.5 0.043434847 289.300176 0.083124573 -1.62869335
0.51 0.044266093 289.283889 0.082985314 -1.62605136
0.52 0.045095946 289.267629 0.082846468 -1.62341702
0.53 0.045924411 289.251395 0.082708034 -1.6207903
0.54 0.046751491 289.235187 0.08257001 -1.61817117
0.55 0.047577191 289.219005 0.082432395 -1.6155596
0.56 0.048401515 289.202849 0.082295186 -1.61295554
0.57 0.049224467 289.18672 0.082158382 -1.61035898
0.58 0.050046051 289.170616 0.082021981 -1.60776988
0.59 0.050866271 289.154538 0.081885982 -1.60518821
0.6 0.051685131 289.138487 0.081750382 -1.60261394
0.61 0.052502635 289.12246 0.081615181 -1.60004703
0.62 0.053318786 289.10646 0.081480375 -1.59748746
0.63 0.05413359 289.090485 0.081345965 -1.59493519
0.64 0.05494705 289.074536 0.081211947 -1.5923902
0.65 0.055759169 289.058612 0.081078321 -1.58985245
0.66 0.056569952 289.042713 0.080945084 -1.58732192
0.67 0.057379403 289.02684 0.080812235 -1.58479857
0.68 0.058187526 289.010992 0.080679772 -1.58228237
0.69 0.058994323 288.995169 0.080547694 -1.57977331
0.7 0.0597998 288.979372 0.080415999 -1.57727133
0.71 0.06060396 288.963599 0.080284686 -1.57477643
0.72 0.061406807 288.947851 0.080153752 -1.57228856
0.73 0.062208345 288.932128 0.080023197 -1.5698077
0.74 0.063008577 288.91643 0.079893018 -1.56733381
0.75 0.063807507 288.900757 0.079763215 -1.56486688
0.76 0.064605139 288.885108 0.079633785 -1.56240687
0.77 0.065401477 288.869484 0.079504727 -1.55995376
0.78 0.066196524 288.853885 0.079376039 -1.55750751
0.79 0.066990284 288.838309 0.07924772 -1.5550681
0.8 0.067782762 288.822759 0.079119768 -1.55263549
0.81 0.068573959 288.807232 0.078992183 -1.55020967
0.82 0.069363881 288.79173 0.078864961 -1.54779061
0.83 0.070152531 288.776252 0.078738102 -1.54537827
0.84 0.070939912 288.760799 0.078611605 -1.54297263
0.85 0.071726028 288.745369 0.078485467 -1.54057366
0.86 0.072510883 288.729963 0.078359687 -1.53818134
0.87 0.073294479 288.714581 0.078234264 -1.53579564
0.88 0.074076822 288.699223 0.078109197 -1.53341652
0.89 0.074857914 288.683889 0.077984483 -1.53104398
0.9 0.075637759 288.668579 0.077860122 -1.52867797
0.91 0.07641636 288.653292 0.077736112 -1.52631847
0.92 0.077193721 288.638029 0.077612451 -1.52396546
0.93 0.077969846 288.622789 0.077489139 -1.52161891
0.94 0.078744737 288.607573 0.077366173 -1.5192788
0.95 0.079518399 288.59238 0.077243552 -1.51694509
0.96 0.080290834 288.577211 0.077121275 -1.51461777
0.97 0.081062047 288.562065 0.07699934 -1.5122968
0.98 0.081832041 288.546942 0.076877747 -1.50998216
0.99 0.082600818 288.531842 0.076756493 -1.50767384
1 0.083368383 288.516765 0.076635578 -1.50537179
1.01 0.084134739 288.501711 0.076514999 -1.503076
1.02 0.084899889 288.486681 0.076394756 -1.50078644
1.03 0.085663836 288.471673 0.076274847 -1.49850309
1.04 0.086426585 288.456688 0.076155271 -1.49622592
1.05 0.087188137 288.441725 0.076036026 -1.49395491
1.06 0.087948498 288.426786 0.075917112 -1.49169003
1.07 0.088707669 288.411869 0.075798526 -1.48943127
1.08 0.089465654 288.396975 0.075680268 -1.48717859
1.09 0.090222457 288.382103 0.075562336 -1.48493197
1.1 0.09097808 288.367254 0.075444729 -1.48269138
1.11 0.091732527 288.352427 0.075327445 -1.48045682
1.12 0.092485802 288.337622 0.075210484 -1.47822824
1.13 0.093237907 288.32284 0.075093844 -1.47600563
1.14 0.093988845 288.30808 0.074977523 -1.47378896
1.15 0.09473862 288.293342 0.074861521 -1.47157821
1.16 0.095487236 288.278626 0.074745836 -1.46937337
1.17 0.096234694 288.263932 0.074630467 -1.46717439
1.18 0.096980999 288.249261 0.074515413 -1.46498127
1.19 0.097726153 288.234611 0.074400672 -1.46279397
 1.2 0.098470159 288.219983 0.074286243 -1.46061249
1.21 0.099213022 288.205377 0.074172125 -1.45843678
1.22 0.099954743 288.190792 0.074058317 -1.45626684
1.23 0.100695326 288.17623 0.073944817 -1.45410263
1.24 0.101434774 288.161689 0.073831625 -1.45194415
1.25 0.102173091 288.147169 0.073718739 -1.44979135
1.26 0.102910278 288.132671 0.073606157 -1.44764423
1.27 0.10364634 288.118195 0.073493879 -1.44550277
1.28 0.104381278 288.10374 0.073381904 -1.44336693
1.29 0.105115097 288.089306 0.07327023 -1.44123669
1.3 0.1058478 288.074894 0.073158856 -1.43911205
1.31 0.106579388 288.060503 0.073047781 -1.43699297
1.32 0.107309866 288.046133 0.072937004 -1.43487943
1.33 0.108039236 288.031784 0.072826523 -1.43277142
1.34 0.108767501 288.017456 0.072716338 -1.4306689
1.35 0.109494665 288.00315 0.072606447 -1.42857187
1.36 0.110220729 287.988864 0.072496849 -1.42648029
1.37 0.110945698 287.974599 0.072387544 -1.42439416
1.38 0.111669573 287.960355 0.072278529 -1.42231344
1.39 0.112392358 287.946132 0.072169804 -1.42023812
1.4 0.113114056 287.93193 0.072061367 -1.41816818
1.41 0.11383467 287.917748 0.071953219 -1.41610359
1.42 0.114554202 287.903587 0.071845356 -1.41404434
1.43 0.115272656 287.889446 0.071737779 -1.41199041
1.44 0.115990034 287.875326 0.071630486 -1.40994177
1.45 0.116706339 287.861227 0.071523476 -1.40789841
1.46 0.117421573 287.847148 0.071416749 -1.4058603
1.47 0.118135741 287.833089 0.071310302 -1.40382743
1.48 0.118848844 287.819051 0.071204135 -1.40179978
1.49 0.119560885 287.805033 0.071098247 -1.39977733
1.5 0.120271868 287.791035 0.070992637 -1.39776005
1.51 0.120981794 287.777058 0.070887303 -1.39574793
1.52 0.121690667 287.7631 0.070782245 -1.39374096
1.53 0.12239849 287.749163 0.070677462 -1.3917391
1.54 0.123105264 287.735246 0.070572952 -1.38974234
1.55 0.123810994 287.721348 0.070468715 -1.38775067
1.56 0.124515681 287.707471 0.070364749 -1.38576405
1.57 0.125219328 287.693613 0.070261054 -1.38378249
1.58 0.125921939 287.679775 0.070157628 -1.38180595
1.59 0.126623515 287.665957 0.070054471 -1.37983441
1.6 0.12732406 287.652159 0.069951581 -1.37786786
1.61 0.128023576 287.63838 0.069848957 -1.37590629
1.62 0.128722065 287.624621 0.069746599 -1.37394966
1.63 0.129419531 287.610882 0.069644505 -1.37199797
1.64 0.130115976 287.597162 0.069542674 -1.3700512
1.65 0.130811403 287.583461 0.069441106 -1.36810932
1.66 0.131505814 287.56978 0.069339799 -1.36617232
1.67 0.132199212 287.556118 0.069238753 -1.36424018
1.68 0.1328916 287.542476 0.069137966 -1.36231289
1.69 0.133582979 287.528853 0.069037438 -1.36039042
1.7 0.134273354 287.515249 0.068937167 -1.35847276
1.71 0.134962725 287.501664 0.068837153 -1.35655989
1.72 0.135651097 287.488098 0.068737395 -1.35465179
1.73 0.136338471 287.474552 0.068637891 -1.35274845
1.74 0.13702485 287.461024 0.068538641 -1.35084985
1.75 0.137710236 287.447516 0.068439644 -1.34895597
1.76 0.138394633 287.434026 0.068340898 -1.34706679
1.77 0.139078042 287.420556 0.068242404 -1.3451823
1.78 0.139760466 287.407104 0.068144159 -1.34330248
1.79 0.140441907 287.393671 0.068046164 -1.34142731
1.8 0.141122369 287.380257 0.067948416 -1.33955678
1.81 0.141801853 287.366861 0.067850916 -1.33769087
1.82 0.142480362 287.353484 0.067753662 -1.33582956
1.83 0.143157899 287.340126 0.067656654 -1.33397284
1.84 0.143834465 287.326786 0.06755989 -1.33212068
1.85 0.144510064 287.313465 0.06746337 -1.33027308
1.86 0.145184698 287.300162 0.067367093 -1.32843002
1.87 0.145858369 287.286878 0.067271057 -1.32659148
1.88 0.146531079 287.273612 0.067175262 -1.32475744
1.89 0.147202832 287.260364 0.067079708 -1.32292789
1.9 0.147873629 287.247135 0.066984393 -1.32110281
1.91 0.148543473 287.233924 0.066889316 -1.31928219
1.92 0.149212366 287.220731 0.066794476 -1.31746601
1.93 0.149880311 287.207557 0.066699873 -1.31565425
1.94 0.15054731 287.1944 0.066605506 -1.3138469
1.95 0.151213365 287.181262 0.066511374 -1.31204395
1.96 0.151878478 287.168141 0.066417476 -1.31024537
1.97 0.152542653 287.155039 0.066323811 -1.30845116
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5.25 0.330440829 283.626609 0.044583832 -0.88892537
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 5.7 0.350052302 283.235375 0.042560244 -0.84953051
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6 0.362635593 282.984118 0.041297136 -0.8249072
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7.05 0.403882225 282.159271 0.037343415 -0.74766042
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7.94 0.435824607 281.519187 0.034469892 -0.69134701
7.95 0.436169305 281.512273 0.034439747 -0.69075545
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7.98 0.437201595 281.491568 0.034349578 -0.6889859
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8 0.437888287 281.477795 0.034289687 -0.68781045
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8.39 0.451043793 281.213818 0.033156073 -0.66554924
 8.4 0.451375354 281.207163 0.033127838 -0.66499447
8.41 0.451706632 281.200513 0.033099644 -0.66444048
8.42 0.452037629 281.193868 0.03307149 -0.66388727
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8.54 0.45598774 281.114565 0.032736755 -0.65730879
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8.56 0.456642199 281.101424 0.032681519 -0.65622304
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8.6 0.457947808 281.075208 0.032571516 -0.65406058
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8.65 0.459573647 281.042558 0.032434884 -0.65137432
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8.68 0.460545878 281.023033 0.032353365 -0.64977146
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8.7 0.461192674 281.010043 0.032299211 -0.64870657
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8.75 0.462804936 280.977661 0.032164487 -0.64605713
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8.8 0.464410481 280.945411 0.032030703 -0.64342581
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8.85 0.466009355 280.913292 0.031897849 -0.64081245
8.86 0.466328334 280.906884 0.031871388 -0.64029192
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8.93 0.468553795 280.862172 0.031687193 -0.63666796
8.94 0.468870667 280.855805 0.031661025 -0.63615307
8.95 0.469187277 280.849444 0.031634893 -0.63563887
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8.98 0.470135541 280.83039 0.031556713 -0.63410044
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9 0.470766416 280.817713 0.031504773 -0.63307829
9.01 0.471081464 280.811382 0.031478856 -0.63256824
9.02 0.471396252 280.805057 0.031452975 -0.63205889
9.03 0.471710782 280.798736 0.03142713 -0.63155023
9.04 0.472025053 280.792421 0.03140132 -0.63104225
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9.07 0.47296632 280.773505 0.031324103 -0.62952241
9.08 0.473279561 280.767209 0.031298434 -0.62901716
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9.1 0.473905273 280.754634 0.031247203 -0.62800869
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9.12 0.474529962 280.742079 0.031196111 -0.62700293
9.13 0.474841923 280.735809 0.031170618 -0.62650106
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9.2 0.477018532 280.692059 0.030993134 -0.62300673
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9.23 0.47794757 280.673384 0.030917585 -0.62151913
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9.27 0.479182768 280.648552 0.030817332 -0.61954488
9.28 0.479490941 280.642357 0.030792353 -0.61905296
9.29 0.479798865 280.636166 0.030767408 -0.61856169
 9.3 0.480106539 280.629981 0.030742497 -0.61807107
9.31 0.480413964 280.6238 0.030717619 -0.61758111
9.32 0.48072114 280.617624 0.030692775 -0.61709179
9.33 0.481028068 280.611453 0.030667965 -0.61660312
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9.35 0.481641179 280.599126 0.030618444 -0.61562771
9.36 0.481947363 280.59297 0.030593733 -0.61514097
9.37 0.482253301 280.586819 0.030569056 -0.61465488
9.38 0.482558991 280.580672 0.030544412 -0.61416943
9.39 0.482864435 280.57453 0.030519802 -0.61368462
9.4 0.483169634 280.568393 0.030495224 -0.61320045
9.41 0.483474586 280.562261 0.030470679 -0.61271691
9.42 0.483779293 280.556134 0.030446167 -0.61223401
9.43 0.484083754 280.550012 0.030421688 -0.61175175
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9.54 0.487416748 280.482983 0.030154568 -0.60648843
9.55 0.487718294 280.476918 0.030130479 -0.60601369
9.56 0.488019599 280.470858 0.030106421 -0.60553958
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9.58 0.488621487 280.458752 0.030058401 -0.6045932
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9.6 0.489222415 280.446665 0.030010509 -0.60364928
9.61 0.48952252 280.440628 0.02998661 -0.60317825
9.62 0.489822386 280.434597 0.029962743 -0.60270782
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9.65 0.490720554 280.416529 0.029891332 -0.60130021
9.66 0.491019467 280.410516 0.029867591 -0.60083223
9.67 0.491318143 280.404508 0.029843882 -0.60036485
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9.74 0.493402253 280.36258 0.029678787 -0.59711008
 9.75 0.493699041 280.356609 0.029655326 -0.59664751
9.76 0.493995595 280.350643 0.029631896 -0.59618553
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10 0.501043282 280.20882 0.029078664 -0.58527418
10.01 0.501334069 280.202967 0.029055985 -0.58482675
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10.19 0.50652973 280.098377 0.028652725 -0.57686914
 10.2 0.506816257 280.092609 0.028630594 -0.57643232
10.21 0.507102563 280.086844 0.028608491 -0.57599605
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10.64 0.519208292 279.843034 0.027684084 -0.55774084
10.65 0.519485133 279.837457 0.027663174 -0.55732771
10.66 0.519761765 279.831884 0.027642291 -0.55691509
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11 0.529044664 279.644815 0.026947406 -0.54317993
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 11.1 0.531730433 279.590674 0.026748479 -0.53924601
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11.55 0.543574958 279.351818 0.025882389 -0.52210841
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 12 0.555039753 279.120479 0.025061197 -0.5058439
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12.45 0.566144273 278.896278 0.024281559 -0.49038828
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 12.9 0.57690654 278.678866 0.023540448 -0.47568345
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13 0.579253382 278.631441 0.023380707 -0.47251226
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13.35 0.587343276 278.467915 0.022835119 -0.46167663
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 13.8 0.597470027 278.263123 0.022163078 -0.4483198
13.81 0.597691658 278.258639 0.022148504 -0.44803003
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13.93 0.600339903 278.205066 0.021974803 -0.44457586
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13.99 0.601656237 278.178435 0.021888765 -0.44286467
14 0.601875125 278.174006 0.021874478 -0.44258049
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14.25 0.607301265 278.064206 0.021522055 -0.43556921
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 14.7 0.616850484 277.870901 0.020909977 -0.42338485
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15 0.623066211 277.745026 0.020517063 -0.41555832
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15.14 0.62592691 277.687081 0.020337668 -0.41198362
15.15 0.626130287 277.682961 0.020324948 -0.41173013
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 15.6 0.635152459 277.500155 0.019765233 -0.40057149
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16 0.64296482 277.341796 0.019287668 -0.39104416
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16.03 0.643543099 277.330072 0.019252577 -0.39034386
16.04 0.643735625 277.326169 0.019240902 -0.39011086
16.05 0.643928034 277.322267 0.019229238 -0.38987808
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 16.5 0.652467359 277.149095 0.018715497 -0.37962154
16.51 0.652654514 277.145298 0.018704323 -0.37939837
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21.45 0.733219845 275.507926 0.014211308 -0.28938031
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 21.9 0.739542409 275.379163 0.013883521 -0.28278948
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 23.7 0.763427209 274.892392 0.012674273 -0.25844525
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25.05 0.779984543 274.554638 0.011861376 -0.24205305
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 27.3 0.805289754 274.037943 0.010655261 -0.21768951
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27.75 0.810035615 273.940974 0.010433527 -0.21320484
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 28.2 0.814682996 273.845997 0.010217656 -0.20883705
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28.65 0.81923448 273.752961 0.010007407 -0.20458134
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29 0.822709815 273.681909 0.009847618 -0.20134593
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 29.1 0.823692546 273.661816 0.009802549 -0.20043319
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29.55 0.828059572 273.572515 0.009602864 -0.19638827
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 30 0.832337841 273.485012 0.009408145 -0.19244251
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30.45 0.836529542 273.399263 0.009218197 -0.18859202
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 30.9 0.840636782 273.315227 0.009032831 -0.1848331
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31 0.841538237 273.296781 0.008992243 -0.18400987
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31.35 0.844661583 273.232863 0.008851872 -0.18116225
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36.75 0.887169162 272.362101 0.00696972 -0.14290459
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 38.1 0.896306452 272.174718 0.006567906 -0.13471825
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38.55 0.899233558 272.114674 0.006438994 -0.13209042
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 39 0.90210318 272.055803 0.006312454 -0.12951026
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39.45 0.904916365 271.998083 0.006188208 -0.12697621
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 39.9 0.907674131 271.941493 0.006066179 -0.12448674
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 41.7 0.918170148 271.726052 0.005598819 -0.11494637
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43.05 0.925505273 271.575436 0.005268269 -0.10819306
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73.22 0.999938106 270.044505 0.000131648 -0.00271177
73.23 0.999939423 270.044478 0.00013024 -0.00268277
73.24 0.999940725 270.044451 0.000128832 -0.00265377
73.25 0.999942013 270.044425 0.000127424 -0.00262476
73.26 0.999943288 270.044398 0.000126016 -0.00259576
73.27 0.999944548 270.044372 0.000124608 -0.00256675
73.28 0.999945794 270.044347 0.000123199 -0.00253774
73.29 0.999947026 270.044321 0.000121791 -0.00250873
73.3 0.999948244 270.044296 0.000120383 -0.00247972
73.31 0.999949448 270.044272 0.000118974 -0.00245071
73.32 0.999950637 270.044247 0.000117565 -0.00242169
73.33 0.999951813 270.044223 0.000116157 -0.00239267
73.34 0.999952975 270.044199 0.000114748 -0.00236365
73.35 0.999954122 270.044175 0.000113339 -0.00233463
73.36 0.999955255 270.044152 0.00011193 -0.00230561
73.37 0.999956375 270.044129 0.000110521 -0.00227658
73.38 0.99995748 270.044106 0.000109112 -0.00224756
73.39 0.999958571 270.044084 0.000107702 -0.00221853
73.4 0.999959648 270.044061 0.000106293 -0.0021895
73.41 0.999960711 270.04404 0.000104884 -0.00216046
73.42 0.99996176 270.044018 0.000103474 -0.00213143
73.43 0.999962795 270.043997 0.000102064 -0.00210239
73.44 0.999963815 270.043976 0.000100654 -0.00207334
73.45 0.999964822 270.043955 9.924425E-05 -0.0020443
73.46 0.999965814 270.043934 9.783412E-05 -0.00201525
73.47 0.999966793 270.043914 9.642385E-05 -0.0019862
73.48 0.999967757 270.043894 9.501344E-05 -0.00195715
73.49 0.999968707 270.043875 9.360288E-05 -0.0019281
73.5 0.999969643 270.043856 9.219218E-05 -0.00189904
73.51 0.999970565 270.043837 9.078132E-05 -0.00186998
73.52 0.999971473 270.043818 8.93703E-05 -0.00184091
73.53 0.999972366 270.043799 8.795912E-05 -0.00181184
73.54 0.999973246 270.043781 8.654776E-05 -0.00178277
73.55 0.999974111 270.043763 8.513622E-05 -0.00175369
73.56 0.999974963 270.043746 8.372451E-05 -0.00172462
73.57 0.9999758 270.043729 8.231259E-05 -0.00169553
73.58 0.999976623 270.043712 8.090048E-05 -0.00166644
73.59 0.999977432 270.043695 7.948817E-05 -0.00163735
73.6 0.999978227 270.043679 7.807564E-05 -0.00160826
73.61 0.999979008 270.043663 7.666289E-05 -0.00157916
73.62 0.999979774 270.043647 7.52499E-05 -0.00155005
73.63 0.999980527 270.043631 7.383668E-05 -0.00152094
73.64 0.999981265 270.043616 7.24232E-05 -0.00149182
73.65 0.99998199 270.043601 7.100947E-05 -0.0014627
73.66 0.9999827 270.043587 6.959546E-05 -0.00143358
73.67 0.999983396 270.043572 6.818116E-05 -0.00140444
73.68 0.999984077 270.043558 6.676657E-05 -0.0013753
73.69 0.999984745 270.043544 6.535167E-05 -0.00134616
73.7 0.999985399 270.043531 6.393645E-05 -0.00131701
73.71 0.999986038 270.043518 6.252089E-05 -0.00128785
73.72 0.999986663 270.043505 6.110497E-05 -0.00125868
73.73 0.999987274 270.043492 5.968867E-05 -0.00122951
73.74 0.999987871 270.04348 5.827199E-05 -0.00120033
73.75 0.999988454 270.043468 5.685489E-05 -0.00117114
73.76 0.999989022 270.043456 5.543736E-05 -0.00114194
73.77 0.999989577 270.043445 5.401937E-05 -0.00111273
73.78 0.999990117 270.043434 5.260089E-05 -0.00108351
73.79 0.999990643 270.043423 5.118191E-05 -0.00105428
73.8 0.999991155 270.043412 4.976239E-05 -0.00102504
73.81 0.999991652 270.043402 4.834229E-05 -0.00099579
73.82 0.999992136 270.043392 4.692159E-05 -0.00096652
73.83 0.999992605 270.043383 4.550024E-05 -0.00093725
73.84 0.99999306 270.043373 4.407821E-05 -0.00090795
73.85 0.999993501 270.043364 4.265543E-05 -0.00087865
73.86 0.999993927 270.043355 4.123187E-05 -0.00084932
73.87 0.99999434 270.043347 3.980746E-05 -0.00081998
73.88 0.999994738 270.043339 3.838215E-05 -0.00079062
73.89 0.999995122 270.043331 3.695585E-05 -0.00076124
73.9 0.999995491 270.043323 3.55285E-05 -0.00073184
73.91 0.999995846 270.043316 3.41E-05 -0.00070242
73.92 0.999996187 270.043309 3.267024E-05 -0.00067296
73.93 0.999996514 270.043302 3.123912E-05 -0.00064349
73.94 0.999996826 270.043296 2.980649E-05 -0.00061398
73.95 0.999997125 270.043289 2.837221E-05 -0.00058443
73.96 0.999997408 270.043284 2.69361E-05 -0.00055485
73.97 0.999997678 270.043278 2.549794E-05 -0.00052522
73.98 0.999997933 270.043273 2.405749E-05 -0.00049555
73.99 0.999998173 270.043268 2.261445E-05 -0.00046583
74 0.999998399 270.043263 2.116847E-05 -0.00043604
74.01 0.999998611 270.043259 1.97191E-05 -0.00040619
74.02 0.999998808 270.043255 1.826579E-05 -0.00037625
74.03 0.999998991 270.043251 1.680785E-05 -0.00034622
74.04 0.999999159 270.043248 1.534439E-05 -0.00031607
74.05 0.999999312 270.043244 1.387422E-05 -0.00028579
74.06 0.999999451 270.043242 1.239569E-05 -0.00025534
74.07 0.999999575 270.043239 1.090649E-05 -0.00022466
74.08 0.999999684 270.043237 9.403137E-06 -0.00019369
74.09 0.999999778 270.043235 7.880042E-06 -0.00016232
 74.1 0.999999857 270.043233 6.327325E-06 -0.00013033
74.11 0.99999992 270.043232 4.724598E-06 -9.7321E-05
74.12 0.999999968 270.043231 3.015861E-06 -6.2123E-05
74.13 0.999999998 270.04323 8.078256E-07 -1.664E-05
74.14 1.000000006 270.04323 #NUM! #NUM!
 Balance de Energia

)/(((600−600𝑓)(0.2238𝑇 - 59.057))+((1200−400𝑓)(0.3566𝑇 - 91.41))+(300𝑓)(0.4254𝑇 - 101.89)+(18)(10000))

T,f vs t
295
290
285
280
275
T

270
265
260
255
10 20 30 40 50 60 70 80
tiempo (min)

f T
+(18)(10000))
 Inter 9.6996 K 0.018720159
EA 8374.8076
A 16311.0815 rx -0.412693526
a 0.5
b 1.5
Cx 2
Cy 3
T (k) 308.15

ΔHf 20000 cal/mol

∆𝐻_(17°𝐶)=20000+∫24_290.15^298.15▒ 〖 3(0.2238𝑇−59.057)+2(0.3566𝑇
T 333.15 K
∆𝐻_(60°𝐶) -996.685375 cal/mol
19003.3146
2238𝑇−59.057)+2(0.3566𝑇 - 91.41)+1.5(0.4254𝑇 - 101.89 〗 )𝑑𝑇